Skip to main content
Log in

Properties of High Basicity Mold Fluxes for Peritectic Steel Slab Casting

  • Published:
Journal of Iron and Steel Research International Aims and scope Submit manuscript

Abstract

In high speed continuous casting of peritectic steel slabs, mold fluxes with high basicity are required for less surface defect product. However, the basicity of remaining liquid slag film tends to decrease in casting process because of the crystallization of 3CaO • 2SiO2 • CaF2. Thus, a way is put forward to improve mold fluxes properties by raising the original basicity. In order to confirm the possibility of this method, the effect of rising original basicity on the properties of mold fluxes is discussed. Properties of high fluorine based mold fluxes with different basicities and contents of CaF2, Na2O, and MgO were measured, respectively. Then, properties of higher basicity mold fluxes were discussed and compared with traditional ones. The results show that increasing the basicity index can improve the melting and flow property of mold fluxes. With the increasing basicity, crystallization rate of mold fluxes increases obviously and crystallization temperature tends to decrease when the basicity exceeds 1. 35. The method presented before is proved as a potential way to resolve the contradiction between horizontal heat transfer controlling and solidified shell lubricating for peritectic steel slab casting. But further study on improving the flow property of liquid slag is needed. This work can be used to guide mold fluxes design for high speed continuous casting of peritectic steel slabs.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. CHI Jing-hao, GAN Yong-nian. Mould Powder for Continuous Casting [M]. Shenyang: Northeastern University Press, 1992 (in Chinese).

    Google Scholar 

  2. Yamauchi A. Effect of Solidus Temperature and Crystalline Phase of Mould Flux on Heat Transfer in Continuous Casting Mould [J]. Ironmaking and Steelmaking, 2002, 29(3): 203.

    Article  Google Scholar 

  3. Mills K C, Fox A B. The Role of Mold Fluxes in Continuous Casting-So Simple Yet So Complex [J]. ISIJ International, 2003, 43(10): 1479.

    Article  Google Scholar 

  4. Kromhout J A, Liebske C, Melzer S, et al. Mould Powder Investigations for High Speed Casting [J]. Ironmaking and Steel-making, 2009, 36(4): 291.

    Article  Google Scholar 

  5. MO De-min, ZHANG Ya-li. Break Temperatures of Mold Fluxes and Their Relevance to Continuous Casting [J]. Wide and Heavy Plate, 2002, 8(4): 40 (in Chinese).

    Google Scholar 

  6. Nakano T, Kishi T, Koyama K, et al. Mold Powder Technology for Continuous Casting of Aluminum-Killed Steel [J]. ISIJ, 1984, 12(11): 950.

    Article  Google Scholar 

  7. Park J H, Min D J. The Effect of CaF2 on the Viscosities and Structures of CaOSiO2 (-MgO)-CaF2 Slags [J]. Metallurgical and Materials Transactions, 2002, 33B(10): 723.

    Article  Google Scholar 

  8. SHU Jun, JIN Shan-tong, ZHANG Li, et al. Crystallization Temperature of Continuous Casting Mold Fluxes [J]. Journal of University of Science and Technology Beijing, 2000, 22(6): 508 (in Chinese).

    Google Scholar 

  9. Sánchez-Jiménez P E, Criado J M, Pérez-Maqueda L A. Kissinger Kinetic Analysis of Data Obtained Under Different Heating Schedules [J]. Journal of Thermal Analysis and Calorime-try, 2008, 94(2): 427.

    Article  Google Scholar 

  10. Boswell P G. On the Calculation of Activation Energies Using a Modified Kissinger Method [J]. Journal of Thermal Analysis, 1980, 18: 353.

    Article  Google Scholar 

  11. Budrugeac P, Segal E. Applicability of the Kissinger Equation in Thermal Analysis [J]. Journal of Thermal Analysis and Calorimetry, 2007, 88(3): 703.

    Article  Google Scholar 

  12. MAO Yu-wen. Metallurgy Fluxes [M]. Beijing: Metallurgy Industry Press, 1994 (in Chinese).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Xiao Long or Sheng-ping He.

Additional information

Foundation Item: Item Sponsored by National Natural Science Foundation of China (50904083)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Long, X., He, Sp., Xu, Jf. et al. Properties of High Basicity Mold Fluxes for Peritectic Steel Slab Casting. J. Iron Steel Res. Int. 19, 39–45 (2012). https://doi.org/10.1016/S1006-706X(12)60111-3

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1016/S1006-706X(12)60111-3

Keywords

Navigation