ansa-metallocene derivatives XXXIX biphenyl-bridged metallocene complexes of titanium, zirconium, and vanadium: Syntheses, crystal structures and enantioseparation1
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Cyclic and Non-Cyclic Pi Complexes of Vanadium
2022, Comprehensive Organometallic Chemistry IV: Volume 1-15Sodium naphthalenide reduction of 1,3–diphenyl–6–(tert-butyl) fulvene: Stabilizing Eu<sup>2+</sup> with a sterically demanding ansa–ligand framework
2018, Journal of Organometallic ChemistryCitation Excerpt :Substituted cyclopentadienyl ligands expanded access to many other Ln2+ metallocenes, and opened synthetic routes for the stabilization of low–coordinate lanthanide complexes [10–21]. The unique structures enforced by the inter-annular bridged cyclopentadienyl ligands of ansa–metallocene complexes introduces attractive properties, such as increased stability and spatially tunable metal active sites that find application in catalytic transformations [22–29]. Typical methods used to synthesize ansa-metallocene complexes involve the reductive dimerization of 6– and 6,6′–substituted fulvenes with various metal reagents to form bridged cyclopentadienyl dianions, and the subsequent in situ reaction with transition– and lanthanide–metal halides [30–37].
Ansa-vanadocene complexes with short interannular bridges
2006, Journal of Organometallic ChemistryGroup 4 metallocene complexes incorporating vinyl or allyl substituted ansa ligands (see abstract)
2003, Journal of Organometallic Chemistry
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For part XXXVIII see Ref. [2].