Strategies for the synthesis of sequence-controlled glycopolymers and their potential for advanced applications
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Graphical abstract
Keywords
Block copolymers
Nanostructures
Self-assembly
Polysaccharides
Controlled polymerization
Abbreviations
AROP
anionic ring-opening polymerization
ATRP
atom transfer radical polymerization
BCP
block copolymer
CDSA
crystallization-driven self-assembly
CROP
cationic ring-opening polymerization
CTA
chain-transfer agent
CuAAC
copper-catalyzed azide-alkyne cycloaddition
DEGA
di(ethylene glycol) methyl ether acrylate
DEGMA
di(ethylene glycol) methyl ether methacrylate
DMAEMA
2-(dimethylamino)ethyl methacrylate
DMF
N,N-dimethylformamide
FRP
free radical polymerization
HEA
2-hydroxyethyl acrylate
HEMA
2-hydroxyethyl methacrylate
LAP
living anionic polymerization
LCP
living cationic polymerization
MAA
methacrylic acid
nBA
n-butyl acrylate
nBMA
n-butyl methacrylate
NCA
N-carboxyanhydride
NiPAAm
N-isopropyl acrylamide
NMP
nitroxide-mediated polymerization
P3HT
poly(3-hexylthiophene)
PBLG
poly(benzyl-L-glutamate)
PCL
poly(ε-caprolactone)
PDEGA
poly(di(ethylene glycol) methyl ether acrylate)
PDEGMA
poly(di(ethylene glycol) methyl ether methacrylate)
pDNA
plasmid DNA
PEO
poly(ethylene oxide)
PHEA
poly(2-hydroxyethyl acrylate)
PHEMA
poly(2-hydroxyethyl methacrylate)
PISA
polymerization-induced self-assembly
PLA
poly(lactic acid)
PMAA
poly(methacrylic acid)
PMMA
poly(methyl methacrylate)
PnBA
poly(n-butyl acrylate)
PnBMA
poly(n-butyl methacrylate)
PS
polystyrene
RAFT
reversible addition-fragmentation chain-transfer
ROMP
ring-opening metathesis polymerization
ROP
ring-opening polymerization
rROP
radical ring-opening polymerization
SET-LRP
single electron transfer ‘living’ radical polymerization
TEMPO
(2,2,6,6-tetramethylpiperidin-1-yl)oxyl)
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© 2021 The Authors. Published by Elsevier B.V.