Abstract
The hydrodynamic diffusion modes of an equimolar methane–ethane mixture have been investigated by dynamic light scattering. Measurements were performed over a wide temperature range between the plait critical point at 263.55 K and 310 K along the critical isochore. Two relaxation modes have been observed which are commonly associated with pure mass diffusion and pure thermal diffusion, but in near-critical binary fluid mixtures—according to recent theory—may alternatively be interpreted as two effective diffusivities resulting from a coupling between mass and thermal diffusion. Diffusivity values for the slow mode were obtained with typical standard deviations of 1% over the whole temperature range, whereas the low amplitude of the fast mode only allowed values of this component with a large measurement uncertainty. The results are discussed in connection with literature data available for the thermophysical properties of this binary fluid mixture and regarding the various possibilities of theoretical interpretation.
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Fröba, A.P., Will, S. & Leipertz, A. Diffusion Modes of an Equimolar Methane–Ethane Mixture from Dynamic Light Scattering. International Journal of Thermophysics 21, 603–620 (2000). https://doi.org/10.1023/A:1006629516889
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DOI: https://doi.org/10.1023/A:1006629516889