Shoshonitic volcanism of the Bodrum caldera (SW Turkey): Hybridization of enriched mantle-derived and crustal melts

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Highlights

  • Miocene Bodrum volcanism is represented by shoshonitic series magmatic rocks.

  • Magma mixing/mingling was a frequent process during magmatic evolution.

  • Partial melting of enriched mantle and subducting crustal rocks produced Bodrum magmas.

  • AFC/FCA processes probably have produced relatively evolved compositions.

Abstract

Bodrum Caldera, located at the southwestern tip of the Anatolian plate, comprises volcanic rocks formed by intrusive, effusive and explosive volcanic activity during Miocene. Volcanic rocks chemically belong to K-rich shoshonitic series and comprised of a range of compositions from absarokites to rhyolites with intrusive micromonzogabbros and micromonzonites. The least evolved magmatic rocks are the post-caldera micromonzogabbros. Blebs/droplets with different mineralogical/petrographical characteristics and resorbed xenocrystic glomerocrysts/cumulates comprised of feldspar and clinopyroxene in disequilibrium with the host rocks suggest that mixing between compositionally different magmas was an important process for the evolution of Bodrum volcanism. Especially shoshonites contain mixing and mingling textures probably occurred between monzogabbroic and more evolved monzonitic magmas. Fractional crystallization was limited to felsic (>60% SiO2) rocks where feldspar, pyroxene, biotite, apatite and zircon were the main fractionating phases. Trace element abundances indicate a garnet-bearing enriched mantle peridotite, resembling EM-1 with a modal assemblage of garnet, rutile, titanite and phlogopite, as the common mantle source rock. Non-modal fractional melting models exhibit that micromonzonites, absarokites and micromonzogabbros were derived from lower (1–3%), moderate (10–15%) and higher (>20%) degrees partial melting of an enriched mantle, respectively. Besides, monzonitic compositions can be produced by partial fusion of a subducting slab with hypothetical composition of 80% GLOSS and 20 % N-MORB. Basic-intermediate compositions can be produced by the mixing/mingling of the micromonzogabbroic and monzonitic magmas. Crustal assimilation and fractional crystallization of hybrid absarokitic melts can yield intermediate-to-felsic compositions of Bodrum shoshonitic series.

Introduction

Potassic volcanic rocks are characteristic of collisional settings where potassium-rich partial melts and/or fluids derived from subducted continental material initiate and/or mix with mantle-derived melts (Palmer et al., 2019). Potassium-rich volcanic rocks belonging to the shoshonite suite are common features of post-orogenic extensional settings inboard from subduction zones (Pe-Piper et al., 2009). Despite having some common geochemical characteristics, shoshonitic series of rocks display a diversity of compositions as a result of the tectonic setting in which they occur, particularly in a) rifts and back-arc basins in intra-oceanic island arcs b) rifts in continental magmatic arcs and c) post-collisional orogenic settings (Gill et al., 2004). Due to the variety of their formation settings, partial melting of metasomatized (lithospheric) mantle and delaminated or thickened crust have been proposed for the genesis of shoshonitic magmas (Wang et al., 2017 and references therein). Moreover, experimental decompression melting of metasomatized phlogopite + pargasite lherzolite produced magmas with shoshonitic affinity (Conceiçao and Green, 2004).

Widespread magmatism was active in the Aegean and the Eastern Mediterranean regions during Neogene (Robert et al., 1992), producing igneous rocks most of which are recognized as resulting from extension and derived mainly from the sub-continental lithospheric mantle (Pe-Piper and Piper, 2001). According to the compilation of radiometric data (Akal et al., 2013) on Western Turkey, the potassic and ultrapotassic magmatism have occurred between 20 and 4 My. Especially, lamprophyric potassic and ultrapotassic volcanism occur around Afyon and Isparta regions (Aydar et al., 2003, Akal et al., 2013, Ersoy and Palmer, 2013, Prelević et al., 2010, Prelević et al., 2012, Prelevic et al., 2015, Elitok, 2019). Prelević et al. (2010) propose to use the lamproitic rocks emplaced between 20 and 4 My as an indicator of accretion and/or shallow subduction event in the assembly of southwestern Turkey. Moreover, Palmer et al. (2019) suggest that continental material was subducted to depths of > 75 km, where phengite breaks down to yield potassic melts that initiate melting of the overlying lithospheric mantle to produce the ultrapotassic volcanism in western Turkey.

Bodrum peninsula, where potassic volcanism is observed in western Turkey, is located in southwestern Anatolia and northeast of Hellenic Arc (Fig. 1a). The volcanism of Bodrum is related to an 18x13 km resurgent caldera with outcropped monzonitic body (magma chamber) and highly altered volcanics at its center (Ulusoy et al., 2004). Lava flows, domes and associated block-and-ash flows, ignimbrite deposits as well as subvolcanic intrusions decorate the volcanic landscape. In this study, we present new petrological data from the Miocene shoshonitic Bodrum volcanism, co-genetic with back-arc volcanic rocks of Cyclades (Robert et al., 1992). In order to better understand the petrogenesis, we discussed the petrological characteristics in terms of magma mixing, different degrees of partial fusion of various sources and assimilation – fractional crystallization.

Section snippets

Geological context

The eastern Mediterranean is shaped by the northeast directed subduction of Africa underneath Greece and Anatolia (Doglioni et al., 2002). The Aegean region is one of the most rapidly extending areas of the continental crust in the world (Jackson, 1994), forming an extensional back-arc area to the South Aegean subduction zone since Miocene (Brun et al., 2016).

Aegean region represents horst-graben systems corresponding a rift complex, interpreted as a classic back-arc basin (Pichon and Angelier,

Volcanic evolution

The evolution of Bodrum volcanism comprises three consecutive stages, namely pre-caldera, syn-caldera and post-caldera (Ulusoy et al., 2004). Paroxysmal caldera-forming ignimbritic eruptions separate the pre-caldera and post-caldera volcanism. Block-and-ash flow deposits, the products of widespread explosive dome activity, are observed throughout both pre- and post-caldera stages. Sub-volcanic intrusions of the dominantly post-caldera stage have been observed extensively in the region (Fig. 1

Electron microscopy and EPMA

Scanning electron microscopy studies were undertaken in the Electron Microscopy and Microanalysis Laboratories of Hacettepe University (Ankara, Turkey) using a Zeiss EVO 50 EP SEM equipped with a Silicon Drift Detector (SDD) Energy Dispersive Spectrometer (EDS) (Bruker-Axs XFlash 3001). Analytical conditions for both Backscattered Electron (BSE) imaging and EDS mapping were 12–15 kV accelerating voltage, 10–15nA beam current, 3–5 µm beam diameter, and 10 mm of working distance. Mineral

Classification and nomenclature

Volcanic products of Bodrum volcanism were classified and named according to their chemical compositions. The nomenclature used throughout this study and as well as the representative mineralogical and petrographical characteristics of each unit were summarized in Table 1. SiO2 and total alkali (Na2O + K2O) contents of the analyzed samples were recalculated on a volatile-free basis and plotted on a TAS (Total Alkali-Silica) diagram according to Le Bas et al. (1986) (Fig. 3a). Samples mostly

Petrography and mineralogy

The Bodrum volcanic rocks are comprised of lava flows, block-and-ash flows, ignimbrites and abundant hypabyssal intrusions with dominantly porphyritic textures. However, rare occurrences of holocrystalline textures are observed in some post-caldera micromonzonitic dykes, pre-caldera monzonitic pluton and also intensely silicified lavas around resurgent domes in Karakaya and Dagbelen. Representative mineralogical and petrographical properties of the Bodrum volcanic rocks were summarized in Table

Geochemistry

Geochemical analyses of the Bodrum volcanics were given in Table 4 and also in Electronic Supplementary Data.

Magma mingling/mixing

Petrographical and mineralogical observations and acquired data imply that mixing/mingling of magmatic bodies was a frequent process during the evolution of the Bodrum volcanic rocks (Fig. 4).

Shoshonites, and to some degree banakites, display evidence for the mixing/mingling between compositionally different melts (Fig. 4). High resolution scanning electron microscopy and integrated energy dispersive spectrometry imaging reveal that some shoshonites bear blebs in which the orientation of the

Conclusions

Miocene Bodrum volcanism largely consists of a shoshonitic series magmas ranging from absarokites to scarce rhyolites formed by intrusive, effusive and explosive activities. Magma mixing between compositionally different melts was the dominant process, and fractional crystallization and crustal assimilation were also operational for the generation of Bodrum volcanics. Geochemical evidence from incompatible element ratios suggests that the Bodrum volcanic rocks formed by different degrees of

CRediT authorship contribution statement

H. Evren Çubukçu: Conceptualization, Methodology, Data curation, Writing - original draft. Erkan Aydar: Supervision, Conceptualization, Data curation, Resources, Project administration, Writing - review & editing. İnan Ulusoy: Investigation, Resources. Alain Gourgaud: Supervision, Resources, Funding acquisition.

Declaration of Competing Interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Acknowledgements

This work was conducted within the framework of French-Turkish scientific cooperation and benefited from a research grant from Hacettepe University (Ankara, Turkey). We gratefully acknowledge the careful and constructive comments of Ibrahim Uysal (Editor) and two anonymous reviewers.

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