Elsevier

Mendeleev Communications

Volume 27, Issue 3, May–June 2017, Pages 260-262
Mendeleev Communications

Molecular tectonics: from a binuclear metallamacrocycle to a 1D isostructural coordination network based on tetracyanomethyl[1.1.1.1]metacyclophane and a silver cation

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Depending on the anion (NO3- or BF4-) and stoichiometry, the combinations of [1.1.1.1]metacyclophane adopting a blocked 1,3-alternate conformation and bearing four cyanomethylene groups with silver cations under self-assembly conditions lead to the formation of either a 1D coordination network or a discrete binuclear metallomacrocycle.

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