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Dual-acting cellulose nanocomposites filled with carbon nanotubes and zeolitic imidazolate framework-67 (ZIF-67)–derived polyhedral porous Co3O4 for symmetric supercapacitors

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A Correction to this article was published on 25 August 2021

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Abstract

Conforming to sustainable development trend, natural material cellulose has been extensively studied in the field of energy storage. However, its low conductivity is a huge obstacle to its application in supercapacitors. Integrating nanocellulose as a green binder with conductive materials achieves the efficient use of natural resources. Here, carbon nanotubes (CNTs) were embedded in porous Co3O4 (PCO) dodecahedrons in situ derived from zeolitic imidazolate framework-67 (ZIF-67), for which the morphologies of the composites were considerably remained at the dodecahedron. The main pseudo-capacitive materials are regulated by different amounts of CNTs to modify the morphology and enhance the conductivity. For electrode materials, the charming structure of PCO-CNTs (PCC) with multichannels allows efficient electron transfer, which brings about a competent utilization of redox active sites in PCO. What is more worth mentioning is that the nanocellulose-PCC nanocomposites with good processing properties were used to form binder-free electrodes. Given the fine designed structure and good electrochemical performance, the electrodes were assembled into symmetric supercapacitors, showing high areal capacitance, energy, and power density. The preparation of composites based on PCC and nanocellulose provides a new way to develop sustainable energy storage devices.

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Funding

This work was supported by the National Natural Science Foundation of China (No. 31670592, 32071713), the Fundamental Research Funds for the Central Universities (No. 2572018AB38), the Outstanding Youth Foundation Project of Heilongjiang Province (JQ2019C001), and the Central University Basic Scientific Research Project of China (No. 2572020DX01).

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Author notes

  1. Keqi Qu and Zhe Sun contributed equally to this work.

Authors and Affiliations

  1. Key Laboratory of Bio-Based Material Science & Technology, Material Science and Engineering College, Northeast Forestry University, Harbin, 150040, China

    Keqi Qu, Zhe Sun, Cai Shi, Weicong Wang, Lidong Xiao, Jiangyang Tian & Zhanhua Huang

  2. Integrated Composites Laboratory (ICL), Department of Chemical and Bimolecular Engineering, University of Tennessee, Knoxville, TN, 37996, USA

    Zhanhu Guo

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  4. Weicong Wang
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  5. Lidong Xiao
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  6. Jiangyang Tian
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  7. Zhanhua Huang
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  8. Zhanhu Guo
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Correspondence to Zhanhua Huang or Zhanhu Guo.

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The original online version of this article was revised: Author Zhanhua Huang was inadvertently not labelled as a co-corresponding author of the paper. This is now correctly reflected in the affiliation section.

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Qu, K., Sun, Z., Shi, C. et al. Dual-acting cellulose nanocomposites filled with carbon nanotubes and zeolitic imidazolate framework-67 (ZIF-67)–derived polyhedral porous Co3O4 for symmetric supercapacitors. Adv Compos Hybrid Mater 4, 670–683 (2021). https://doi.org/10.1007/s42114-021-00293-2

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