Highlights
-
Soluble compounds are added to the Dion–Jacobson (DJ) perovskite precursor solutions.
-
Current studies and development trends of additive compounds in DJ-phase perovskite solar cells are reviewed.
-
The innate functions of additive compounds in DJ-phase perovskite solar cells are developed.
-
An insightful perspective is outlined for future research in additive compounds for DJ-phase perovskite solar cells.
Abstract
Because of their better chemical stability and fascinating anisotropic characteristics, Dion–Jacobson (DJ)-layered halide perovskites, which owe crystallographic two-dimensional structures, have fascinated growing attention for solar devices. DJ-layered halide perovskites have special structural and photoelectronic features that allow the van der Waals gap to be eliminated or reduced. DJ-layered halide perovskites have improved photophysical characteristics, resulting in improved photovoltaic performance. Nevertheless, owing to the nature of the solution procedure and the fast crystal development of DJ perovskite thin layers, the precursor compositions and processing circumstances can cause a variety of defects to occur. The application of additives can impact DJ perovskite crystallization and film generation, trap passivation in the bulk and/or at the surface, interface structure, and energetic tuning. This study discusses recent developments in additive engineering for DJ multilayer halide perovskite film production. Several additive-assisted bulk and interface optimization methodologies are summarized. Lastly, an overview of research developments in additive engineering in the production of DJ-layered halide perovskite solar cells is offered.
Similar content being viewed by others
Avoid common mistakes on your manuscript.
1 Introduction
Halide perovskites have acted well in outstanding solar cells which achieved a best efficiency of 25.7% [1,2,3,4,5] and are driving current photovoltaic technology development [6,7,8]. Nevertheless, the weak stability of halide perovskites stays an essential problem that has to be addressed before this low-priced and solution-processable photovoltaic equipment can be commercialized on a large scale [9, 10].
Prior research has shown that adding large or long-chain monovalent organic cations [11], for example C4H9NH3+ [12,13,14,15], to create two-dimensional (2D) Ruddlesden–Popper (RP)-layered halide perovskite phases [11, 16] is a useful method for boosting the chemical steadiness of halide perovskites (PVK). Even though these materials appear to have better chemical stability in a variety of environmental settings [5, 17], their photovoltaic performance is typically worse than that of three-dimensional (3D) halide PVK [18, 19], primarily because the intrinsic van der Waals gap hinders carrier transport across the long organic spacers [20,21,22,23]. To attain improved steadiness although limiting carrier transport in solar cells, it is important to look into strategies to offset the unfavorable impacts of such interlayer constructions as those observed in RP-layered halide perovskites [24,25,26,27].
Dion–Jacobson (DJ) phase-layered halide PVK are the subject of this review since they have received a lot of interest from scientists. DJ-layered halide perovskites have the chemical formula (A’)(A)n−1BnX3n+1 (A = CH3NH3+ (MA+), HC(NH2)2+ (FA+), and/or Cs+; B = Sn2+ and/or Pb2+, X = Cl−, Br− and/or) I− [28, 29], which is a derivation of ABX3 [30,31,32,33,34]. Divalent interlayer organic cations in structure A' are what set it apart [35, 36]. In Fig. 1a, the potential chemical components of A' interlayer cations are shown [37]. As schematically shown in Fig. 1a, these innovative chemical configurations of organic cation interlayers reduce the interlayer spacing and delete the van der Waals gap in DJ phases [38]. These distinct interlayer chemistry designs encourage increased stability while opening a higher likelihood of carrier hopping or tunnelling [39]. As a result, the potential of DJ-stacked halide perovskite to provide more perfect device performance in solar cells has been proven [40, 41].
To enhance DJ PSC performance, several strategies have been proposed [40, 42, 43]. Among these, additives are often employed and have been crucial to several discoveries [44, 45]. In addition to increasing the DJ PSCs' efficiency, additives are also used to reduce hysteresis and boost stability [46]. The hysteresis is affected by the interaction of ion movement, charge buildup, and charge trapping/detrapping. Here, a significant portion is attributable to the movement of ions when taking into account the timeframes for each activity. By enlarging crystal grains, enhancing crystal quality, and passivating flaws, additive engineering is utilized to get rid of or lessen hysteresis [31, 47, 48]. This research reviews the additives used to create stable, effective, and hysteresis-reduced DJ PSCs. We clarify the key characteristics of additives, which are: (i) influencing the morphological characteristics of the DJ perovskite layer; (ii) trying to stabilize the phase of DJ perovskites; (iii) adapting the energy level alignment in DJ PSCs; (iv) repressing non-radiative recombination in DJ perovskites; (v) removing hysteresis; and (vi) boosting the steadiness of DJ PSCs [49]. The workings of the mechanisms and the effects of additions on the functionality of DJ equipment are also evaluated. Despite some encouraging developments, there are still several problems with these DJ-stacked halide perovskites that need basic comprehension and device development.
2 Short Outline of the DJ-Layered Halide Perovskites' Structural and Optical Characteristics
The divalent-cation and "large-small" alternating-cation layer configurations [51, 52], which produce significant chemical changes [53, 54], are the essential features that separate DJ from RP phases.
The first difference relates to the crystal formations' octahedral configuration [55]. As shown in Fig. 1, the bulky or long-chain monovalent organic cation pairs in the RP-stacked halide perovskite fill the interlayer gap [32], displacing the neighboring 2D perovskite slabs by half an octahedron [56, 57]. In DJ-layered halide perovskite, however, divalent cations are perpendicularly associated with 2D perovskite pieces [38, 58]. Well-aligned layered structures are produced because there is no shift between octahedral slabs [59, 60]. The focus of the second distinction is the interlayer gap [61], which is clearly affected by the spacer cation properties [62, 63]. Thanks to the bilayer configuration of univalent cation pairs, as indicated in Fig. 1a, interlayer spaces in RP multilayer halide perovskites are frequently the largest [64, 65]. DJ-layered halide perovskite can have significantly lower interlayer distances than RP-layered halide perovskite because their divalent organic cations have a monolayer structure [66,67,68]. The third difference in layered halide perovskite has to do with how 2D perovskite slabs interact with one another [69]. As seen in Fig. 1a, DJ-layered halide perovskites completely fill the van der Waals gap that appeared in the RP-layered halide perovskite [70]. Through hydrogen bonding, the interlayer cations with double ammonium groupings act together considerably along with the surrounding 2D perovskite pieces [71]. Therefore, the structural stability of 2D-layered halide perovskite may be improved by reducing or removing van der Waals gaps [72]. DJ-stacked halide perovskite has really shown to have extraordinarily good stability [73]. Further hydrogen bond engineering, particularly at high temperatures, can result in the creation of multilayer halide perovskites that are even more stable [74].
We discover that DJ has specific (dis)advantages in relation to the three chemo-structural properties mentioned above when compared to RP-layered halide perovskite [75, 76]. The level of photogenerated carrier dissociation is often greater in DJ-stacked halide perovskites [77, 78] due to the significantly smaller interlayer distances. The stability of DJ multilayer halide perovskite may also be better since hydrogen bonds are present and van der Waals gaps are completely absent [79]. An integrated design of DJ in thin films is therefore essential [50] to achieve the perfect stability between chemical steadiness and carrier transportation, that is widely sought for solar cells. The development of the recorded efficiency for RP and DJ PSCs is seen in Fig. 1b. Table 1 lists all the additives' detailed descriptions for DJ PSC's performances.
3 DJ-Layered Halide Perovskites Materials and Devices
Nonradiative recombination severely reduces the efficiency of solar cells. Defects are inevitable since perovskite films are often polycrystalline [17, 80]. The most common cause of nonradiative recombination is a carrier recombination center caused by a defect [51, 81]. There are many different types of flaws in solution-processed DJ halide perovskite films, including dislocations, grain boundaries, and point flaws like vacancy [82], interstitial, and antisite substitution defects [50]. Although research has shown that the majority of these defects are light carriers' traps and do not cause significant nonradiative recombination [79], cautious modification of defects in DJ halide perovskites is still necessary to advance DJ PSC performance toward the Shockley-Queisser efficiency limit [78]. In Fig. 2a, a novel crystal pattern established on the DJ class of PVK creates 2D hybrid PVK devoid of additives, as examined by the Mao research team [83]. These materials are composed of layers, and the precise arrangement of the inorganic layers one on upper of the other gives the filling of these layers a distinctive appearance. The use of the different spacer cations (3AMP and 4AMP) significantly affects the general properties. The 3AMP and 4AMP exhibit lesser band gaps than the most widely used 2D-RP perovskites as a result of a fewer distorted inorganic structure and nearer interlayer gaps. The actual device assembly demonstrated that the 3AMP series had superior optoelectronic properties over the 4AMP series. The winning gadget, according to the preliminary findings, has a PCE of more than 7%. It has been revealed that nonradiative recombination-causing flaws in 2D-DJ-layered halide PVK layers are typically present at grain boundaries or at the interfaces of PVK and choosy connections [76]. The bulk of these faults are uncoordinated ions like I− or Pb2+ [84] and faults are divided into two types: positive defects and negative defects. This is due to the periodicity of the termination lattice. As a result, a variety of compounds might be used to passivate flaws [31, 85].
3.1 N, N-dimethyl Sulfoxide Additives
Different types of additives are used in the manufacture of DJ PSCs [86]. The strong coordination capability of Pb2+ and I− in DJ halide PVK [87], that additionally serves as the basis for PSC solution procedure [88, 89], is primarily responsible for the diversity of accessible additives. Ions from salt additions can coordinate with the lead cation or iodine anion from DJ perovskites thanks to an ionic connection, which is well understood. Via exhausting an antisolvent rinsing stage throughout spin-coating of the perovskite solution, Zhang et al. [90] proved a solvent manufacturing technique. This caused fast supersaturation for even, dense nucleation, creation of perovskite grains, which resulted in the development of a dense, flat, fully enclosing, extremely crystalline DJ perovskite thin layer in Fig. 2b-e. The Lewis base N, N-dimethyl sulfoxide (DMSO) was utilized to create a stable and homogeneous intermediate phase of MAI, PbI2, and DMSO, which was then used to anneal into perovskite to slow down the interaction between MAI and PbI2. As a result, carrier movement along the perpendicular direction was considerably boosted and power conversion efficiency was increased. The efficiency of the hot-casting equipment was excellent at 15.81%.
In order to generate a Lewis adduct and passivate the defects, Lewis bases often serve as electron donors that are able to attach to the clearly charged, undercoordinated Pb2+ [83, 91,92,93]. According to Cohen et al. [94], PbI2∙DMSO adducts are created when Lewis bases DMSO and/or iodide interact with Lewis’s acids PbI2, and it has been demonstrated that these adducts are essential on behalf of advanced charge extraction and a gentler rate of recombination in the H3N–C4H6(OH)2–NH3 (n = 5) spacer-based low-dimensional DJ perovskite. Accordingly, the DJ solar cell demonstrated improved stability and a 10% efficiency during 1030 h of relative humidity (RH) of more than 50%. A Lewis base is an oxygen-containing lone pair of electrons which coordinately bonds to undercoordinated PbI2 [95]. It has been discovered that several solvents, such as DMSO, are polar aprotic and include an oxygen-bearing lone electron pair, indicating that they can function as O-donor Lewis bases [96]. By replacing DMSO with -butyrolactone (GBL), Ahmad et al. [97] showed that a steady intermediate adduct phase is able to form. This phase can then be converted into homogeneous and fresnel lens Dion–Jacobson phase 2D (PDA)MA2Pb3I10 perovskites, which provide PCE of 13.3% as well as extremely high device stability.
DMSO can provide intermediates that can make crystallized and great DJ perovskite layers [6]. Applying a hybrid solvent of GBL and DMSO, Fu et al. [63] evolved solvent manufacturing to generate a consistent, good DJ (PDA)MA3Pb4I13 (n = 4, PDA stands for 1,3-propanediammonium) PVK layer for high-performance PSCs by a credentialed PCE of 13.8% and brilliant thermal steadiness at 85 °C in humid atmosphere. PbI2 solubility was increased when DMSO was used, and the crystallization kinetics were adjusted for significantly better film coverage and smoothness. A larger monoammonium is added to the diammonium-based 2D-DJ-DMSO perovskite as the matrix to produce a second RP phase PVK that coexists with DJ PVK. This helps with crystal formation, reduces charge recombination, and enhances charge transport.
DMSO, a very polar solvent that can dissolve lead halide, was generally used to dissolve DJ halide perovskites [98, 99]. It has also been shown that DMSO can be used to make excellent DJ perovskite film based on tin (Sn) [100,101,102]. Li et al. [102] used solvent-controlled perovskite film development to achieve a record PCE of 6.43% based on Sn-based DJ (BDA)FA2Sn3I10. The reaction between DMSO molecules and Lewis' acid Tin (II) iodide (SnI2) produced the intermediate adduct SnI2·3DMSO, that competently slows the reaction between SnI2 and methylammonium iodide (MAI), producing an even and pinhole-free MASnI3 layer by micron-sized grains afterward the DMSO molecules are removed by annealing at 100 °C. The intermediate's crystal structure was determined to be SnI2·3DMSO, with the coordination sphere being made up of three DMSO molecules that are connected to Sn by oxygen and iodide ions. Additionally, (BDA)FA2Sn3I10 displayed strong crystal symmetry, which led to efficient carrier separation and absorption. The compact (BDA)FA2Sn3I10 film displayed weaker quantum confinement with better carrier diffusion and mobility, according to transient absorption (TA) studies. However, the (BDA)FA2Sn3I10 devices demonstrated greater resistance to oxidation, light, and humidity.
The performance of the device was improved when DMSO additive was added to the (ThDMA)(MA)n-1PbnI3n+1 (n = 5) precursor solution, along with Lu and coworkers [101] (Fig. 3). A process utilizing a combined solvent of DMF and DMSO might be used to create significant 2D-DJ perovskite, as well as better crystallinity, desired vertical orientation, and expanded spatially determined carrier life. The enhanced device demonstrated a good PCE of 15.75%, that was a record, for aliphatic spacer-based 2D-DJ PSCs. The unconjugated 2D-DJ perovskite cells also retained around 95% after 1,655 h in N2. These findings imply that the design of thiophene-based aromatic spacers and the engineering of devices may result in extremely effective and reliable 2D-DJ PSCs.
Xiang’s study [103] recognized a facile green-antisolvent procedure with DMSO additive to control the phase delivery of MA-free quasi-2D DJ phase PVK films (DMePDA)FA3Pb4I13 (n = 4). The layers offered a more homogeneous phase delivery, resulting in higher out-plane mobility, decreased surface-trap density, and better conductivity. The PCE of 2D-DJ-layered halide PSCs and the shape of perovskites were both shown to be significantly enhanced by DMSO-induced complexes.
3.2 Chlorine Anion Additive
Chloride is a common addition for passivation (Cl−) [85]. Cl− significantly lowers trap density and enhances charge durations of diffusion and carrier lives in DJ halide perovskite films [104, 105]. DJ phase Pb–Sn PVK of (PhDMA)MA4(Pb0.5Sn0.5)5I16 in 2D PSCs is used with MACl additive [105]. MACl is adopted to enhance the layer quality of 2D Pb–Sn PVK, enabling the suppression of the trap density and nonradiative recombination for DJ PSCs. Zhao’s research team [106] recently developed a technique for solvent vapor plasticizing 2D PVK layers by addition of 20 mol% methylammonium chloride (MACl) additives. Their rotation caused by the surface and accompanying grain development were assisted by MACl, which improved out-of-plane charge transfer. Comparing 2D perovskite solar cells to their untreated counterparts, they are more efficient and stable. Their (BDA)(Cs0.1FA0.9)4Pb5I16 solar cell showed a certified PCE of 18.00%.
Cl− is crucial for effective planar DJ PSCs in the early stage [107] because it passivates flaws in DJ perovskite films and on the surface of titanium dioxide's (TiO2) ETL and at the interface between TiO2 and DJ perovskite. Significantly, (BDA)-based PSCs were created by Niu and colleagues [108]. To help the perovskite (PVK) film crystallize and produce big, high-quality PVK grains, they applied the MACl additive. The BDA caused the inorganic sheet gap to be smaller and the inorganic sheets to be more ordered, which allowed the PVK layers to present favorable charge movement, very few defects, and almost crystallinity with a single crystal. The PCE of the solar cells that performed the best was 17.91%, and there was negligible hysteresis. The PSCs demonstrated high stability as well; after 1,182 h of storage (humidity: 60% RH) in room air without any encapsulation, 84% of the original PCE was still present. Even though the majority of these research primarily focused on morphology and demonstrated that the chloride residual in the film A rising (BDA)MA4Pb5I16 film was produced by Zheng et al. [109] using MACl in precursor solution. The formation energies demonstrated that the perovskite construction is thermodynamically stabilized by Cl−. Because to the excellent surface shape, crystallographic characteristics, and optical absorption properties, the device displayed an appealing PCE of 16.38%.
Common processes like the antisolvent approach and sequential deposition technique for producing DJ perovskite films often include chloride additives. Jin [110] have studied a novel method with MACl additive to better remove the surface traps in PVK layers by the additional secondary anti-solvent treatment. A highest PCE of 19.55% is completed based on DJ PVK. Recently, Wang et al. [111] reported that the delivery uniformity is significantly enhanced with a temperature fabrication method by adding Cl− to the MAI precursor solution and using (BDA) as cross-linking molecules to generate 2D-DJ PSCs. By using MACl and/or DMSO as additives, the dispersity and crystalline orientation may be adjusted, leading to the production of perovskite films of excellent quality. It produced (BDA)MA3Pb4I13 recipes with PCEs up to 12.81% efficiency. MACl is one of the additives utilized most often to create superior PVK layers among these organic ammonium salts [39]. Ma et al. [112] created a (PDA)-based 2D perovskite cell and used MACl additive, which was found all over the film and was integrated into the perovskite lattice, to obtain a PCE of 13.0%. The increased connection across the perovskite structure also contributes to the steadiness of the PDA-based DJ PVK. The findings show that 2D perovskites with low interlayer distances function very well, offering an alternate method for enhancing the effectiveness and stability of 2D perovskites. They concluded that the secret to good performance is Cl−.
Additionally, a secondary interlayer spacer, Lead (II) chloride (PbCl2), has been added to low-dimensional perovskites based on formamidinium (FA), which significantly enhances the film quality [90, 107]. According to Zhao and colleagues [113], the Cl additive can greatly lengthen the diffusion lengths of the hole and electron. Additionally, it lowers the PVK thin film's bulk trap-state density [114]. Recent research by Wang et al. [115] focused on the nucleation of DJ (PXD)(MA)2Pb3I10 perovskite layers with the MACl additive. For DJ perovskites with large organic cations, this is accurate, such as p-xylylenediamine (PXD) in Fig. 4. Due to its low sublimation temperature, the majority of MACl was eliminated during the thermal annealing. Pure perovskite films were produced, improving coverage and absorption, which boosted device performance. For PSCs based on (PXD)(MA)2Pb3I10, the engineering resulted in a dramatic improvement in PCE, going from 1.2% to 15.6%. Even after 1,500 h of storage in a glove box or 700 h of continuous light, the unencapsulated DJ perovskite devices still had an efficiency of above 90%.
Wang et al. [116] also discovered that 2,3,5,6-tetrafluoro-1,4-benzenedimethanammonium (TFBDA+) may be utilized to create a unique DJ PVK layer with dense and evenly dispersed geomorphology and enhanced charge transfer. Cl− slowed down the manufacture of PVK layers and made the PVK layers' color darker. The delayed crystallization procedure raised the film coverage on the planar substratum and considerably enhanced the device presentation of the mesoporous cell architectures. The unconjugated cells reserved more than 90% of their fresh efficiency after 1,300 h in 40%-70% RH air more than 80% that after 100 h of annealing process at 80 °C, demonstrating its noticeably enhanced water as the base and thermal performances compared to its nonfluorinated counterpart. Larger-sized cations as MA+, FA+, or (ammonium) NH4+ are used as additions in chloride salts [117]. Because of the organic cation's mass, there is a lot of interionic space, which reduces the strength of the electrostatic attraction that attracts electrons to one another [47]. In the PVK annealing post-treatment, the organic chloride addition may be simply removed because chloride is combustible [89]. Additionally, researchers have investigated how NH4Cl additive affects the crystallinity and surface morphology of perovskites. Su [118] et al. showed that NH4Cl improves crystallinity and morphology of (BDA)FA4Pb5I16 perovskite thin films in Fig. 5. Beginning with the gradient energy band alignment, carrier transit, extraction, and transfer are made simpler. Better crystallinity and a decrease in defect density as a result of recrystallization are seen after FABr treatment. Last but not least, Br inclusion primarily increases device stability. The device's PCE of 16.75%, which was much greater than the control devices of 0.5%, was primarily caused by a massive increase in VOC of 1.107 V.
In addition, Xu et al. [85] investigated TTDMAI, a spacer made of fused thiophene that has been effectively produced for 2D-DJ PSCs with Cl−. In comparison with the mesoporous design, the planar architecture was shown to have bigger grain sizes and higher interfacial charge injection rates due to chloride doping. The effectiveness of PSCs was greatly enhanced. Cl− was discovered to help crystals form; perovskite films' absorbance or photoluminescence properties were unaffected. It's significant to note that the TTDMA-based unencapsulated device kept its average efficiency at 99% of its starting value despite being stored in N2 for 4,400 h. Additionally, compared to their 3D counterparts, light, thermal, environmental, and operational stabilities were all greatly increased.
Cl− ions have been shown to regulate DJ PVK growth and nucleation without interfering with the lattice [119,120,121]. Due to its volatile nature, it prefers to remain near the grain borders after post-annealing. The crystals are more homogeneous, and the crystal growth rate is lowered [122]. The consequence is larger grains and improved pinhole density in the film morphology. Finally, it improves the DJ cell's photovoltage capability.
3.3 Thiocyanate Anion Additive
PSC performance is greatly influenced by the surface abrasiveness, grain size, and homogenous coverage of the DJ perovskite absorber layer [41, 123, 124]. Although they have a high defect tolerance, organohalide lead perovskites are not defect-proof.
Li et al. [125] showed that recrystallization caused by ammonium thiocyanate (NH4SCN) may be used to enhance the shape and crystalline quality of PVK films (Fig. 6). The additive was largely dissolved when they created the (BDA)(MA)4Pb5I16 solution with NH4SCN, and the PbI2 compound then formed the mesoporous framework (intermediate film). The NH3 and HSCN that were created during the annealing process soon volatilized. Because of the large crystal grain sizes and reduced trap density, (BDA)(MA)4Pb5I16 produced by this intermediate catalytic action of NH4SCN had a higher PCE of 14.53%. The devices that were created also had good stability, retaining 85% under RH 50% ± 5% for 900 h. NH4SCN and MASCN have been used to enhance DJ PVK films' crystallinity and boost cell performance [3, 126]. The DJ PVK layer's grain size, material crystallinity, and optical properties may be improved by pseudo-halide [103, 127]. This manuscript examined a number of BDA-based 2D DJ perovskites. However, stability of some BDA-based 2D DJ perovskite devices was rather low in comparison with their counterparts of other types. Table 1 demonstrates that testing of 2D DJ PVK solar cells typically takes place in low humidity environments, N2 atmospheres, or in the absence of light.
2D (3-AMP) (MA0.75FA0.25)3Pb4I13 DJ perovskite layers were produced by Wu et al. [128] using a room temperature method and the MASCN additive. With the right number of additives, the perovskite layer displayed improved crystallinity, enhanced orientation growing, and fewer flaws. Planar-structured PSCs had the highest PCE of 16.25%. After 35 days of air storage at a RH of 45%, the unsealed cells still contained 80% of its initial efficiency.
A number of thiocyanate ions have been suggested as ways to regulate the crystal border (GB), charge carrier trapping, and defect tolerance in perovskite thin films. Wu et al. [129] produced (3AMP) (MA0.75FA0.25)3Pb4I13 films of excellent quality by adding MASCN to the precursor. When the centration is high enough, it is probable that SCN− outcompetes DMSO for coordination sites, reducing the interaction between Pb2+ ions and DMSO and facilitating easier DMSO elimination. Reduced fault density allowed for an exceptionally low energy loss and high VOC (1.24 V) (0.35 eV). A large PCE of 18.67% was present in a gadget. After storage in the open air, it retained 90% of its original PCE over 50 cycles of thermal cycling testing.
Halogen shares similar chemical characteristics and behaviors with pseudo-halides like SCN−. Yukta et al. [37] reported the eclipsed DJ perovskite employing the 1,5-diaminonaphthalene cation in Fig. 7a. In NDA-based DJ phase perovskite (NDA is 1,5-diaminonaphthalene), NH4SCN surface treatment increased carrier mobility, film shape, crystallinity, trap-assisted nonradiative recombination, and trap-assisted nonradiative recombination significantly decreased. Consequently, the efficiency of perovskite device treated with NH4SCN increased by over 46%, from 10.3% to 15.08%. The effectiveness of the devices treated with the NH4SCN addition was verified using electrochemical impedance spectroscopy [130, 131]. To date, many pseudo-halides have been incorporated onto DJ perovskite layer in order to change the processes for PVK crystal formation and passivate crystal defects, improving PSC performance.
Trans-1,4-cyclohexanediamine (CHDA)MA(3)Pb(4)I(13)(n = 4) was manufactured via Wang et al. [132] using NH4SCN as an addition. They showed that both cation and anion had synergistic effects on the perovskite layer's nucleation and growth, resulting in bigger grains and more stable layers. Less flaws were created, and the crystallization process took longer. The device generated astounding efficiency of up to 15.01%. The encased devices' efficiency remained at 80.7% over 270 min of continuous maximum power point monitoring. Devices manufactured maintained 96.5% and 74.4% efficiency during 68 h at 60 and 70 °C, respectively. One of the maximum stabilized efficiencies for a DJ phase perovskite has been informed by Yukta et al. [131] for (XDA)(MA)3(Pb)4(I)13 PVK (Fig. 7b). The ideal phase distribution, bigger grains, and better crystallinity are produced by the NH4SCN additive alteration. The passivated perovskite also demonstrated improved charge transport and decreased defect density.
The DJ PVK film has been passivated using the SCN− as an additive [133]. Inorganic perovskite Pb2+ may coordinate with the S and N atom donors found in thiocyanate to generate the Lewis acid–base adduct [93]. The SCN ions would cause the perovskite layer to emit gases in the form of methylamine (CH3NH2) and HSCN through the annealing procedure [57]. The emission of CH3NH2 gas during perovskite synthesis enhances the crystallinity and grain size of the layers [134].
3.4 Hydrohalic Acids Additive
The perovskite precursor solution is made up of colloids with an organic and inorganic lead polyhalide framework between them [60]. These colloids, that also behave as nucleation sites, control the coverage and form of the thin films that undergo deposition [34]. Large colloids cause poor film morphology [23]. Large colloid particles can be broken down by hydrohalic acids, and they can also change the colloidal concentration [38], which modifies DJ perovskite shape while it is being deposited. Ke et al. [135] discovered that adding a little quantity of HI to a precursor solution allowed for the structure of phase-pure, uniform, and continuous 3AMP (MA0.75FA0.25)3Pb4I13 layers. Particularly, 3AMP perovskites showed lower recombination, boosting the devices' FF and VOC. The ideal level of 25% FA was present in these perovskites. The solar cells therefore showed a 50% improvement over the original cells, producing a winner efficiency of 12.04% with a great FF of 81.04% and an efficiency of 9.83%. When the solvent-engineering technique is paired with hybrid DMF/DMSO solvent and HI additive, the films have a noticeably more desirable perpendicular orientation and greater crystalline quality, resulting in solar cells with outstanding repeatability and good presentation. Due to the hydrophobic nature of the organic spacer layer of the 3AMP cation, which increases the materials' resistance to moisture and light, these DJ PVK layer cells also demonstrated substantially greater environmental stability than their 2D-RP and 3D analogs.
The presentation of DJ PSCs as a device and the layer quality of DJ perovskites are both impacted by the aging of DJ perovskite precursors [136]. Controlling the colloid dispersion in the precursor is necessary to produce uniform films [52]. HI was used most frequently as an additive in the early stages of DJ PSC development. He et al. [100] fabricated dense (4-AMP)MAn−1PbnI3n+1 perovskite films by introducing HI to the (4-AMP)MAn−1PbnI3n+1 precursor in Fig. 8 (MAMP is 4-AMP in Figure). The addition of HI could make the (4-AMP)MAn−1PbnI3n+1 solution more soluble, increasing the surface coverage on the substrate. Furthermore, by meticulously controlling the crystallization kinetics using HI additive, 4-AMP film with a homogenous energy landscape was achieved. Electrical analyses proved that the homogenous energy landscape decreased defect density and lowered energy disorder in the film. Due to the homogenous energy environment, which reduces nonradiative recombination and energy disorder, little V loss was obtained. The solar cell had an impressive VOC of 1.21 V and a noteworthy efficiency of 16.53%. Due to its excellent vertical phase alignment, the device also has shown far more stability than normal hot-casting films, keeping around 90% of the fresh PCE after 1000 h of storage.
In contrast to neutral additives, the addition of acids may change how the molecules of the solvent interact and decrease the viscosity of the solution [11]. This alters the solvent's rate of evaporation and influences how quickly DJ PVK crystallizes. Li et al. developed exceptionally smooth and totally covering PVK layers with big crystalline grains at ambient temperature in this study [137]. The devices had a PCE of 9.20% (A'A(n-1)Pb(n)I(3n+1) (A' = 4-(aminomethyl)pyridinium (4AMPY), A = methylammonium (MA), n = 1–4)).
Acids can make DJ PVK precursors more soluble and aid in the production of DJ PVK films that are uniform and well-covered. Subsequently, Safdari et al. [138] used HI into [NH3(CH2)4NH3]PbI4 and successfully prepared stable cubic [NH3(CH2)4NH3]PbI4 films. It was shown that the stable black phase could only be created at low temperatures due to the smaller grains and lattice strain caused by HI. It was the first time that [NH3(CH2)4NH3]PbI4 was shown to be an alternate absorber, despite the fact that the PSCs only managed to attain a low PCE of 1.1%. Large colloidal particles in the perovskite precursor have been observed to dissolve when acidic additives are present, changing the shape of halide perovskite [117]. Safdari et al. [139] created thick, homogeneous perovskite films with greater surface coverage on the substrate by adding HI to the precursor solution, as an example. In compared to the reference model without the additive, the device's performance was prolonged when HI was introduced because it made the perovskite more soluble and produced dense layers. The greatest performance material below moisture environments was BDAPbI4 (1.08% PCE), that was equal to MAPbI3 solar cells (2.1% PCE). Both MAPbI3 and BDAPbI4 solar cells had an equivalent absorbed photon-to-current PCE, but the 2D PVK had wider band gaps and less photoconductivity.
Acidic-natured molecule additions have been shown to have a significant impact on the DJ perovskite shape [140] by encouraging the breakup of huge PVK particles into smaller ones with a more homogeneous dispersion of particles. Yu et al. [141] used the (PDMA)(MA)5Pb6I19 precursor solution to add HI acids to study the nucleation and development phases of perovskite layers. After the addition of acid, which caused the colloids in suspension to progressively disperse, the amount of tiny colloidal particles increased with longer aging times. Colloids are the nucleation centers, and this fact significantly influenced the crystallization kinetics and form of the thin layers. The density of nucleation sites was eventually reduced to produce huge grains and well-covering layers. Large crystal grains frequently came with unfavorable pinholes since crystal development might also proceed vertically. The best device was made with n = 6 in DJ perovskite, producing a PCE of up to 11%, which is remarkable.
As a result, the complete crystallization of those old precursors with acid additions required a higher temperature and longer time [122, 142]. The aged precursor produced a superior morphology with bigger grains, higher crystallinity, and better texture thanks to its smaller, more uniform colloidal particles [41, 143].
3.5 Tin (II) Fluoride Additive
Due to fluorine's small size and high electronegativity [17, 144], fluoride species can interact with DJ PVK to generate powerful ionic and intermolecular bonds [125, 145]. The beneficial chemical reaction between fluoride and DJ PVK allows for the passivation of crystal boundaries and surface defects [14]. Fluoride is frequently appeared on the surface of DJ perovskite when it is integrated into the film [1, 121], displaying surface hydrophobicity and shielding the DJ PVK from moisture erosion [79, 117, 146]. In order to decrease the inherent Sn-cation vacancies in DJ phases (BDA)FA2Sn3I10 perovskites, Li and colleagues initially employed Tin (II) fluoride (SnF2) [102]. Theoretical simulations show that the addition of SnF2 considerably increases the chemical potential of Sn and the energy needed to create Sn vacancies. Furthermore, (BDA)FA2Sn3I10 has a high degree of crystal symmetry, which leads to efficient carrier separation and absorption. They were able to attain a PCE up to 6.43%, that is significantly greater than that of the FASnI3 cell (4.20%), by taking advantage of outstanding film forming and carrier transport features. More significantly, compared to 3D FASnI3 devices, the (BDA)FA2Sn3I10 devices demonstrated greater resistance to oxidation, light, and humidity.
The quick oxidation of Sn2+ to Sn4+ in ambient air is one of the crucial reasons for the minimal PCE and bad long-term steadiness of tin DJ PSCs [38]. Therefore, reductive additives are included to lessen the oxidation process for improved device performance, such as the frequently utilized divalent tin halides and their additives [67] and hydrazine derivatives. In order to create novel materials of the type FASnI3 with SnF2 additive, Ke et al. [92] presented a novel kind of tin-based PVK absorber that combines [45] both ethylenediammonium (en) and FA. Studies show that the tin double halide (SnF2) protects the FASnI3 perovskite films by acting as both an antioxidant and a tin source compensator. The atmosphere steadiness and photoelectric characteristics of the tin-based PVK absorbers were also markedly enhanced by the insertion of the en cation into the architecture.
While F ion (as SnF2) is stoichiometrically injected into the ASnI3 DJ PVK to create an ASnI3-xFx DJ perovskite film, the tolerance factor, t, rises as x boosts due to the decreased F ionic radius and boosts the phase steadiness of Sn-based DJ perovskite [76]. The use of fluoride complex as an adjuvant consequently increased the stability of Sn-based DJ PVK. SnF2 was added by Ke et al. [147] to the perovskite solution to regulate the shape of DJ FASnI3 films. Propylenediammonium (PN) and trimethylenediammonium (TN) may both be incorporated into FASnI3 perovskite while still maintaining its three-dimensional structure and offering improved film shape and optoelectronic capabilities. It has been shown that adding SnF2 lowers background carrier density and Sn defects by increasing the Sn potential and lowering the energy required for the creation of Sn vacancies in lead-free PVK. Ma et al. [148] discovered that adding SnF2 to the precursor solution may create a homogeneous, thick, amorphous layer over the polycrystalline perovskite layer that would successfully obstruct oxygen and moisture from the outside while also reducing ion transport inside the devices. The layered 2D perovskite was made by mixing an organic cationic salt called hexamethylenediamine diiodide (HDAI) with FA tin iodide (FASnI3) PSCs.
Electron recombination can be decreased by interfacial engineering, the application of drugs in controlled dosages, or the adoption of HTL or ETL that may minimize cell recombination [24, 149]. When used as a single addition in DJ Sn-PSCs, SnF2 exhibits a superior response in this aspect [51]. According to Zhang et al. [150], the quasi-2D perovskite (PDMA) (FA0.7MA0.3)3(Pb0.5Sn0.5)4I13 (n = 4 phase) with SnF2 additive showed a blue-shifted absorption edge in Fig. 9 when compared to pure MASnI3 thin film. They established which the SnF2 additive represses the production of Sn4+ and significantly reduces the hole density (by 1–2 orders of magnitude). PSCs based on FA0.7MA0.3Pb0.5Sn0.5I3 films saw a considerable improvement in PCE and stability with the addition of a modest quantity of PDMADI. This method prevented Jsc deterioration, enhanced film crystallinity and shape, and allowed for a one order of magnitude decrease in defect density by not causing the bandgap to shift blue. The PSCs with 2D/3D bulk heterojunction Pb–Sn PVK finally achieved an enhanced efficiency of 20.5%.
SnF2 additive was utilized to improve phase stability [151]. In contrast to Pb2+, DJ PVK has a reduced bandgap when Sn2+ is used [65]; however, DJ PSCs exhibit instability and poor performance due to the phase change and rapid oxidation of Sn2+ to Sn4+ [152]. In order to make undoped (Sn4+ free) films with reduced defect concentration, Ke et al. [153] recommended that SnF2 simply function as an inhibitor of Sn2+ oxidation in the (3AMP)(MA0.5FA0.5)n-1(Pb0.5Sn0.5)nI3n+1 (n = 4) precursor solution. PVK films' shape was enhanced, and the crystallization process was changed using the SnF2 addition. The ionic radius of F is substantially less than that of I, hence F doping of iodide PVK won't cause any appreciable changes to the lattice parameter or undesirable film phases. As a consequence, solar cells utilizing 2D 3AMP and 3D perovskite composites as light absorbers were more efficient and stable, with a 20.09% power conversion efficiency. According to reports, tin fluoride (SnF2) protects the ASnX3 perovskite films by acting as both an antioxidant and a tin source compensator.
3.6 Other Additives
The functionality of DJ PSCs is considerably affected via the shape of perovskite films [154, 155]. The uniformity, coverage, and roughness of a surface are all influenced by the size and distribution of the grains, the texture, and pinholes in the films [156, 157]. The optimal situation is that PVK form a single crystal sheet on the substrate [105, 158, 159]. The nucleation, growth, and post-treatment stages of crystallization, as well as the coarsening or ripening process, can all be controlled to optimize the morphology [160]. For DJ perovskite films, additional chemicals, such as too much PbI2, are chosen and used. A surplus of formamidinium iodide can passivate the GBs (FAI). By creating self-assembled GBs on the ((PDA)(FA)x(MA)3-xPb4I13 film, Ahmad et al. [161] chose the excess FAI to influence the grain surface of the PVK layers, resulting in better PVK performance and reduced hysteresis of PSCs in Fig. 10. DJ 2D perovskite with 10% FA+ doping has superior crystallinity, a preference for vertical orientation, and a lengthier charge carrier life than DJ 2D perovskite with no FA+. The 2D PSCs demonstrated an improved device stability and a champion PCE of 14.74%. After 6000 h of storing at a RH 65%, 800 h of exposure to warm at 85 °C, and 5000 h to one sun's light, the cells still hold more than 92%. These results imply that the DJ perovskite may be modified to produce extremely effective and steady DJ PSCs via the addition of FA cation.
Su et al. have disclosed [162] an additive method used for producing good DJ perovskite films devoid of MA, in which molecules of 1,1′-carbonyldi(1,2,4-triazole) (CDTA) are added to the PVK solution. Through CDTA adjustment, it is possible to change the distribution of phases, grain volume, crystallinity, crystal orientation, defect passivation. A further advantageous gradient phase distribution and subsequently gradient band alignment are produced, that is advantageous for carrier extraction and transport. The enhanced crystal orientation can make collecting and transporting carriers easier. As a result of the larger grain size and effective defect passivation, the trap density decreased. The result was a PCE of 16.07% from the CDTA-modified device. The cell retains 92% under irradiation and 86% of its original PCE after 360 h at 60 °C.
Additionally, Chen [163] demonstrated in Fig. 11 the scalable printing of superior DJ perovskite thin films by adjusting crystallization kinetics. The standard DMF:DMSO-based precursor may be significantly delayed in crystallizing when a small quantity of 1-methyl-2-pyrrolidinone is added. This made it feasible for rapid interphase charge transfer. The winning perovskite cell generated a stable PCE of 16.19%. Additionally, thanks to their exceptional phase stability, the devices made with the ternary solvent displayed a noticeably improved stability when exposed to stimuli like light, heat, and humidity.
Due to its environmentally friendly, non-toxic, and superior photoelectric physical features, tin-based perovskite has received much research [103, 164]. The great sensitivity of Sn2+ cations to oxygen and moisture, however, posed a significant obstacle to creating robust solar cells [165]. Guo [166] discovered that the 4-(aminomethyl) pyridine (4AMPY) cation may be added to create the DJ perovskite 4AMPYSnX4. In the beginning, modulation of the halogen component improves charge transfer efficiency. The efficiency of charge transfer was further improved. In the end, they succeeded in fabricating good DJ PSCs with the best PCE of 5.03%. During 200 h of observing the functionality of unencapsulated devices in an ambient air (RH = 30%, T = 25 °C), there was no discernible PCE decline.
The fundamental problem preventing PSCs from being commercialized is volatility of performance under high RH [167], light exposure, and heat [104]. Lead halide perovskite quantum dots (QDs) [168, 169], that passivate the GBs and improve the crystallinity of the PVK [170], have been reported to improve the presentation of PSCs. To increase PCE of PSC devices, carbon quantum dots have proven to be effective perovskite absorber additions [171, 172]. Because of great charge carrier mobility and excellent transmittance over whole visible light spectrum, quantum dots are good-looking for photovoltaic devices. To control the crystallization of 2D PVSs, Li and colleagues [120] created a form of C3N QDs containing ordered carbon and nitrogen atoms. They caused the crystallization procedure, phase organization, and morphology to improve (Fig. 12). The QDs allowed for the creation of electron-rich regions to adsorb large organic cations and afford nucleation sites to achieve a bi-directional crystallization procedure. Combining theoretical modeling, morphological control, and femtosecond transient absorption characterization analysis allowed for this. Meanwhile, improved surface potential, compact topology, and decreased trap density all contributed to the improvement in 2D DJ film quality.
Salts called ionic liquids (Ils) are in liquid under 100 °C and are made up of massive organic cations and a variety of organic or inorganic anions. As a result of the strong interionic electrostatic force, they are practically nonvolatile. Normal IL properties include excellent thermal and electrochemical stability, as well as high ionic conductivity. A variety of chemical and inorganic substances can also be dissolved by ILs. By choosing various cation and anion combinations and permutations, you may make various binary and ternary ionic liquids. In newly developed quasi-2D-DJ phased PVK of (PDA)MA4Pb5I16 perovskite absorber, Ma et al. [173] used IL 1-butyl-3-methylimidazolium tetrafluoroborate (BMIMBF4) as an additive. The interaction between BMIM+ and perovskite also enabled a reduction in defect density, a suppression of ion motion, and improvements in film form and crystal quality. When the BMIMBF4 was introduced to the PVK, ion migration in the PVK layers was dramatically decreased. In order to prevent ions from migrating by intensifying chemical interactions in the vicinity, fluoride additive has only lately been utilized. In comparison with the control devices, which had an ideal PCE of 12.45%, the PSCs had a 14.07% PCE. Additionally, BMIMBF4 significantly increased the heat steadiness of the PSCs. The efficiency of the cells containing BMIMBF4 provides 72% of the original value after 120 h of heating at 85 °C, though efficiency of the control cells reduces to 19% of the initial value. The increase in performance was correlated with the benefits of employing IL BMIMBF4, including bigger grains, improved energy alignment at interfaces, and restricted ion migration.
Li and his colleagues [110] successfully developed the application of double organic ammonium salts with the same chain length (BAI and BDAI2). In contrast to using monoammonium BAI, they discovered that the BDA successfully decreases defect density and generates a 2D-DJ composition to improve interfacial charge extraction and prevent surface charge recombination. The outcome was an increased efficiency of 18.34%. It is common to attribute the enhanced stability to the massive organic cations that produce 2D constructions.
Ahmad [174] reported several DJ 2D perovskites that were cesium-doped (PDA = 1,3-propanediammonium) and explored the impact of cesium doping on characteristics and cell presentations. The 5% Cs-doped cells have a highest PCE of 18.30%, which is greater than the equivalent with no doping. Unencapsulated cells also show extraordinary stability, maintaining 95% of original efficiency after 5000 h of nonstop irradiation by one son, 240 h of moist heat at 85 °C and 95% RH, and 1000 h of MPP monitoring. The Cs doping's effects on improved film form, crystallographic orientation, lengthier charge carrier life, and decreased nonradiative recombination are responsible for the higher efficiency and stability. This study demonstrates that making extremely efficient and stable 2D PSCs is as easy and effective as adding Cs to DJ 2D perovskites.
Huang [175] learned the solvent function on layer generation and defect states of DJ PVK with methylammonium acetate (MAAc). It is studied that the nucleation procedure of DJ PVK can be blocked by extra coordination, that is evidenced by in situ optical spectra. As a result, out-of-plane oriented crystallization and ordered phase distribution are achieved. The thiourea (TU) [176] is positively utilized to make great efforts in optimizing the crystallization development, resulting in an increased grain size, flat and dense surface structure, and controlled delivery of n values for enhanced phase purity (Fig. 13).
These findings suggest that using additives is a viable method for creating DJ PSCs that are effective, stable, and free of hysteresis. There are differences between the introduction and existing forms of additives for DJ PSCs. Prior to the manufacture of the film, certain additives are added to the precursor, and others are added to the film after post-processing [127, 177]. After the creation of the devices, certain additives are eliminated while others are left in the finished products. For the remaining ones, some develop within the crystal, while others do so at edges, surfaces, or interfaces [110].
4 Conclusion and Outlook
4.1 Conclusion
We have shown that to produce effective, stable, and hysteresis-free 2D-DJ PSCs, additives have a great deal of promise and are frequently used. We have reviewed and described the various additives used for 2D-DJ PSCs. The geomorphology of perovskite layers is modulated via additives through changes in colloid size in the solution, formation of intermediates for nucleation, templating growing on substrates, causing coarsening of crystal size, and suppression of solution flow. This enables quick deposition techniques for more DJ perovskite layers. Additionally, nonradiative recombination may be avoided, ion migration can be suppressed, and DJ perovskite can be protected from harm by the coordination of additives by an ionic or other bonding at grain boundaries or on surfaces. This would boost VOC, eliminate hysteresis, and significantly enhance operating stability.
Three processes make up the DJ-phase multilayer perovskite crystallization process: (a) disordered colloidal sol–gel; (b) an oriented 3D-like phase; and (c) oriented 2D phase. The film-formation process of DJ-phase-layered perovskite is directly connected to the precursor in the first stage, which is also referred to as the intermediate stage. By creating intermediates between solvent molecules and PbI2, it is possible to prevent the quick crystallization of DJ-phase multilayer perovskite, which results in unpredictable orientation. The intermediate serves as a framework to make it easier to build perovskite QW because it progressively releases PbI2 to produce the perovskite phase as a result of the solvent evaporating during the annealing procedure. The creation of a 3D-like PVK phase at the gas–liquid interface, a crucial step, is subordinated in the second stage to the crystallization of the DJ-phase-layered PVK precursor. The desired orientation must be obtained with the constraint that the process is not interrupted. Additionally, whether preferred crystallization occurs inside the liquid or from the liquid–solid boundary, it is more likely to take on a random direction. Therefore, the secret to getting the desirable orientation in DJ-phase multilayer perovskites is managing the crystallization process. The DJ-phase-layered perovskite eventually expands and is preferentially orientated until the crystallization process is complete in the third step. In DJ-phase-layered perovskites, additive engineering can improve the nucleation and crystallization kinetics, resulting in the creation of crystals with well-defined shapes and sizes.
A fundamental concept is morphology. Making DJ perovskite precursor an actual solution would be intriguing for creating additive-assisted techniques for creating perovskite films that resemble single crystals or are highly oriented. Once the DJ film has attained a high level of quality and the grain boundaries are perpendicular to the base, it might be possible to develop additives to passivate the defects at the grain boundaries and shield them from deterioration by sturdy bonds for greater PCE and steadiness with no losing charge transport ability in one grain. Additionally, for those additives that are still found in DJ perovskite films, a detailed investigation of their effects on DJ perovskite energy level structure and energy level bending at interfaces is necessary to appreciate how these effects influence efficiency and hysteresis. DJ PSCs' device stability and efficiency may also be increased by adding the appropriate electrodes, interfacial modifiers, and charge-transport layers. Functional additives may be particularly created to passivate the faults in interfacial traps and DJ perovskite layers, which has shown to be a useful method to reduce energy loss and improve DJ PSC performance.
4.2 Outlook
A few in situ characterization approaches are useful for completely understanding how the additives affect DJ perovskite crystallization, despite the fact that many groups have looked into the potential processes of additive-engineered DJ perovskite formation. To guide the creation of efficient additives, we must first get a fundamental understanding of how the different DJ perovskite materials' defect types and densities impact electrical transport properties. It is important to carefully examine the impacts and capabilities of additives with different molecular constructions. Consistent characterization methods should also be developed in order to precisely examine how additives affect the performance and stability of DJ PSCs. The development of a molecular library may result from research into how functional groups, conjugated systems, and extra substituents affect the passivation capacity. Once research data has been collected and analyzed, machine learning may be used to determine the fundamental concepts for selecting materials and improving technologies. The development of a molecular library might possibly result from research into the effects of functional groups, conjugated systems, and the extra substituent on the passivation capacity. Once research data has been collected and shared throughout the whole research community, we may apply machine learning to find the basic theories for choosing materials and improving equipment.
Although great advances in DJ perovskite have been made in recent years by using additive compounds, based on their original physicochemical and chemical advantages, numerous challenges such as a complex preparation process, low reproducibility, and toxicological safety remain for commercial application.
Although some challenges remain, additive compounds have increasingly been shown to be capable of preparing and improving DJ PSCs. A large variety of other optoelectronic devices, for example light-emitting diodes (LED), transistors, photodetectors, and lasers, as well as PSCs, still need to be constructed utilizing 2D DJ perovskites. A lengthy operational lifespan under ambient circumstances is envisaged in the future. Due to the 2D DJ perovskites' unique charge-transport capabilities along the in-plane and out-of-plane directions, careful examination in this area is necessary to further research into a variety of optoelectronic applications based on these materials.
The performance and stability of DJ perovskites can be enhanced using additive engineering, which is becoming more and more clear as a technique. The evaluation is anticipated to spur more efforts to support the usage of additive compounds in high-performing DJ perovskite systems, which can be applied for outstanding optoelectronic devices. The review is expected to pave the way for these key areas and stimulate more research to promote the use of additive engineering in excellent DJ perovskite optoelectronic device systems.
References
B. Dahal, W. Li, Configuration of methylammonium lead iodide perovskite solar cell and its effect on the device’s performance: a review. Adv. Mater. Interfaces 9(19), 2200042 (2022). https://doi.org/10.1002/admi.202200042
Q. Dou, T. Whatley, T. Syed, W. Wei, H. Wang, Carbon nanomaterials-polymer composites for perovskite solar cells: preparation, properties and applications. J. Mater. Chem. A 10(37), 19211–19230 (2022). https://doi.org/10.1039/d2ta02175g
E.C. Kohlrausch, D.d.V. Freitas, C.I. da Silva Filho, L.F. Loguercio, L.A. Santa-Cruz et al., Advances in carbon materials applied to carbon-based perovskite solar cells. Energy Technol. 2200676 (2023). https://doi.org/10.1002/ente.202200676
X. Luo, X. Lin, F. Gao, Y. Zhao, X. Li et al., Recent progress in perovskite solar cells: from device to commercialization. Sci. China-Chem. 65(12), 2369–2416 (2022). https://doi.org/10.1007/s11426-022-1426-x
D. Sharma, R. Mehra, B. Raj, Comparative study of hole transporting layers commonly used in high-efficiency perovskite solar cells. J. Mater. Sci. 57(45), 21172–21191 (2022). https://doi.org/10.1007/s10853-022-07958-3
F. Zhu, G. Lian, B.C. Yu, T. Zhang, L. Zhang et al., Pressure-enhanced vertical orientation and compositional control of Ruddlesden-Popper perovskites for efficient and stable solar cells and self-powered photodetectors. ACS Appl. Mater. Interfaces 14(1), 1526–1536 (2022). https://doi.org/10.1021/acsami.1c18522
D.M. Zheng, C. Schwob, Y. Prado, Z. Ouzit, L. Coolen et al., How do gold nanoparticles boost the performance of perovskite solar cells? Nano Energy 94, 106934 (2022). https://doi.org/10.1016/j.nanoen.2022.106934
D. Zheng, F. Raffin, P. Volovitch, T. Pauporte, Control of perovskite film crystallization and growth direction to target homogeneous monolithic structures. Nat. Commun. 13(1), 6655 (2022). https://doi.org/10.1038/s41467-022-34332-3
C. Liang, H. Gu, Y.D. Xia, Z. Wang, X.T. Liu et al., Two-dimensional Ruddlesden-Popper layered perovskite solar cells based on phase-pure thin films. Nat. Energy 6(1), 38 (2021). https://doi.org/10.1038/s41560-020-00721-5
Z.Q. Li, J.J. Dong, C.Y. Liu, J.X. Guo, L. Shen et al., Surface passivation of perovskite solar cells toward improved efficiency and stability. Nano-Micro Lett. 11(1), 50 (2019). https://doi.org/10.1007/s40820-019-0282-0
Y.W. Jang, S. Lee, K.M. Yeom, K. Jeong, K. Choi et al., Intact 2D/3D halide junction perovskite solar cells via solid-phase in-plane growth. Nat. Energy 6(1), 63 (2021). https://doi.org/10.1038/s41560-020-00749-7
Q. Dai, Q. Ling, L. Huang, X. Liu, H. Zhang et al., Regulating radial morphology in hot-casting two-dimensional ruddlesden-popper perovskite film growth for high-efficient photovoltaics. ACS Appl. Energy Mater. 6(3), 1585–1594 (2023). https://doi.org/10.1021/acsaem.2c03458
P. Li, L. Yan, Q. Cao, C. Liang, H. Zhu et al., Dredging the charge-carrier transfer pathway for efficient low-dimensional ruddlesden-popper perovskite solar cells. Angew. Chem. Int. Ed. 62(13), e202217910 (2023). https://doi.org/10.1002/anie.202217910
J.S. Du, D. Shin, T.K. Stanev, C. Musumeci, Z. Xie et al., Halide perovskite nanocrystal arrays: multiplexed synthesis and size-dependent emission. Sci. Adv. 6(39), eabc4959 (2020). https://doi.org/10.1126/sciadv.abc4959
W.J. Zhao, J. Xu, K. He, Y. Cai, Y. Han et al., A special additive enables all cations and anions passivation for stable perovskite solar cells with efficiency over 23%. Nano-Micro Lett. 13(1), 169 (2021). https://doi.org/10.1007/s40820-021-00688-2
J. Xu, J. Chen, S. Chen, H. Gao, Y. Li et al., Organic spacer engineering of ruddlesden-popper perovskite materials toward efficient and stable solar cells. Chem. Eng. J. 453(1), 139790 (2023). https://doi.org/10.1016/j.cej.2022.139790
N. Zhou, H.P. Zhou, Spacer organic cation engineering for quasi-2D metal halide perovskites and the optoelectronic application. Small Struct. 3(7), 2100232 (2022). https://doi.org/10.1002/sstr.202100232
L.F. Yan, J.J. Ma, P.W. Li, S.Q. Zang, L.Y. Han et al., Charge-carrier transport in quasi-2D Ruddlesden-Popper perovskite solar cells. Adv. Mater. 34(7), 2106822 (2022). https://doi.org/10.1002/adma.202106822
J.M. Hoffman, C.D. Malliakas, S. Sidhik, I. Hadar, R. McClain et al., Long periodic ripple in a 2D hybrid halide perovskite structure using branched organic spacers. Chem. Sci. 11(44), 12139–12148 (2020). https://doi.org/10.1039/d0sc04144k
L.L. Xu, G.Y. Liu, H.Y. Xiang, R. Wang, Q.S. Shan et al., Charge-carrier dynamics and regulation strategies in perovskite light-emitting diodes: from materials to devices. Appl. Phys. Rev. 9(2), 021308 (2022). https://doi.org/10.1063/5.0080087
T. Zhu, D.M. Zheng, J.W. Liu, L. Coolen, T. Pauporte, Peai-based interfacial layer for high-efficiency and stable solar cells based on a macl-mediated grown FA(0.94)MA(0.06)PbI(3) perovskite. ACS Appl. Mater. Interfaces 12(33), 37197–37207 (2020). https://doi.org/10.1021/acsami.0c09970
Z.Y. Xu, L. Li, X.Y. Dong, D. Lu, R. Wang et al., CsPbl(3)-based phase-stable 2D Ruddlesden-Popper perovskites for efficient solar cells. Nano Lett. 22(7), 2874–2880 (2022). https://doi.org/10.1021/acs.nanolett.2c00002
P. Acharyya, T. Ghosh, K. Pal, K. Kundu, K.S. Rana et al., Intrinsically ultralow thermal conductivity in Ruddlesden-Popper 2D perovskite Cs2PbI2Cl2: localized anharmonic vibrations and dynamic octahedral distortions. J. Am. Chem. Soc. 142(36), 15595–15603 (2020). https://doi.org/10.1021/jacs.0c08044
M.D. Malouangou, Y.F. Yang, Y.J. Zhang, L.Y. Bai, J.T. Matondo et al., Recent progress in perovskite materials using diammonium organic cations toward stable and efficient solar cell devices: Dion–Jacobson. Energy Technol. 10(5), 2101155 (2022). https://doi.org/10.1002/ente.202101155
Y. Zhang, M. Chen, T. He, H. Chen, Z. Zhang et al., Long. Highly efficient and stable FA-based quasi-2D Ruddlesden-Popper perovskite solar cells by the incorporation of beta-fluorophenylethanamine cations. Adv. Mater. e2210836 (2023). https://doi.org/10.1002/adma.202210836
M.C. Shih, H.C. Hsu, C.C. Lin, S.K. Huang, T.P. Chen et al., Atomically resolved quantum-confined electronic structures at organic-inorganic interfaces of two-dimensional Ruddlesden-Popper halide perovskites. Nano Lett. 21(19), 8066–8072 (2021). https://doi.org/10.1021/acs.nanolett.1c02409
N.L. Chen, X.H. Yi, J. Zhuang, Y.Z. Wei, Y.Y. Zhang et al., An efficient trap passivator for perovskite solar cells: Poly(propylene glycol) bis(2-aminopropyl ether). Nano-Micro Lett. 12(1), 177 (2020). https://doi.org/10.1007/s40820-020-00517-y
M. Chen, Z. Shan, X. Dong, S.F. Liu, Z. Xu, Discovering layered lead-free perovskite solar absorbers via cation transmutation. Nanoscale Horiz. (2023). https://doi.org/10.1039/d2nh00499b
W. Deng, F. Wan, X. Peng, X. Ren, J. Wang et al., Super hydrophilic, ultra bubble repellent substrate for pinhole free Dion–Jacobson perovskite solar cells. Appl. Phys. Lett. 121(23), (2022). https://doi.org/10.1063/5.0127262
N. Li, Y.F. Yang, Z.H. Shi, Z.G. Lan, A. Arramel et al., Shedding light on the energy applications of emerging 2D hybrid organic-inorganic halide perovskites. Iscience 25(2), 103753 (2022). https://doi.org/10.1016/j.isci.2022.103753
F. Cheng, J. Zhang, T. Pauporte, Chlorides, other halides, and pseudo-halides as additives for the fabrication of efficient and stable perovskite solar. Chemsuschem 14(18), 3665–3692 (2021). https://doi.org/10.1002/cssc.202101089
D.M. Zheng, T. Pauporte, Control of the quality and homogeneity of halide perovskites by mixed-chloride additives upon the film formation process. J. Mater. Chem. A 9(33), 17801–17811 (2021). https://doi.org/10.1039/d1ta04651a
L.L. Gao, X.T. Li, B. Traore, Y.L. Zhang, J. Fang et al., M-phenylenediammonium as a new spacer for Dion–Jacobson two-dimensional perovskites. J. Am. Chem. Soc. 143(31), 12063–12073 (2021). https://doi.org/10.1021/jacs.1c03687
Y.P. Fu, X.Y. Jiang, X.T. Li, B. Traore, I. Spanopoulos et al., Cation engineering in two-dimensional Ruddlesden-Popper lead iodide perovskites with mixed large a-site cations in the cages. J. Am. Chem. Soc. 142(8), 4008–4021 (2020). https://doi.org/10.1021/jacs.9b13587
R.L.Z. Hoye, J. Hidalgo, R.A. Jagt, J.P. Correa-Baena, T. Fix et al., The role of dimensionality on the optoelectronic properties of oxide and halide perovskites, and their halide derivatives. Adv. Energy Mater. 12(4), 2100499 (2022). https://doi.org/10.1002/aenm.202100499
X. Guo, Y. Gao, F. Long, L. Lin, Y. Wang et al., The interplay of organic spacers and small cations for efficient Dion–Jacobson perovskite solar cells. Sol. RRL 2201021 (2023). https://doi.org/10.1002/solr.202201021
Yukta, R.D. Chavan, D. Prochowicz, P. Yadav, M.M. Tavakoli et al., Thiocyanate-passivated diaminonaphthalene-incorporated Dion–Jacobson perovskite for highly efficient and stable solar cells. ACS Appl. Mater. Interfaces 14(1), 850–860 (2022). https://doi.org/10.1021/acsami.1c19546
H.H. Yao, G.Q. Peng, Z.Z. Li, Q. Wang, Y.K. Xu et al., Fine coverage and uniform phase distribution in 2D (PEA)(2)Cs3Pb4I13 solar cells with a record efficiency beyond 15%. Nano Energy 92, 106790 (2022). https://doi.org/10.1016/j.nanoen.2021.106790
H.M. Xiang, P.Y. Liu, R. Ran, W. Wang, W. Zhou et al., Two-dimensional Dion–Jacobson halide perovskites as new-generation light absorbers for perovskite solar cells. Renew. Sust. Energ. Rev. 166, 112614 (2022). https://doi.org/10.1016/j.rser.2022.112614
X.J. Wang, Y. Zhao, L. Bin, X.F. Han, Z.M. Jin et al., Interfacial modification via a 1,4-butanediamine-based 2D capping layer for perovskite solar cells with enhanced stability and efficiency. ACS Appl. Mater. Interfaces 14(20), 22879–22888 (2022). https://doi.org/10.1021/acsami.1c21036
J. Lu, T.H. Yang, T.Q. Niu, N. Bu, Y.L. Zhang et al., Formamidinium-based Ruddlesden-Popper perovskite films fabricated via two-step sequential deposition: quantum well formation, physical properties and film-based solar cells. Energy Environ. Sci. 15(3), 1144–1155 (2022). https://doi.org/10.1039/d1ee02851k
R. Shi, R. Long, W.-H. Fang, O.V. Prezhdo, Rapid interlayer charge separation and extended carrier lifetimes due to spontaneous symmetry breaking in organic and mixed organic-inorganic Dion–Jacobson perovskites. J. Am. Chem. Soc. 145(9), 5297–5309 (2023). https://doi.org/10.1021/jacs.2c12903
Ul Haq, G. Rehman, I. Ahmad, H.A. Yakout, I. Khan, Lead-free Dion–Jacobson halide perovskites CsMX2Y2 (M = Sb, Bi and x, y = Cl, Br, I) used for optoelectronic applications via first principle calculations. J. Phys. Chem. Solids 174, 111157 (2023). https://doi.org/10.1016/j.jpcs.2022.111157
A. Ummadisingu, A. Mishra, D.J. Kubicki, T. LaGrange, A. Ducinskas et al., Multi-length scale structure of 2D/3D Dion–Jacobson hybrid perovskites based on an aromatic diammonium spacer. Small 18(5), 2104287 (2022). https://doi.org/10.1002/smll.202104287
L. Gollino, T. Pauporte, Lead-less halide perovskite solar cells. Sol. RRL 5(3), 2000616 (2021). https://doi.org/10.1002/solr.202000616
Q. Sun, Z. Fang, Y.P. Zheng, Z.B. Yang, F. Hu et al., Regulating the phase stability and bandgap of quasi-2D Dion–Jacobson CsSnI3 perovskite via intercalating organic cations. J. Mater. Chem. A 10(8), 3996–4005 (2022). https://doi.org/10.1039/d1ta10246j
Z.F. Shi, Z.Y. Ni, J.S. Huang, Direct observation of fast carriers transport along out-of-plane direction in a Dion–Jacobson layered perovskite. ACS Energy Lett. 7(3), 984–987 (2022). https://doi.org/10.1021/acsenergylett.2c00098
J. Xi, J. Byeon, U. Kim, K. Bang, G.R. Han et al., Abnormal spatial heterogeneity governing the charge-carrier mechanism in efficient Ruddlesden-Popper perovskite solar cells. Energy Environ. Sci. 14(9), 4915–4925 (2021). https://doi.org/10.1039/d1ee00984b
P. Kour, M.C. Reddy, S. Pal, S. Sidhik, T. Das et al., An organic-inorganic perovskitoid with zwitterion cysteamine linker and its crystal-crystal transformation to Ruddlesden-Popper phase. Angew. Chem. Int. Ed. 60(34), 18750–18760 (2021). https://doi.org/10.1002/anie.202105918
J. Gong, M.W. Hao, Y.L. Zhang, M.Z. Liu, Y.Y. Zhou, Layered 2D halide perovskites beyond the Ruddlesden-Popper phase: tailored interlayer chemistries for high-performance solar cells. Angew. Chem. Int. Ed. 61(10), e202112022 (2022). https://doi.org/10.1002/anie.202112022
Y.-C. Liu, J.-T. Lin, Y.-L. Lee, C.-M. Hung, T.-C. Chou et al., Recognizing the importance of fast nonisothermal crystallization for high-performance two-dimensional Dion–Jacobson perovskite solar cells with high fill factors: a comprehensive mechanistic study. J. Am. Chem. Soc. 144(33), 14897–14906 (2022). https://doi.org/10.1021/jacs.2c06342
M. Shao, T. Bie, L. Yang, Y. Gao, X. Jin et al., Over 21% efficiency stable 2d perovskite solar cells. Adv. Mater. 34(1), e2107211 (2022). https://doi.org/10.1002/adma.202107211
S. Chen, G.Q. Shi, Two-dimensional materials for halide perovskite-based optoelectronic devices. Adv. Mater. 29(24), 1605448 (2017). https://doi.org/10.1002/adma.201605448
J. Wu, H. Zeng, Y. Li, Z. Jiang, C. Liu, J. Zhang et al., Tailoring two-dimensional ruddlesden-popper perovskite via 1D perovskitoid enables efficient and stable solar cells. ACS Energy Lett. 8(1), 637–646 (2022). https://doi.org/10.1021/acsenergylett.2c02373
F.U. Kosasih, C. Ducati, Attaining high photovoltaic efficiency and stability with multidimensional perovskites. Chemsuschem 11(24), 4193–4202 (2018). https://doi.org/10.1002/cssc.201801905
C. Liang, D.D. Zhao, Y. Li, X.J. Li, S.M. Peng et al., Ruddlesden-Popper perovskite for stable solar cells. Energy Environ. Sci. 1(4), 221–231 (2018). https://doi.org/10.1002/eem2.12022
L. Cheng, Z. Liu, S.D. Li, Y.F. Zhai, X. Wang et al., Highly thermostable and efficient formamidinium-based low-dimensional perovskite solar cells. Angew. Chem. Int. Ed. 60(2), 856–864 (2021). https://doi.org/10.1002/anie.202006970
L.N. Quan, F.P.G. de Arquer, R.P. Sabatini, E.H. Sargent, Perovskites for light emission. Adv. Mater. 30(45), 1801996 (2018). https://doi.org/10.1002/adma.201801996
X.P. Gao, X.T. Zhang, W.X. Yin, H. Wang, Y. Hu et al., Ruddlesden-Popper perovskites: synthesis and optical properties for optoelectronic applications. Adv. Sci. 6(22), 1900941 (2019). https://doi.org/10.1002/advs.201900941
X.Q. Jiang, J.F. Zhang, S. Ahmad, D.D. Tu, X. Liu et al., Dion–Jacobson 2D-3D perovskite solar cells with improved efficiency and stability. Nano Energy 75, 104892 (2020). https://doi.org/10.1016/j.nanoen.2020.104892
A. Leblanc, N. Mercier, M. Allain, J. Dittmer, V. Fernandez et al., Lead- and iodide-deficient (CH(3) NH(3) )PbI(3) (d-MAPI): the bridge between 2D and 3D hybrid perovskites. Angew. Chem. Int. Ed. 56(50), 16067–16072 (2017). https://doi.org/10.1002/anie.201710021
A. Krishna, S. Gottis, M.K. Nazeeruddin, F. Sauvage, Mixed dimensional 2D/3D hybrid perovskite absorbers: the future of perovskite solar cells? Adv. Funct. Mater. 29(8), 1806482 (2019). https://doi.org/10.1002/adfm.201806482
P. Fu, Y. Liu, S.W. Yu, H. Yin, B.W. Yang et al., Dion–Jacobson and Ruddlesden-Popper double-phase 2D perovskites for solar cells. Nano Energy 88, 106249 (2021). https://doi.org/10.1016/j.nanoen.2021.106249
F.A. Roghabadi, M. Alidaei, S.M. Mousavi, T. Ashjari, A.S. Tehrani et al., Stability progress of perovskite solar cells dependent on the crystalline structure: from 3D ABX(3) to 2D Ruddlesden-Popper perovskite absorbers. J. Mater. Chem. A 7(11), 5898–5933 (2019). https://doi.org/10.1039/c8ta10444a
G.B. Wu, T.H. Yang, X. Li, N. Ahmad, X.N. Zhang, S.L. Yue et al., Molecular engineering for two-dimensional perovskites with photovoltaic efficiency exceeding 18%. Matter 4(2), 582–599 (2021). https://doi.org/10.1016/j.matt.2020.11.011
X.X. Tian, Y.Z. Zhang, R.K. Zheng, D. Wei, J.Q. Liu, Two-dimensional organic-inorganic hybrid Ruddlesden-Popper perovskite materials: preparation, enhanced stability, and applications in photodetection. Sustain. Energy Fuels 4(5), 2087–2113 (2020). https://doi.org/10.1039/c9se01181a
P.P. Sun, D.R. Kripalani, W.J. Chi, S.A. Snyder, K. Zhou, High carrier mobility and remarkable photovoltaic performance of two-dimensional Ruddlesden-Popper organic-inorganic metal halides (PA)(2)(MA)(2)M3I10 for perovskite solar cell applications. Mater. Today 47, 45–52 (2021). https://doi.org/10.1016/j.mattod.2021.02.007
J. Xi, I. Spanopoulos, K. Bang, J. Xu, H. Dong et al., Alternative organic spacers for more efficient perovskite solar cells containing Ruddlesden-Popper phases. J. Am. Chem. Soc. 142(46), 19705–19714 (2020). https://doi.org/10.1021/jacs.0c09647
Y. Zhao, F. Ma, F. Gao, Z.G. Yin, X.W. Zhang et al., Research progress in large-area perovskite solar cells. Photonics Res. 8(7), A1–A15 (2020). https://doi.org/10.1364/prj.392996
L.L. Gao, J.X. You, S.Z. Liu, Superior photovoltaics/optoelectronics of two-dimensional halide perovskites. J. Energy Chem. 57, 69–82 (2021). https://doi.org/10.1016/j.jechem.2020.08.0222095-4956/
M.S. de Holanda, R.F. Moral, P.E. Marchezi, F.C. Marques, A.F. Nogueira, Layered metal halide perovskite solar cells: a review from structure-properties perspective towards maximization of their performance and stability. Ecomat 3(4), e12124 (2021). https://doi.org/10.1002/eom2.12124
X. Bao, Y. Gao, Y. Liu, Z. Xu, F. Zhang et al., Molecular bridging strategy enables high performance and stable quasi-2D perovskite light-emitting devices. ACS Energy Lett. 8(2), 1018–1025 (2023). https://doi.org/10.1021/acsenergylett.2c02877
W. Guo, Z. Yang, J.L. Dang, M.Q. Wang, Progress and perspective in Dion–Jacobson phase 2D layered perovskite optoelectronic applications. Nano Energy 86, 106129 (2021). https://doi.org/10.1016/j.nanoen.2021.106129
X.T. Li, J.M. Hoffman, M.G. Kanatzidis, The 2D halide perovskite rulebook: how the spacer influences everything from the structure to optoelectronic device efficiency. Chem. Rev. 121(4), 2230–2291 (2021). https://doi.org/10.1021/acs.chemrev.0c01006
P.Y. Liu, N. Han, W. Wang, R. Ran, W. Zhou et al., High-quality Ruddlesden-Popper perovskite film formation for high-performance perovskite solar cells. Adv. Mater. 33(10), 2002582 (2021). https://doi.org/10.1002/adma.202002582
J.V. Milic, S.M. Zakeeruddin, M. Gratzel, Layered hybrid formamidinium lead iodide perovskites: challenges and opportunities. Acc. Chem. Res. 54(12), 2729–2740 (2021). https://doi.org/10.1021/acs.accounts.0c00879
M. Righetto, D. Giovanni, S.S. Lim, T.C. Sum, The photophysics of Ruddlesden-Popper perovskites: a tale of energy, charges, and spins. Appl. Phys. Rev. 8(1), 011318 (2021). https://doi.org/10.1063/5.0031821
G.B. Wu, R. Liang, Z.P. Zhang, M.Z. Ge, G.C. Xing et al., 2D hybrid halide perovskites: structure, properties, and applications in solar cells. Small 17(43), 2000395 (2021). https://doi.org/10.1002/smll.202103514
Q.L. Cao, P.W. Li, W. Chen, S.Q. Zang, L.Y. Han et al., Two-dimensional perovskites: impacts of species, components, and properties of organic spacers on solar cells. Nano Today 43, 101394 (2022). https://doi.org/10.1016/j.nantod.2022.101394
H.L. Loi, J.P. Cao, X.Y. Guo, C.K. Liu, N.X. Wang et al., Gradient 2D/3D perovskite films prepared by hot-casting for sensitive photodetectors. Adv. Sci. 7(14), 2000776 (2020). https://doi.org/10.1002/advs.202000776
S.W. Cui, J.F. Wang, H.P. Xie, Y. Zhao, Z.M. Li et al., Rubidium ions enhanced crystallinity for Ruddlesden-Popper perovskites. Adv. Sci. 7(24), 2002445 (2020). https://doi.org/10.1002/advs.202002445
Y. Kusumawati, M.A. Martoprawiro, T. Pauporté, Effects of graphene in graphene/TiO2 composite films applied to solar cell photoelectrode. J. Phys. Chem. C 118(19), 9974–9981 (2014). https://doi.org/10.1021/jp502385p
L.L. Mao, W.J. Ke, L. Pedesseau, Y.L. Wu, C. Katan et al., Hybrid Dion–Jacobson 2D lead iodide perovskites. J. Am. Chem. Soc. 140(10), 3775–3783 (2018). https://doi.org/10.1021/jacs.8b00542
S. Liu, Y.J. Guan, Y.S. Sheng, Y. Hu, Y.G. Rong et al., A review on additives for halide perovskite solar cells. Adv. Energy Mater. 10(13), 1902492 (2020). https://doi.org/10.1002/aenm.201902492
Z.Y. Xu, D. Lu, X.Y. Dong, M.Q. Chen, Q. Fu et al., Highly efficient and stable Dion–Jacobson perovskite solar cells enabled by extended pi-conjugation of organic spacer. Adv. Mater. 33(51), 2105083 (2021). https://doi.org/10.1002/adma.202105083
R. Shi, Z.S. Zhang, W.H. Fang, R. Long, Charge localization control of electron-hole recombination in multilayer two-dimensional Dion–Jacobson hybrid perovskites. J. Mater. Chem. A 8(18), 9168–9176 (2020). https://doi.org/10.1039/d0ta01944e
K. Hojo, S. Nishioka, Y. Miseki, Y. Kamakura, T. Oshima et al., An improved z-scheme for overall water splitting using dye-sensitized calcium niobate nanosheets synthesized by a flux method. ACS Appl. Energy Mater. 4(9), 10145–10152 (2021). https://doi.org/10.1021/acsaem.1c02050
Z. Fang, X.M. Hou, Y.P. Zheng, Z.B. Yang, K.C. Chou et al., First-principles optimization of out-of-plane charge transport in Dion–Jacobson CsPbI3 perovskites with pi-conjugated aromatic spacers. Adv. Funct. Mater. 31(28), 2102330 (2021). https://doi.org/10.1002/adfm.202102330
H. Li, Y. Xu, S. Ramakrishnan, Y. Zhang, M. Cotlet et al., Pseudo-halide anion engineering for efficient quasi-2D Ruddlesden-Popper tin perovskite solar cells. Cell Rep. Phys. Sci. 3(10), (2022). https://doi.org/10.1016/j.xcrp.2022.101060
X. Zhang, T.H. Yang, X.D. Ren, L. Zhang, K. Zhao et al., Film formation control for high performance Dion–Jacobson 2D perovskite solar cells. Adv. Energy Mater. 11(19), 2002733 (2021). https://doi.org/10.1002/aenm.202002733
Y.Q. Liu, L.K. Ono, G.Q. Tong, T.L. Bu, H. Zhang et al., Spectral stable blue-light-emitting diodes via asymmetric organic diamine based Dion–Jacobson perovskites. J. Am. Chem. Soc. 143(47), 19711–19718 (2021). https://doi.org/10.1021/jacs.1c07757
W.J. Ke, C.C. Stoumpos, M.H. Zhu, L.L. Mao, I. Spanopoulos et al., Enhanced photovoltaic performance and stability with a new type of hollow 3D perovskite {en}FASnI(3). Sci. Adv. 3(8), e1701293 (2017). https://doi.org/10.1126/sciadv.1701293
D.X. Li, Z. Xing, L. Huang, X.C. Meng, X.T. Hu et al., Spontaneous formation of upper gradient 2D structure for efficient and stable quasi-2D perovskites. Adv. Mater. 33(34), 2101823 (2021). https://doi.org/10.1002/adma.202101823
B.E. Cohen, T. Binyamin, T. Ben-Tzvi, O. Goldberg, A. Schlesinger et al., Hydroxyl functional groups in two-dimensional Dion–Jacobson perovskite solar cells. ACS Energy Lett. 7(1), 217–225 (2022). https://doi.org/10.1021/acsenergylett.1c01990
I.H. Park, Q.N. Zhang, K.C. Kwon, Z.Y. Zhu, W. Yu et al., Ferroelectricity and rashba effect in a two-dimensional Dion–Jacobson hybrid organic-inorganic perovskite. J. Am. Chem. Soc. 141(40), 15972–15976 (2019). https://doi.org/10.1021/jacs.9b07776
H.T. Lai, D. Lu, Z.Y. Xu, N. Zheng, Z.Q. Xie et al., Organic-salt-assisted crystal growth and orientation of quasi-2D Ruddlesden-Popper perovskites for solar cells with efficiency over 19%. Adv. Mater. 32(33), 2001470 (2020). https://doi.org/10.1002/adma.202001470
S. Ahmad, P. Fu, S.W. Yu, Q. Yang, X. Liu et al., Dion–Jacobson phase 2D layered perovskites for solar cells with ultrahigh stability. Joule 3(3), 794–806 (2019). https://doi.org/10.1016/j.Joule2018.11.026
W.C. Zhang, X.X. Wu, J. Zhou, B. Han, X.F. Liu et al., Pseudohalide-assisted growth of oriented large grains for high-performance and stable 2D perovskite solar cells. ACS Energy Lett. 7(5), 1842–1849 (2022). https://doi.org/10.1021/acsenergylett.2c00485
H.Y. Zheng, W.W. Wu, H.F. Xu, F.C. Zheng, G.Z. Liu et al., Self-additive low-dimensional Ruddlesden-Popper perovskite by the incorporation of glycine hydrochloride for high-performance and stable solar cells. Adv. Funct. Mater. 30(15), 2000034 (2020). https://doi.org/10.1002/adfm.202000034
T.W. He, S.S. Li, Y.Z. Jiang, C.C. Qin, M.H. Cui et al., Reduced-dimensional perovskite photovoltaics with homogeneous energy landscape. Nat. Commun. 11(1), 1672 (2020). https://doi.org/10.1038/s41467-020-15451-1
D. Lu, G.W. Lv, Z.Y. Xu, Y.X. Dong, X.F. Ji et al., Thiophene-based two-dimensional Dion–Jacobson perovskite solar cells with over 15% efficiency. J. Am. Chem. Soc. 142(25), 11114–11122 (2020). https://doi.org/10.1021/jacs.0c03363
P.W. Li, X.L. Liu, Y.Q. Zhang, C. Liang, G.S. Chen et al., Low-dimensional Dion–Jacobson-phase lead-free perovskites for high-performance photovoltaics with improved stability. Angew. Chem. Int. Ed. 59(17), 6909–6914 (2020). https://doi.org/10.1002/anie.202000460
J. Xiang, X. Li, S. Gong, S. Wang, X. Chen et al., Green-antisolvent-induced homogeneous phase distribution for efficient and stable MA-free 2D perovskite solar cells. Chem. Eng. J. 460, 141758 (2023). https://doi.org/10.1016/j.cej.2023.141758
J.Y. Zhang, S. Langner, J.C. Wu, C. Kupfer, L. Luer et al., Intercalating-organic-cation-induced stability bowing in quasi-2D metal-halide perovskites. ACS Energy Lett. 7(1), 70–77 (2022). https://doi.org/10.1021/acsenergylett.1c02081
H.X. Shi, L. Zhang, H. Huang, Y.L. Ou, X.T. Wang et al., Additive engineering for high-performance two-dimensional Dion–Jacobson Pb-Sn alloyed perovskite solar cells. Energy Technol. 10(12), 2200983 (2022). https://doi.org/10.1002/ente.202200983
X.M. Zhao, T.R. Liu, A.B. Kaplan, C. Yao, Y.L. Loo, Accessing highly oriented two-dimensional perovskite films via solvent-vapor annealing for efficient and stable solar cells. Nano Lett. 20(12), 8880–8889 (2020). https://doi.org/10.1021/acs.nanolett.0c03914
L. Cheng, K. Meng, Z. Qiao, Y.F. Zhai, R.Z. Yu et al., Tailoring interlayer spacers for efficient and stable formamidinium-based low-dimensional perovskite solar cells. Adv. Mater. 34(4), 2106380 (2022). https://doi.org/10.1002/adma.202106380
T.T. Niu, H. Ren, B. Wu, Y.D. Xia, X.J. Xie et al., Reduced-dimensional perovskite enabled by organic diamine for efficient photovoltaics. J. Phys. Chem. A 10(10), 2349–2356 (2019). https://doi.org/10.1021/acs.jpclett.9b00750
Y.T. Zheng, T.T. Niu, J. Qiu, L.F. Chao, B.X. Li et al., Oriented and uniform distribution of Dion–Jacobson phase perovskites controlled by quantum well barrier thickness. Sol. RRL 3(9), 1900090 (2019). https://doi.org/10.1002/solr.201900090
L. Jin, N. Ren, P. Wang, R. Li, Q. Xue et al., Secondary anti-solvent treatment for efficient 2D Dion–Jacobson perovskite solar cells. Small 19(3), e2205088 (2023). https://doi.org/10.1002/smll.202205088
H. Wang, C.C.S. Chan, M. Chu, J.S. Xie, S.H. Zhao et al., Interlayer cross-linked 2D perovskite solar cell with uniform phase distribution and increased exciton coupling. Sol. RRL 4(4), 1900578 (2020). https://doi.org/10.1002/solr.201900578
C.Q. Ma, D. Shen, T.W. Ng, M.F. Lo, C.S. Lee, 2D perovskites with short interlayer distance for high-performance solar cell application. Adv. Mater. 30(22), 1800710 (2018). https://doi.org/10.1002/adma.201800710
W.D. Zhao, Q.S. Dong, J.W. Zhang, S. Wang, M. Chen et al., Asymmetric alkyl diamine based Dion–Jacobson low-dimensional perovskite solar cells with efficiency exceeding 15%. J. Mater. Chem. A 8(19), 9919–9926 (2020). https://doi.org/10.1039/d0ta02706e
Z. Wang, L. Liu, X.D. Liu, D.D. Song, D. Shi et al., Uncovering synergistic effect of chloride additives for efficient quasi-2D perovskite solar cells. Chem. Eng. J. 432, 134367 (2022). https://doi.org/10.1016/j.cej.2021.134367
J.F. Wang, D.X. Lin, Y.F. Chen, S.Q. Luo, L.L. Ke et al., Suppressing the excessive solvated phase for Dion–Jacobson perovskites with improved crystallinity and vertical orientation. Sol. RRL 4(11), 2000371 (2020). https://doi.org/10.1002/solr.202000371
D. Wang, S.C. Chen, Q.D. Zheng, Enhancing the efficiency and stability of two-dimensional Dion–Jacobson perovskite solar cells using a fluorinated diammonium spacer. J. Mater. Chem. A 9(19), 11778–11786 (2021). https://doi.org/10.1039/d1ta01447a
E.S. Vasileiadou, X.Y. Jiang, M. Kepenekian, J. Even, M.C. De Siena et al., Thick-layer lead iodide perovskites with bifunctional organic spacers allylammonium and iodopropylammonium exhibiting trap-state emission. J. Am. Chem. Soc. 144(14), 6390–6409 (2022). https://doi.org/10.1021/jacs.2c00571
P.Y. Su, L. Bai, H. Bi, B.B. Liu, S. Chen et al., Interfacial gradient energy band alignment modulation via ion exchange reaction toward efficient and stable methylammonium-free Dion–Jacobson quasi-2D perovskite solar cells. J. Power Sources 506, 230213 (2021). https://doi.org/10.1016/j.jpowsour.2021.230213
J.K. Quan, S.D. Yu, B.Y. Xing, X. He, L.J. Zhang, Two-dimensional Ruddlesden-Popper halide perovskite solar absorbers with short-chain interlayer spacers. Phys. Rev. Mater. 6(6), 065405 (2022). https://doi.org/10.1103/PhysRevMaterials.6.065405
Z.Z. Li, S.W. Yang, C.C. Ye, G. Wang, B. Ma et al., Ordered element distributed C3N quantum dots manipulated crystallization kinetics for 2D CsPbI3 solar cells with ultra-high performance. Small 18(15), 2108090 (2022). https://doi.org/10.1002/smll.202108090
J. Guo, Z.J. Shi, J.M. Xia, K.Y. Wang, Q. Wei et al., Phase tailoring of Ruddlesden-Popper perovskite at fixed large spacer cation ratio. Small 17(43), 2100560 (2021). https://doi.org/10.1002/smll.202100560
C.C. Qin, L.H. Xu, Z.P. Zhou, J. Song, S.H. Ma et al., Carrier dynamics in two-dimensional perovskites: Dion–Jacobson vs. Ruddlesden-Popper thin films. J. Mater. Chem. A 10(6), 3069–3076 (2022). https://doi.org/10.1039/d1ta09549h
W.D. Zhu, J.X. Ma, W.M. Chai, T.J. Han, D.D. Chen et al., Intermediate phase-assisted sequential deposition toward 15.24%-efficiency carbon-electrode CsPbI(2)Br perovskite solar cells. Sol. RRL 6(6), 2200020 (2022). https://doi.org/10.1002/solr.202200020
C.L. Zhou, W.B. Ma, Z.L. Zhang, Y.L. Mao, Effect of anti-solvents on the performance of solar cells based on two-dimensional Ruddlesden-Popper-phase perovskite films. J. Phys. D 55(35), 354004 (2022). https://doi.org/10.1088/1361-6463/ac7267
F.Z. Li, J. Zhang, S. Jo, M.C. Qin, Z. Li et al., Vertical orientated Dion–Jacobson quasi-2D perovskite film with improved photovoltaic performance and stability. Small Methods 4(5), 1900831 (2020). https://doi.org/10.1002/smtd.201900831
F. Zheng, D. Angmo, C.R. Hall, S. Rubanov, F.F. Yuan et al., Brownian tree-shaped dendrites in quasi-2D perovskite films and their impact on photovoltaic performance. Adv. Mater. Interfaces 9(13), 2102231 (2022). https://doi.org/10.1002/admi.202102231
Z.L. Li, Z.T. Deng, A. Johnston, J.W. Luo, H.J. Chen et al., Precursor tailoring enables alkylammonium tin halide perovskite phosphors for solid-state lighting. Adv. Funct. Mater. 32(18), 2111346 (2022). https://doi.org/10.1002/adfm.202111346
H.T. Wu, X.M. Lian, S.X. Tian, Y.Z. Zhang, M.C. Qin et al., Additive-assisted hot-casting free fabrication of Dion–Jacobson 2D perovskite solar cell with efficiency beyond 16%. Sol. RRL 4(7), 2000087 (2020). https://doi.org/10.1002/solr.202000087
H.T. Wu, X.M. Lian, J. Li, Y.Z. Zhang, G.Q. Zhou et al., Merged interface construction toward ultra-low Voc loss in inverted two-dimensional Dion–Jacobson perovskite solar cells with efficiency over 18%. J. Mater. Chem. A 9(21), 12566–12573 (2021). https://doi.org/10.1039/d1ta02015c
S.M. Gowdru, J.C. Lin, S.T. Wang, Y.C. Chen, K.C. Wu et al., Accelerated formation of 2D Ruddlesden-Popper perovskite thin films by lewis bases for high efficiency solar cell applications. Nanomaterials 12(11), 1816 (2022). https://doi.org/10.3390/nano12111816
R.D. Yukta, P. Chavan, S. Yadav, Satapathi, Ammonium thiocyanate-passivated quasi-two-dimensional Dion–Jacobson perovskite solar cells for improved efficiency and stability. ACS Appl. Energy Mater. 5(11), 13723–13734 (2022). https://doi.org/10.1021/acsaem.2c02398
H. Wang, Z.T. Qin, J.S. Xie, S.H. Zhao, K. Liu et al., Efficient slantwise aligned Dion–Jacobson phase perovskite solar cells based on trans-1,4-cyclohexanediamine. Small 16(42), 2003098 (2020). https://doi.org/10.1002/smll.202003098
A. Caiazzo, K. Datta, J.K. Jiang, M.C. Gelvez-Rueda, J.Y. Li et al., Effect of co-solvents on the crystallization and phase distribution of mixed-dimensional perovskites. Adv. Energy Mater. 11(42), 2102144 (2021). https://doi.org/10.1002/aenm.202102144
Y.P. Lv, H.R. Ma, Y.F. Yin, Q.S. Dong, W.D. Zhao et al., NH3(CH2)(6)NH3 PbI4 as Dion–Jacobson phase bifunctional capping layer for 2D/3D perovskite solar cells with high efficiency and excellent UV stability. J. Mater. Chem. A 8(20), 10283–10290 (2020). https://doi.org/10.1039/d0ta02437f
W.J. Ke, L.L. Mao, C.C. Stoumpos, J. Hoffman, I. Spanopoulos et al., Compositional and solvent engineering in Dion–Jacobson 2D perovskites boosts solar cell efficiency and stability. Adv. Energy Mater. 9(10), 1803384 (2019). https://doi.org/10.1002/aenm.201803384
Y. Zheng, C.H. Zhao, Y.F. Li, W.Q. Zhang, T. Wu et al., Directly visualizing and exploring local heterointerface with high electro-catalytic activity. Nano Energy 78, 105236 (2020). https://doi.org/10.1016/j.nanoen.2020.105236
X.T. Li, W.J. Ke, B. Traore, P.J. Guo, I. Hadar et al., Two-dimensional Dion–Jacobson hybrid lead iodide perovskites with aromatic diammonium cations. J. Am. Chem. Soc. 141(32), 12880–12890 (2019). https://doi.org/10.1021/jacs.9b06398
M. Safdari, D. Phuyal, B. Philippe, P.H. Svensson, S.M. Butorin et al., Impact of synthetic routes on the structural and physical properties of butyl-1,4-diammonium lead iodide semiconductors. J. Mater. Chem. A 5(23), 11730–11738 (2017). https://doi.org/10.1039/c6ta10123b
M. Safdari, P.H. Svensson, M.T. Hoang, I. Oh, L. Kloo et al., Layered 2D alkyldiammonium lead iodide perovskites: synthesis, characterization, and use in solar cells. J. Mater. Chem. A 4(40), 15638–15646 (2016). https://doi.org/10.1039/c6ta05055g
H. Ren, S.D. Yu, L.F. Chao, Y.D. Xia, Y.H. Sun et al., Efficient and stable Ruddlesden-Popper perovskite solar cell with tailored interlayer molecular interaction. Nat. Photonics 14(3), 154 (2020). https://doi.org/10.1038/s41566-019-0572-6
S. Yu, Y.J. Yan, M. Abdellah, T. Pullerits, K.B. Zheng et al., Nonconfinement structure revealed in Dion–Jacobson type quasi-2D perovskite expedites interlayer charge transport. Small 15(49), 1905081 (2019). https://doi.org/10.1002/smll.201905081
E. Mahal, S.C. Mandal, B. Pathak, Band edge engineering of 2D perovskite structures through spacer cation engineering for solar cell applications. J. Phys. Chem. C 126(23), 9937–9947 (2022). https://doi.org/10.1021/acs.jpcc.2c01840
B.D. Lee, J.W. Lee, M. Kim, W.B. Park, K.S. Sohn, Discovery of Pb-free hybrid organic-inorganic 2D perovskites using a stepwise optimization strategy. NPJ Comput. Mater. 8(1), 83 (2022). https://doi.org/10.1038/s41524-022-00781-z
Y. Wei, B.Q. Chen, F. Zhang, Y.Y. Tian, X.C. Yang et al., Compositionally designed 2D Ruddlesden-Popper perovskites for efficient and stable solar cells. Sol. RRL 5(4), 2000661 (2021). https://doi.org/10.1002/solr.202000661
Z.H. Liu, L. Wang, X.Y. Xie, C.Y. Xu, J.F. Tang et al., High-performance Ruddlesden-Popper two-dimensional perovskite solar cells via solution processed inorganic charge transport layers. Phys. Chem. Chem. Phys. 24(26), 15912–15919 (2022). https://doi.org/10.1039/d2cp02033e
M. Rahil, R.M. Ansari, C. Prakash, S.S. Islam, A. Dixit et al., Ruddlesden-Popper 2D perovskites of type (C6H9C2H4NH3)(2) (CH3NH3)(n-1)PbnI3n+1(n=1-4) for optoelectronic applications. Sci. Rep. 12(1), 2176 (2022). https://doi.org/10.1038/s41598-022-06108-8
W.J. Ke, C.C. Stoumpos, I. Spanopoulos, M. Chen, M.R. Wasielewski et al., Diammonium cations in the FASnI(3) perovskite structure lead to lower dark currents and more efficient solar cells. ACS Energy Lett. 3(7), 1470–1476 (2018). https://doi.org/10.1021/acsenergylett.8b00687
B. Ma, J.W. Chen, M.H. Wang, X. Xu, J. Qian et al., Passivating charged defects with 1,6-hexamethylenediamine to realize efficient and stable tin-based perovskite solar cells. J. Phys. Chem. C 124(30), 16289–16299 (2020). https://doi.org/10.1021/acs.jpcc.0c03401
H.Y. Fu, Dion–Jacobson halide perovskites for photovoltaic and photodetection applications. J. Mater. Chem. C 9(20), 6378–6394 (2021). https://doi.org/10.1039/d1tc01061a
L. Zhang, Q. Kang, Y.P. Song, D. Chi, S.H. Huang et al., Grain boundary passivation with Dion–Jacobson phase perovskites for high-performance Pb-Sn mixed narrow-bandgap perovskite solar cells. Sol. RRL 5(4), 2000681 (2021). https://doi.org/10.1002/solr.202000681
C. Hanmandlu, A. Singh, K.M. Boopathi, C.S. Lai, C.W. Chu, Layered perovskite materials: key solutions for highly efficient and stable perovskite solar cells. Rep. Prog. Phys. 83(8), 086502 (2020). https://doi.org/10.1088/1361-6633/ab9f88
T.Q. Niu, Q.F. Xue, H.L. Yip, Advances in Dion–Jacobson phase two-dimensional metal halide perovskite solar cells. Nanophotonics 10(8), 2069–2102 (2021). https://doi.org/10.1515/nanoph-2021-0052
W.J. Ke, C. Chen, I. Spanopoulos, L.L. Mao, I. Hadar et al., Narrow-bandgap mixed lead/tin-based 2D Dion–Jacobson perovskites boost the performance of solar cells. J. Am. Chem. Soc. 142(35), 15049–15057 (2020). https://doi.org/10.1021/jacs.0c06288
Y.L. Zhang, N.G. Park, Quasi-two-dimensional perovskite solar cells with efficiency exceeding 22%. ACS Energy Lett. 7(2), 757–765 (2022). https://doi.org/10.1021/acsenergylett.1c02645
J.M. Yang, S.B. Xiong, J.N. Song, H.B. Wu, Y.H. Zeng et al., Energetics and energy loss in 2D Ruddlesden-Popper perovskite solar cells. Adv. Energy Mater. 10(23), 2000687 (2020). https://doi.org/10.1002/aenm.202000687
P.W. Li, C. Liang, X.L. Liu, F.Y. Li, Y.Q. Zhang et al., Low-dimensional perovskites with diammonium and monoammonium alternant cations for high-performance photovoltaics. Adv. Mater. 31(35), 1901966 (2019). https://doi.org/10.1002/adma.201901966
T. Duong, H. Pham, T.C. Kho, P. Phang, K.C. Fong et al., High efficiency perovskite-silicon tandem solar cells: effect of surface coating versus bulk incorporation of 2D perovskite. Adv. Energy Mater. 10(9), 1903553 (2020). https://doi.org/10.1002/aenm.201903553
N.E. Wright, X.X. Qin, J.W. Xu, L.L. Kelly, S.P. Harvey et al., D. Stiff-Roberts. Influence of annealing and composition on the crystal structure of mixed-halide, Ruddlesden-Popper perovskites. Chem. Mater. 34(7), 3109–3122 (2022). https://doi.org/10.1021/acs.chemmater.1c04213
Z. Wang, X.D. Liu, H. Ren, L. Liu, X.Y. Tang et al., Insight into the enhanced charge transport in quasi-2D perovskite via fluorination of ammonium cations for photovoltaic applications. ACS Appl. Mater. Interfaces 14(6), 7917–7925 (2022). https://doi.org/10.1021/acsami.1c21715
C.Q. Ma, M.F. Lo, C.S. Lee, A simple method for phase control in two-dimensional perovskite solar cells. J. Mater. Chem. A 6(39), 18871–18876 (2018). https://doi.org/10.1039/c8ta06976j
S. Ahmad, W. Yu, R.X. Lu, Y. Liu, T.G. Jiu et al., Formamidinium-incorporated Dion–Jacobson phase 2D perovskites for highly efficient and stable photovoltaics. J. Energy Chem. 57, 632–638 (2021). https://doi.org/10.1016/j.jechem.2020.08.055
P.Y. Su, L. Bai, H. Bi, B.B. Liu, D.M. He et al., Crystal orientation modulation and defect passivation for efficient and stable methylammonium-free Dion–Jacobson quasi-2D perovskite solar cells. ACS Appl. Mater. Interfaces 13(25), 29567–29575 (2021). https://doi.org/10.1021/acsami.1c05498
Y.J. Chen, J.L. Hu, Z.H. Xu, Z.Y. Jiang, S. Chen et al., Managing phase orientation and crystallinity of printed Dion–Jacobson 2D perovskite layers via controlling crystallization kinetics. Adv. Funct. Mater. 32(19), 2112146 (2022). https://doi.org/10.1002/adfm.202112146
S. Aharon, D.R. Ceratti, N.P. Jasti, L. Cremonesi, Y. Feldman et al., 2D Pb-halide perovskites can self-heal photodamage better than 3D ones. Adv. Funct. Mater. 32(24), 2113354 (2022). https://doi.org/10.1002/adfm.202113354
S.M. Yang, W.D. Liu, Y. Han, Z.K. Liu, W.J. Zhao et al., 2D Cs2PbI2Cl2 nanosheets for holistic passivation of inorganic CsPbI2Br perovskite solar cells for improved efficiency and stability. Adv. Energy Mater. 10(46), 2002882 (2020). https://doi.org/10.1002/aenm.202002882
Y. Guo, M.Y. Sun, W.J. Yang, S.Y. Yuan, H. Xiong et al., Enhanced charge transport by regulating the electronic structure in 2D tin-based perovskite solar cells. J. Phys. Chem. C 126(22), 9425–9436 (2022). https://doi.org/10.1021/acs.jpcc.2c02830
C.M.M. Soe, C.C. Stoumpos, M. Kepenekian, B. Traore, H. Tsai et al., New type of 2D perovskites with alternating cations in the interlayer space, (C(NH2)(3))(CH3NH3)(n)PbnI3n+1: structure, properties, and photovoltaic performance. J. Am. Chem. Soc. 139(45), 16297–16309 (2017). https://doi.org/10.1021/jacs.7b09096
Y.L. Zhang, P.J. Wang, M.C. Tang, D. Barrit, W.J. Ke et al., Dynamical transformation of two-dimensional perovskites with alternating cations in the interlayer space for high-performance photovoltaics. J. Am. Chem. Soc. 141(6), 2684–2694 (2019). https://doi.org/10.1021/jacs.8b13104
G.J. Yan, G.M. Sui, W.T. Chen, K. Su, Y.Q. Feng et al., Selectively fluorinated benzylammonium-based spacer cation enables graded quasi-2D perovskites for efficient and stable solar cells. Chem. Mater. 34(7), 3346–3356 (2022). https://doi.org/10.1021/acs.chemmater.2c00146
S. Chen, N. Shen, L.H. Zhang, L.Z. Zhang, S.H. Cheung et al., Understanding the interplay of binary organic spacer in Ruddlesden-Popper perovskites toward efficient and stable solar cells. Adv. Funct. Mater. 30(10), 1907759 (2020). https://doi.org/10.1002/adfm.201907759
H. Gu, C. Liang, Y.D. Xia, Q. Wei, T.H. Liu et al., Nanoscale hybrid multidimensional perovskites with alternating cations for high performance photovoltaic. Nano Energy 65, 104050 (2019). https://doi.org/10.1016/j.nanoen.2019.104050
T.Y. Xu, S. Lu, Y.J. Wang, X.Y. Gan, L.L. Guo et al., Optimization of multilayered Ruddlesden-Popper perovskite with 4-bromophenylethylamine by ionic liquid for solar cell applications. J. Mater. Sci. 57(16), 7896–7908 (2022). https://doi.org/10.1007/s10853-022-07154-3
W.B. Ma, Z.L. Zhang, M. Kang, Y.F. Liu, H.F. Zhang et al., Enhanced efficiency and stability of Dion–Jacobson quasi-two-dimensional perovskite solar cells by additive. J. Phys. D 55(41), 414002 (2022). https://doi.org/10.1088/1361-6463/ac84e8
S. Ahmad, R. Lu, Y. Liu, X. Liu, Q. Yang et al., Cesium-doped Dion–Jacobson 2D perovskites for highly stable photovoltaics with an 18.3% efficiency. Nano Energy 103, 107822 (2022). https://doi.org/10.1016/j.nanoen.2022.107822
G. Huang, J. Chen, B. Wang, Q. Cheng, Y. Li et al., Solvent effect on film formation and trap states of two-dimensional Dion–Jacobson perovskite. Nano Lett. 22(18), 7545–7553 (2022). https://doi.org/10.1021/acs.nanolett.2c02533
G.X. Ren, C. Yan, L.A. Xiao, X. Wu, S.C. Peng et al., Additive-induced film morphology evolution for inverted Dion–Jacobson quasi-two-dimensional perovskite solar cells with enhanced performance. ACS Appl. Energy Mater. 5(8), 9837–9845 (2022). https://doi.org/10.1021/acsaem.2c01559
M.C. Gelvez-Rueda, P. Ahlawat, L. Merten, F. Jahanbakhshi, M. Mladenovic et al., Formamidinium-based Dion–Jacobson layered hybrid perovskites: structural complexity and optoelectronic properties. Adv. Funct. Mater. 30(38), 2003428 (2020). https://doi.org/10.1002/adfm.202003428
Acknowledgements
Marie Cresp is acknowledged for the carefully reading of the manuscript and her suggestions. Min Liu thanks the CSC for funding his PhD scholarship (grant number 202008120110). The ANR agency is acknowledged for financial support via the ChemSta project ANR-21-CE05-0022.
Funding
Open access funding provided by Shanghai Jiao Tong University.
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
Conflict of interest
The authors declare no conflict of interest.
Rights and permissions
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
About this article
Cite this article
Liu, M., Pauporté, T. Additive Engineering for Stable and Efficient Dion–Jacobson Phase Perovskite Solar Cells. Nano-Micro Lett. 15, 134 (2023). https://doi.org/10.1007/s40820-023-01110-9
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s40820-023-01110-9