CCCO: Generation by dc glow discharge in carbon suboxide, and microwave spectrum
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Possible interstellar anions: C <inf>n</inf> S <sup>-</sup> and C <inf>n</inf> O <sup>-</sup> (n = 2-8)
2011, Advances in Space ResearchCitation Excerpt :The newly calculated rotational constant (1376.9 MHz) and the earlier estimated values (1376.2 or 1377.1 MHz) are in good agreement with the laboratory and astronomical values (1376.86298 and 1376.86248 MHz). It is known that the electronic ground states of CnS (n = 2–8) (Saito et al., 1987; Ohshima and Endo, 1992; Gordon et al., 2001) and CnO (Brown et al., 1985; Tang et al., 1985; Ohshima et al., 1995; Ogata et al., 1995) are a 3Σ− one for even n and a 1Σ+ one for odd n, respectively. The optimized geometries are in good agreement with the geometric shapes derived from the experimental electronic states as shown in Figs. 1 and 2.
SiCCO and CCCO: Accurate equilibrium structures and spectroscopic constants
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