A simple procedure for the synthesis of three-carbon homologated boronate esters and terminal alkenes via nucleopbilic displacement in α-haloallylboronate ester

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Abstract

The transfer reactions of α-haloallylboronate ester I with representative organolithium and Grignard reagents provide α-alkyl- or α-aryl-subsfituted aUylboronate esters, readily converted into three-carbon homologated boronate esters and terminal alkenes.

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