Supramolecular assembly of [Co2(2,2′-bpy)6]·(BTCA)·Cl·11H2O: 3D negatively charged cages
Graphical Abstract
A novel Co (II) complex with 2,2′-bpy ligand, which contains supramolecular (H2O)11 morphology. The hydrogen-bonding association leads to the formation of the infinite morphology of water molecules.
Research Highlights
► Cobalt complex [Co2(2,2'-bpy)6]4+ pillars 2D layers of organic anions [(BTCA).11(H2O)]3-. ► The structure contains 3D negatively charged cage. ► Dual host-guest structure features including water clusters.
Section snippets
Acknowledgements
The authors thank the Project Supported by Scientific Research Fund of Zhejiang Provincial Education Department (y200908138).
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