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Effect of MWCNT anchoring to the carbon fiber surface on the interlaminar property and fracture topography of carbon fabric/vinyl ester composites: comparisons between conventional and semi-spread carbon fabrics

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Abstract

In the present work, multi-walled carbon nanotubes (MWCNT) were anchored with the assistance of vinyl ester resin (VE) on the carbon fiber surfaces of conventional carbon fabrics (CCF) and semi-spread carbon fabrics (SSCF) having different areal density, ply thickness, and crimp number, respectively. Here, MWCNT anchoring means that MWCNT were physically attached on the individual carbon fiber surfaces of each fabric by coating with dilute VE and then by thermally curing it. The MWCNT anchoring effect on the interlaminar shear strength (ILSS) of CCF/VE and SSCF/VE composites was investigated. MWCNT were also simply applied (without physical attachment) to the carbon fiber surfaces of CCF and SSCF for comparison, respectively. It was found that SSCF/VE composites exhibited the ILSS higher than CCF/VE composites, regardless of simple-applying or anchoring of MWCNT, increasing the ILSS with the MWCNT concentration. It was noted that MWCNT anchoring was effective to improve not only the interlaminar adhesion but also the interfacial bonding between the carbon fiber and the matrix due to the formation of MWCNT bridges between the individual carbon fibers of SSCF, indicating that the MWCNT anchoring effect was more pronounced with SSCF than with CCF. The result of the interlaminar property was well supported by the fiber and composite fracture topography.

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Data availability

The data used in the present study are available from the corresponding author on reasonable request.

References

  1. Lee D, Kim Y, Kwon OH, Park WH, Cho D (2021) Carbon fiber coating with MWCNT in the presence of polyethyleneimine of different molecular weights and the effect on the interfacial shear strength of thermoplastic and thermosetting carbon fiber composites. Carbon Lett 31:407–417

    Article  Google Scholar 

  2. Zhang Z, Fu K, Li Y (2021) Improved interlaminar fracture toughness of carbon fiber/epoxy composites with a multiscale cellulose fiber interlayer. Compos Comm 27:100898

    Article  Google Scholar 

  3. Sayam A, Rahman ANMM, Rahman MS, Smriti SA, Ahmed F, Rabbi MF, Hossain M, Faruque MO (2022) A review on carbon fiber-reinforced hierarchical composites: mechanical performance, manufacturing process, structural applications and allied challenges. Carbon Lett 32:1173–1205

    Article  Google Scholar 

  4. Kim DK, Kang SH, Han W, Kim KW, Kim BJ (2022) Facile method to enhance the mechanical interfacial strength between carbon fibers and polyamide 6 using modified silane coupling agents. Carbon Lett 32:1463–1472

    Article  Google Scholar 

  5. Kwon DJ, Park SM, Kwon IJ, Park JM, Jeong E (2019) Improvement of interlaminar properties of carbon fiber-reinforced epoxy composites using aluminum trihydroxide. Carbon Lett 29:183–191

    Article  Google Scholar 

  6. Chang IY, Lee JK (1988) Recent development in thermoplastic composites: a review of matrix systems and processing methods. J Thermoplast Compos Mater 1:277–296

    Article  Google Scholar 

  7. Li C, Fei J, Zhang T, Zhao S, Qi L (2023) Relationship between surface characteristics and properties of fiber-reinforced resin-based composites. Compos Part B 249:110422

    Article  CAS  Google Scholar 

  8. Borg C (2015) An introduction to spread tow reinforcements: part 1—manufacture and properties. Reinf Plast 59:194–198

    Article  Google Scholar 

  9. Kim RY, Soni SR (1984) Experimental and analytical studies on the onset of delamination in laminated composites. J Compos Mater 18:70–80

    Article  CAS  Google Scholar 

  10. Coulter JP, Güçeri SI (1989) Resin impregnation during composites manufacturing: theory and experimentation. Compos Sci Technol 35:317–330

    Article  CAS  Google Scholar 

  11. Dessouky HE, Lawrence C (2013) Ultra-lightweight carbon fibre/thermoplastic composite material using spread tow technology. Compos Part B 50:91–97

    Article  Google Scholar 

  12. Moradi A, Sun C, Guan Z, Rastegarzadeh S (2023) Technology for lateral spreading of fibre bundles for applications in manufacturing thermoplastic composites. Compos Part A 167:107422

    Article  CAS  Google Scholar 

  13. Gaur B, Rai JSP (1992) Curing and decomposition behaviour of vinyl ester resins. Polymer 33:4210–4214

    Article  CAS  Google Scholar 

  14. Sultania M, Rai JSP, Srivastava D (2012) Modeling and simulation of curing kinetics for the cardanol-based vinyl ester resin by means of non-isothermal DSC measurements. Mater Chem Phy 132:180–186

    Article  CAS  Google Scholar 

  15. Ji SG, Drzal LT, Cho D (2021) Chemical modification of exfoliated graphite nanoplatelets with CTBN rubber and highly enhanced impact strength of vinyl ester resin by them. J Indus Eng Chem 102:293–301

    Article  CAS  Google Scholar 

  16. Joshi SC, Dikshit V (2012) Enhancing interlaminar fracture characteristics of woven CFRP prepreg composites through CNT dispersion. J Compos Mater 46:665–675

    Article  CAS  Google Scholar 

  17. Felisberto M, Tzounis L, Sacco L, Stamm M, Candal R, Rubiolo G, Goyanes S (2017) Carbon nanotubes grown on carbon fiber yarns by a low temperature CVD method: a significant enhancement of the interfacial adhesion between carbon fiber/epoxy matrix hierarchical composites. Compos Comm 3:33–37

    Article  Google Scholar 

  18. Song X, Gao J, Zheng N, Zhou H, Mai YW (2021) Interlaminar toughening in carbon fiber/epoxy composites interleaved with CNT-decorated polycaprolactone nanofibers. Compos Commun 24:100622

    Article  Google Scholar 

  19. Pötschke P, Mothes F, Krause B, Voit B (2019) Melt-mixed PP/MWCNT composites: influence of CNT incorporation strategy and matrix viscosity on filler dispersion and electrical resistivity. Polymers 11:189

    Article  PubMed  PubMed Central  Google Scholar 

  20. Kumar A, Sharma K, Dixit AR (2021) A review on the mechanical properties of polymer composites reinforced by carbon nanotubes and graphene. Carbon Lett 31:149–165

    Article  Google Scholar 

  21. Akar AO, Yildiz UH, Tirkes S, Tayfun U, Hacivelioglu F (2022) Influence of carbon nanotube inclusions to electrical, thermal, physical and mechanical behaviors of carbon-fiber-reinforced ABS composites. Carbon Lett 32:987–998

    Article  Google Scholar 

  22. Ma PC, Siddiqui NA, Marom G, Kim JK (2010) Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: a review. Compos Part A 41:1345–1367

    Article  Google Scholar 

  23. Davis DC, Wilkerson JW, Zhu J, Hadjiev VG (2011) A strategy for improving mechanical properties of a fiber reinforced epoxy composite using functionalized carbon nanotubes. Compos Sci Technol 71:1089–1097

    Article  CAS  Google Scholar 

  24. Gupta N, Gupta SM, Sharma SK (2019) Carbon nanotubes: synthesis, properties and engineering applications. Carbon Lett 29:419–447

    Article  Google Scholar 

  25. Ahmadi M, Zabihi O, Masoomi M, Naebe M (2016) Synergistic effect of MWCNTs functionalization on interfacial and mechanical properties of multi-scale UHMWPE fibre reinforced epoxy composites. Compos Sci Technol 134:1–11

    Article  CAS  Google Scholar 

  26. Jiménez-Suárez A, Campo M, Gaztelumendi I, Markaide N, Sánchez M, Ureña A (2013) The influence of mechanical dispersion of MWCNT in epoxy matrix by calendering method: batch method versus time controlled. Compos Part B 48:88–94

    Article  Google Scholar 

  27. Cheon J, Yoon BI, Cho D (2018) The synergetic effect of phenolic anchoring and multi-walled carbon nanotubes on the yarn pull-out force of para-aramid fabrics at high speed. Carbon Lett 26:107–111

    Google Scholar 

  28. Cheon J, Cho D (2020) Enhancement of yarn pull-out force of para-aramid fabric at high speed by dispersion and phenolic anchoring of MWCNT on the fiber surfaces in the presence of surfactant and ultrasonic process. Macromol Res 28:881–884

    Article  CAS  Google Scholar 

  29. Cheon J, Cho D (2022) Effects of peroxide-based initiators with different molecular sizes on cure behavior and kinetics of vinyl ester resin containing multi-walled carbon nanotubes. J Therm Anal Calori 147:11883–11898

    Article  CAS  Google Scholar 

  30. Cho D, Choi Y, Drzal LT (2003) Characterization, properties, and processing of LaRC PETI-5 as a high-temperature sizing material. III. Adhesion enhancement of carbon/BMI composites. J Adhes 79:1–23

    Article  CAS  Google Scholar 

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Acknowledgements

This research was supported by Kumoh National Institute of Technology (2021).

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Correspondence to Donghwan Cho.

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Cheon, J., Cho, D. Effect of MWCNT anchoring to the carbon fiber surface on the interlaminar property and fracture topography of carbon fabric/vinyl ester composites: comparisons between conventional and semi-spread carbon fabrics. Carbon Lett. 34, 619–626 (2024). https://doi.org/10.1007/s42823-023-00625-w

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