High-pressure study of the intramolecular electron-transfer luminescence of 9,9′-bianthryl in viscous solvents

doi:10.1016/0009-2614(84)85695-X

Chemical Physics Letters

Volume 107, Issue 2, 25 May 1984, Pages 178-180

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Abstract

The intramolecular electron-transfer state of 9,9′-bianthryl was investigated in viscous solvents at high pressures. In the low-pressure region, there is a true equilibrium between the electron transfer and locally excited states, whereas the increase in the viscosity of the solvents becomes the dominant factor in the high-pressure region. In particular, a change in the kinetics was observed in i-butanol and in i-amyl alcohol as the pressure was increased to 10 kbar.

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High-pressure study of the intramolecular electron-transfer luminescence of 9,9′-bianthryl in viscous solvents

Abstract

Ber. Bunsenges. Physik. Chem.

Bull. Chem. Soc. Japan

Ber. Bunsenges. Physik. Chem.

J. Am. Chem. Soc.

Z. Physik. Chem.