Skip to main content
SpringerLink
Log in

DME synthesis from carbon dioxide and hydrogen over Cu–Mo/HZSM-5

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

HZSM-5 supported copper–molybdenum oxide prepared by an impregnation method has been applied for the first time in the hydrogenation of CO2. The effect of the loading of Mo, the reaction temperature and the stability of hydrogenation of CO2 were investigated. The results indicate that adding a small amount of Mo (Mo/Cu = 1/2 wt) markedly enhances the catalytic activity. The highest DME selectivity was more than 70%. The change of species on the catalyst surface due to the addition of Mo was also investigated by in situ DRIFT.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. K. Fujimoto and K. Yokota, Chem. Lett. (1991) 559.

  2. L.J. Gao and C.T. Au, J. Catal. 189 (2000) 1.

    Google Scholar 

  3. P. Koenig, CHEMTECH 24 (1994) 36.

    Google Scholar 

  4. T. Znui and T. Takeguchi, Catal. Today 10 (1991) 95.

    Google Scholar 

  5. D. Gasser and A. Baiker, Appl. Catal. 28 (1986) 235.

    Google Scholar 

  6. E. Ramaroson, R. Kieffer and A. Kiennemann, J. Chem. Soc. Chem. Commun. 12 (1982) 645.

    Google Scholar 

  7. M.Q. Kang and Z.X. Ren, Hencheng Huaxue 2 (1994) 320.

    Google Scholar 

  8. A.M. Rouhi, Chem. Eng. News 73 (1995) 37.

    Google Scholar 

  9. T. Myake and A. Taima, Jpn. Patent 6–249 080 (1994).

  10. S. Bobbo, R. Camporese and R. Stryjeck, Fluid Phase Equilib. 161 (1999) 305.

    Google Scholar 

  11. Z.-Y. Hou, J.-H. Fei and X.-M. Zheng, Petrochem. Technol. (Chinese) 28 (1999) 59.

    Google Scholar 

  12. B. Herman, Aerosol. Spray. Rep. 33 (1994) 385.

    Google Scholar 

  13. S. Lee, M.R. Gogate and C.J. Kulik, Fuel. Sci. Technol. Int. 13 (1993) 1039.

    Google Scholar 

  14. R. Stryjeck, R. Camporese and C. Zilio, J. Chem. Eng. Data 44 (1999) 568.

    Google Scholar 

  15. J.L. Dubois, K. Sayama and H. Arakawa, Chem. Lett. (1992) 1115.

  16. S. Natio and K. Fujimoto, J. Chem. Soc. Chem. Commun. 20 (1972) 1266.

    Google Scholar 

  17. K.K. Bardo, K. Sayama, H. Kusama, K. Okabe and H. Arakawa, Appl. Catal. 165 (1997) 391.

    Google Scholar 

  18. G.J. Millar and C.H. Rochester, J. Catal. 53 (1978) 208.

    Google Scholar 

  19. C. Schild and A. Wakaum, J. Mol. Catal. 63 (1990) 223, 243.

    Google Scholar 

  20. D. Bianchi, T. Chaflk, M. Khalfah et al., Appl. Catal. 105 (1993) 223.

    Google Scholar 

  21. D. Bianchi, T. Chaflk, M. Khalfah et al., Appl. Catal. 112 (1994) 219.

    Google Scholar 

  22. T.C. Schilke, I.A. Fisher and A.T. Bell, J. Catal. 184 (1999) 144.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Catalysis, Zhejiang University (Xixi Campus), Hangzhou, 310028, PR China

    Gong-Xin Qi, Jin-Hua Fei, Xiao-Ming Zheng & Zhao-Yin Hou

Authors
  1. Gong-Xin Qi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jin-Hua Fei
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Xiao-Ming Zheng
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Zhao-Yin Hou
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Qi, GX., Fei, JH., Zheng, XM. et al. DME synthesis from carbon dioxide and hydrogen over Cu–Mo/HZSM-5. Catalysis Letters 72, 121–124 (2001). https://doi.org/10.1023/A:1009049513834

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1009049513834

Search

Navigation