Synthesis and biological activity of both (E)- and (Z)-isomers of optically pure (S)-14-methyl-8-hexadecenal (trogodermal), the antipodes of the pheromone of the khapra beetle
References (28)
Tetrahedron Letters
(1973)Tetrahedron
(1974)The Synthesis of Insect Pheromones
- et al.
Agric. Biol. Chem.
(1979) - et al.
Tetrahedron
(1979) - et al.
Naturwissenschaften
(1979) - et al.
Tetrahedron
(1981) Tetrahedron
(1977)- et al.
Agric. Biol. Chem.
(1979) - et al.
Naturwissenschaften
(1981) - et al.
Tetrahedron
(1979)
Tetrahedron
(1980)
The Synthesis of Insect Pheromones
Science
(1969)
J. Chem. Ecol.
(1976)
Cited by (50)
Chiral methyl-branched pheromones
2015, Natural Product ReportsPheromone synthesis. Part 240: Cross-metathesis with Grubbs I (but not Grubbs II) catalyst for the synthesis of (R)-trogodermal (14-methyl-8-hexadecenal) to study the optical rotatory powers of compounds with a terminal sec-butyl group
2009, TetrahedronCitation Excerpt :The absolute configuration of the levorotatory 3 and 4 of insect origin was determined as R by synthesizing dextrorotatory (S)-3 from the known (S)-2-methyl-1-butanol (5).4,5 Although these two pheromone aldehydes (R)-1 and (R)-2 as well as their enantiomers have been synthesized repeatedly by us6–8 and also by others,9–11 it is worthwhile to achieve a simple synthesis of (R)-trogodermal (1) by olefin cross-metathesis reaction (A+B→C) as shown in Scheme 1. Olefin cross-metathesis12–14 has been employed advantageously in the synthesis of olefinic pheromones,15 including aliphatic pheromones with methyl-branchings.1,16
Synthesis of new polyisocyanates
2001, Materials Science and Engineering CSynthesis of new polyisocyanates
2001, European Polymer JournalPrediction of the absolute configuration of optically active pheromones using liquid crystals
1993, Tetrahedron: AsymmetryOverview of Kenji Mori’s pheromone synthesis series
2023, Journal of Pesticide Science
Copyright © 1982 Published by Elsevier Ltd.