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Structures and properties of anionic clay minerals

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Abstract

The Mössbauer spectra of pyroaurite-sjögrenite-type compounds (PTC) (layered anion exchangers) are discussed with reference to the crystal structure, cation order, and crystallite morphology. It is shown that cation-ordered layers are produced in the synthesis of carbonate and sulphate types of green rust. In contrast, synthetic and natural pyroaurite only occurs as disordered types. The redox chemistry of Fe(III) within the metal hydroxide layer is illustrated with examples of electrochemical oxidation and reversible reduction by boiling glycerol. The chemistry of iron in the interlayer is exemplified by the intercalation of Fe-cyanide complexes in hydrotalcite. This reaction may be used as a probe for the charge distribution in the interlayer.

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References

  1. V.A. Drits, T.N. Sokolova and V.I. Cherkashin, Clays Clay Miner. 35 (1987) 401.

    Google Scholar 

  2. J.L. Crovisier, J.H. Thomassin, T. Juteau, J.P. Eberhart, J.C. Touray and P. Bailif, Geochim. Cosmochim. Acta 47 (1983) 377.

    Article  ADS  Google Scholar 

  3. J.S. White Jr., E.P. Henderson and B. Mason, Am. Miner. 52 (1967) 1190.

    Google Scholar 

  4. J.D. Bernal, D.R. Dasgupta and A.L. Mackay, Clay Miner. Bull. 4 (1959) 15.

    Google Scholar 

  5. G. Butler and J.G. Benyon, Corros. Sci. 7 (1967) 385.

    Article  Google Scholar 

  6. M.R. Al-Agha, S.D. Burley, C.D. Curtis and J. Esson, J. Geol. Soc., London, 152 (1995) 157.

    Google Scholar 

  7. C.B. Koch and S. Mørup, Clay Miner. 26 (1991) 577.

    Google Scholar 

  8. F. Trolard, J.-M. Génin, M. Abdelmoula, G. Bourrie, B. Humbert and A. Herbillon, Geochim. Cosmochim. Acta 61 (1997) 1107.

    Article  ADS  Google Scholar 

  9. H.C.B. Hansen and C.B. Koch, Appl. Clay Sci. 10 (1995) 5.

    Article  Google Scholar 

  10. F.C. Hawthorne, in: Spectroscopic Methods in Mineralogy and Geology, Reviews in Mineralogy, Vol. 18, Mineralogical Soc. of America (1988).

  11. R. Allmann, Acta Crystallogr. B 24 (1968) 972.

    Google Scholar 

  12. R. Allmann, Neues Jahrb. Mineral. Monatsh. (1969) 552.

  13. R. Allmann, Chimia 24 (1970) 99.

    Google Scholar 

  14. H.F.W. Taylor, Mineral. Mag. 39 (1973) 377.

    Google Scholar 

  15. T.C. Gibb, in: Principles of Mössbauer Spectroscopy (Chapman and Hall, London, 1965).

    Google Scholar 

  16. T. Ericsson and R. Wäppling, J. Phys. Coll. C 6(37) (1976) 719.

    Google Scholar 

  17. G.W. Brindley and S. Kikkawa, Am. Miner. 64 (1979) 836.

    Google Scholar 

  18. Z. Weiss, M. Rieder and M. Chmielová, Eur. J. Mineral. 4 (1992) 665.

    Google Scholar 

  19. Y. Tamaura, T. Yoshida and T. Katsure, T. Bull. Chem. Soc. Japan 57 (1984) 2411.

    Google Scholar 

  20. H. Miyamoto, T. Shinlo, Y. Bando and T. Takada, J. Phys. Soc. Japan 23 (1967) 1421.

    Article  Google Scholar 

  21. C.M. Cardile and D.G. Lewis, Aust. J. Soil. Res. 29 (1991) 399.

    Article  Google Scholar 

  22. C. Wivel and S. Mørup, J. Phys. E: Sci. Instrum. 14 (1981) 605.

    Article  ADS  Google Scholar 

  23. W. Feitknecht and G. Keller, Z. Anorg. Allg. Chemie 262 (1950) 61.

    Google Scholar 

  24. G.W. Brindley and D.L. Bish, Nature 263 (1976) 353.

    Article  Google Scholar 

  25. D. Lewis, Adv. Geoecol. 30 (1997) 345.

    Google Scholar 

  26. H. Drissi, P. Refait and J.-M. Génin, Hyp. Interact. 90 (1994) 395.

    Article  Google Scholar 

  27. R. Lin, R.L. Spicer, F.L. Tungate and B.H. Davis, Colloids and Surfaces A 13 (1996) 79.

    Google Scholar 

  28. R. Srinivasan, R. Lin, R.L. Spicer and B.H. Davis, Colloids and Surfaces A 113 (1996) 97.

    Google Scholar 

  29. H.C.B. Hansen and C.B. Koch, Can. J. Soil Sci., in press.

  30. E. Murad and R.M. Taylor, Clay Miner. 19 (1984) 77.

    Google Scholar 

  31. E. Murad and R.M. Taylor, in: Industrial Application of the Mössbauer Effect, eds. G.J. Long and J.G. Stevens (1987) p. 585.

  32. A.H. Cuttler, V. Man, T.E. Cranshaw and G. Longworth, Clay Miner. 25 (1990) 289.

    Google Scholar 

  33. U. Schwertmann and H. Fechter, Clay Miner. 29 (1994) 87.

    Google Scholar 

  34. H.C.B. Hansen, Clay Miner. 24 (1989) 663.

    Google Scholar 

  35. C.B. Koch and H.C.B. Hansen, Adv. Geoecol. 30 (1997) 373.

    Google Scholar 

  36. R. Ingalls, Phys. Rev. 133 (1964) 787.

    Article  ADS  Google Scholar 

  37. H.C.B. Hansen, O.K. Borggaard and J. Sørensen, Geochim. Cosmochim. Acta 58 (1994) 2599.

    Article  ADS  Google Scholar 

  38. H.C.B. Hansen, C.B. Koch, H. Nancke-Krogh, O.K. Borggaard and J. Sørensen, Environm. Sci. Technol. 30 (1996) 2053.

    Article  Google Scholar 

  39. H.C.B. Hansen and C.B. Koch, Clay Miner. 33 (1998) 87.

    Article  Google Scholar 

  40. L. Raki, D.G. Rancourt and C. Detellier, Chem. Mater. 7 (1995) 221.

    Article  Google Scholar 

  41. R.M. Taylor, H.C.B. Hansen, G. Stanger and C.B. Koch, Clay Miner. 26 (1991) 297.

    Google Scholar 

  42. R.S. Braithwaite, P.J. Dunn, R.G. Pritchard and W.H. Paar, Mineral. Mag. 58 (1994) 79.

    Google Scholar 

  43. H.C.B. Hansen, C.B. Koch and R.M. Taylor, J. Solid State Chem. 113 (1994) 46.

    Article  ADS  Google Scholar 

  44. A.F. Wells, in: Structural Inorganic Chemistry, 5th ed. (Clarendon Press, Oxford, 1984) p. 1382.

    Google Scholar 

  45. H.C.B. Hansen and C.B. Koch, Clay Miner. 31 (1996) 53.

    Google Scholar 

  46. A. Manceau, Can. Mineral. 28 (1990) 321.

    Google Scholar 

  47. H.C.B. Hansen and R.M. Taylor, Clay Miner. 26 (1991) 311.

    Google Scholar 

  48. H.C.B. Hansen and C.B. Koch, Inorganic Chem. 33 (1994) 5363.

    Article  Google Scholar 

  49. S. Miyata and T. Kumura, Chem. Lett. (1973) 843.

  50. S. Miyata and T. Hirose, Clays Clay Miner. 26 (1978) 441.

    Google Scholar 

  51. S. Kikkawa and M. Koizumi, Math. Res. Bull. 17 (1982) 191.

    Article  Google Scholar 

  52. K. Itaya, H.-C. Chang and I. Uchida, Inorg. Chem. 26 (1986) 624.

    Article  Google Scholar 

  53. K.A. Carrado and A. Kostapapas, Solid State Ionics 26 (1988) 77.

    Article  Google Scholar 

  54. B.R. Shaw, Y. Deng, F.E. Strillacci, K.A. Carrado and M.G. Fessehaie, J. Electrochem. Soc. 137 (1990) 3136.

    Article  Google Scholar 

  55. F.A.P. Cavalcanti, A. Schutz and P. Biloen, in: Preparation of Catalysts IV, eds. B. Delmon et al. (1987) p. 165.

  56. S. Idemura, E. Suzuki and Y. Ono, Clays Clay Miner. 37 (1989) 553.

    Google Scholar 

  57. H.C.B. Hansen and C.B. Koch, Clays Clay Miner. 42 (1994) 170.

    Google Scholar 

  58. G.K. Wertheim, in: Mössbauer Effect: Principles and Applications (Academic Press, New York, 1971) p. 116.

    Google Scholar 

  59. N.N. Greenwood and T.C. Gibb, in: Mössbauer Spectroscopy (Chapman and Hall, London, 1971) p. 659.

    Google Scholar 

  60. E.P. Giannelis, D.G. Nocera and T.J. Pinnavaia, Inorg. Chem. 26 (1987) 203.

    Article  Google Scholar 

  61. J.M.D. Coey, in: Mössbauer Spectroscopy Applied to Inorganic Chemistry, Vol. 1, ed. G.J. Long (Plenum Press, New York, 1984) p. 443.

    Google Scholar 

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  1. Chemistry Department, The Royal Veterinary and Agricultural University, Thorvaldsensvej 40, DK-1871, Frederiksberg C., Denmark

    Chr. Bender Koch

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Koch, C.B. Structures and properties of anionic clay minerals. Hyperfine Interactions 117, 131–157 (1998). https://doi.org/10.1023/A:1012603712578

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