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The role of metal-oxygen intermediates in biological and chemical monooxygenation of alkanes

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Abstract

The role of metal-peroxo, -hydroperoxo, and -oxo intermediates in activation of O2 and transfer of an oxygen atom to the C—H bond in biocatalysis by heme and non-heme monooxygenases and biomimetic oxidation of alkanes is reviewed.

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Shteinman, A.A. The role of metal-oxygen intermediates in biological and chemical monooxygenation of alkanes. Russian Chemical Bulletin 50, 1795–1810 (2001). https://doi.org/10.1023/A:1014321827168

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