Net directed 180° aryl–aryl bond rotation in a prototypical achiral biaryl lactone synthetic molecular motor
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Acknowledgements
We are grateful to NSF-CHE-9986926, PRF #35372AC-1, the US Department of Education GAANN P200A010222-03, and the NSF-IGERT DGE-0114419, for financial support.
References and notes (20)
- et al.
Molecular Devices and Machines
(2003)et al.Angew. Chem.
(2000)Angew. Chem., Int. Ed.
(2000) Molecular Motors
(2003)Our Molecular Nature
(1996)- et al.
Angew. Chem.
(2004)Angew. Chem., Int. Ed.
(2004) - et al.
J. Am. Chem. Soc.
(2002)et al.Org. Biomol. Chem.
(2004)et al.Nature
(1999) - et al.
Nature
(2003)et al.Science
(2004) - et al.
Nature
(1999)et al.J. Am. Chem. Soc.
(2000)et al.Acc. Chem. Res.
(2001) - et al.
J. Org. Chem.
(2003)et al.Org. Lett.
(2004)et al.J. Am. Chem. Soc.
(2004)et al.New J. Chem.
(2005)et al.J. Am. Chem. Soc.
(2005)et al.Science
(2004)et al.Tetrahedron Lett.
(2004) - et al.
Proc. Nat. Acad. Sci. U.S.A.
(2002)et al.Nat. Mater.
(2003)
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