Regular paperSynthesis and surface-active properties of amphiphilic 6-aminocarbonyl derivatives of d-glucose
Abstract
Several 6-amido-6-deoxy derivatives of methyl α-d-glucopyranoside and d-glucopyranose were prepared from 6-azido-6-deoxy intermediates. The Staudinger reaction (PPh3, carboxylic acid or acid chloride) or the addition of n-heptanol on the 6-deoxy-6-isocyano derivatives, obtained from the 6-azido analogues, completed the synthesis. The Krafft temperatures and surfactant properties of these compounds are reported.
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