FTIR studies of the kinetics and mechanism for the reaction of Cl atom with formaldehyde
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Cited by (38)
Atmospheric sink of styrene, Α-methylstyrene, trans-Β-methylstyrene and indene: Rate constants and mechanisms of Cl atom-initiated degradation
2019, Atmospheric EnvironmentCitation Excerpt :From a minimum of three experiments, plots of the yields of products versus the amount of consumed styrene gave a molar benzaldehyde, benzoyl chloride, formyl chloride and formaldehyde yield of 22 ± 3%, 28 ± 6%, 24 ± 4% and 29 ± 2%, respectively. The yields for formaldehyde and benzaldehyde were corrected due to secondary losses reaction with Cl using k (Cl + formaldehyde) = 7.8 × 10−11 cm3 molecule−1 s−1 (Niki et al., 1978) and k(Cl + benzaldehyde) = 1.0 × 10−10 cm3 molecule−1 s−1 (Thiault et al., 2002) by the method outlined in Tuazon et al. (1986). The rate constants with Cl atoms for benzoyl chloride (Caralp et al., 1999) and formyl chloride (Sanhueza et al., 1975; Niki et al., 1980) have been reported to be fairly low at room temperature, i.e. 1.16 × 10−15 cm3 molecule−1 s−1 and 7.8 × 10−13 cm3 molecule−1 s−1, respectively, so these two products were not corrected for secondary losses.
Reaction products and mechanisms for the reaction of n-butyl vinyl ether with the oxidants OH and Cl: Atmospheric implications
2015, Atmospheric EnvironmentCitation Excerpt :The main products identified by comparison of the IR spectra after the consumption of BVE >99% were butyl formate (CH3(CH2)3OC(O)H), butyl chloroacetate CH3(CH2)3OC(O)CH2Cl), formic acid (HCOOH), HCl, and CO. The IR bands at 1784 and 738 cm−1 were assigned to formyl chloride (HCOCl) by comparison with the characteristic IR bands of this compound from the literature (Niki et al., 1978; French et al., 1994). In a separate experiment it was confirmed that the peaks at 1148 and 695 cm−1 were due to reaction products of BVE with Cl2.
The reaction of formyl radical with chlorine atom
2004, Chemical Physics LettersThe reaction of formaldehyde with chlorine atom
2003, Chemical Physics LettersA high-resolution fourier transform infrared study of the out-of-plane bending fundamentals of hcocl and dcocl
1995, Journal of Molecular SpectroscopyA high-resolution fourier transform infrared study of the ν<inf>3</inf>, ν<inf>4</inf>, and ν<inf>5</inf> bands of deuterated formyl chloride (DCOCl)
1995, Journal of Molecular Spectroscopy