γ-Regioselective reaction of metaloxysilyl-substituted allyllithium derived from allyldiphenylsilanol
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Oxygen-promoted coupling of arylboronic acids with olefins catalyzed by [CA]<inf>2</inf>[PdX<inf>4</inf>] complexes without a base
2015, Journal of Molecular Catalysis A: ChemicalCitation Excerpt :Despite its high potential and many applications, this reaction has some drawbacks such as harsh reaction conditions, the requirement of an inert atmosphere, and the generation of hydrogen halide as a byproduct [1–10]. In addition to the conventional Heck reaction, olefins can also be arylated by the use of nucleophilic organometallic reagents such as aryl derivatives of silicon [11–14], antimony [15], and tin [16–20]. Unfortunately, these organometallic reagents and their byproducts are highly toxic and difficult to separate from the final product.
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