-
Controversial luminescent centers and edge states in low-dimensional perovskites were summarized.
-
Evaluated experimental evidences and discussed the root cause for challenges and controversies.
-
New experimental techniques were suggested to resolve the controversies and identify the nature of luminescent centers.
Abstract
With only a few deep-level defect states having a high formation energy and dominance of shallow carrier non-trapping defects, the defect-tolerant electronic and optical properties of lead halide perovskites have made them appealing materials for high-efficiency, low-cost, solar cells and light-emitting devices. As such, recent observations of apparently deep-level and highly luminescent states in low-dimensional perovskites have attracted enormous attention as well as intensive debates. The observed green emission in 2D CsPb2Br5 and 0D Cs4PbBr6 poses an enigma over whether it is originated from intrinsic point defects or simply from highly luminescent CsPbBr3 nanocrystals embedded in the otherwise transparent wide band gap semiconductors. The nature of deep-level edge emission in 2D Ruddlesden–Popper perovskites is also not well understood. In this mini review, the experimental evidences that support the opposing interpretations are analyzed, and challenges and root causes for the controversy are discussed. Shortcomings in the current density functional theory approaches to modeling of properties and intrinsic point defects in lead halide perovskites are also noted. Selected experimental approaches are suggested to better correlate property with structure of a material and help resolve the controversies. Understanding and identification of the origin of luminescent centers will help design and engineer perovskites for wide device applications.
Similar content being viewed by others
1 Introduction
Lead halide perovskites have provided us not only a long-awaited material platform to realize the dream of high-efficiency solar cells and many other optoelectronic devices, but also a wide range of structures to explore unusual fundamental sciences [1,2,3,4,5]. Depending on spatial configurations, lead halide octahedrons can form structures from three-dimensional (3D) all the way to 0D perovskites [6]. While still not completely understood, the superior optoelectronic properties of perovskites are believed to originate from their immunity to defects and lack of non-radiative deep-level traps, which have made them ideal materials for high-efficiency low-cost solar cells and many other optoelectronic devices [1,2,3,4,5, 7]. This is another reason why recent observations of possible new types of luminescent states in low-dimensional perovskites are surprising; in particular, they have been used for higher efficient solar cells and even brighter light-emitting diodes [6, 8,9,10,11,12,13,14,15,16,17,18]. Such apparent deep-level luminescent centers have been observed in 2D CsPb2Br5 [19,20,21,22,23,24] and 0D Cs4PbBr6 [11, 15, 16, 25, 26]. Because of their optical property similarities to those of CsPbBr3 [27,28,29], the emission is believed to originate from embedded CsPbBr3 nanocrystals [15, 16, 30,31,32,33,34,35,36]. But many other researchers attribute it to intrinsic point defects because no CsPbBr3 nanocrystals have been found in their emissive samples [11, 25, 26]. The debates on the origin of Cs4PbBr6 are especially hot, as seen from four recent articles which acknowledge the controversy but are inclined to support one over the other [15, 16, 25, 26]. Similar deep-level luminescence centers have also been observed in low-dimensional organic–inorganic metal halide materials with better pronounced morphological dimensionality [37, 38] than that in Cs–Pb–Br system. The study of luminescence centers in structurally simpler all-inorganic lead halide perovskites, however, is expected to be instructive for further understanding the origin of these centers in all types of metal halide perovskites. As perovskites bring us more interesting properties and have found wide device applications, it is essential to understand the nature and mechanism for these luminescent centers.
In this mini review, the experimental evidences that support the opposing interpretations of the luminescence centers in Cs–Pb–Br system are analyzed, and challenges and root causes for the controversy are discussed. Selected experimental approaches are suggested to better correlate property with structure of a material and help resolve the controversies.
2 Defects and Inclusions in Cs–Pb–Br System Rooted in the Ternary Phase Diagram
The perovskite-like compounds in Cs–Pb–Br system, CsPbBr3, CsPb2Br5 and Cs4PbBr6, can be easily synthesized via solution process or melt-grown [11, 19, 34, 39,40,41,42]. The possibility of the different phase coexistence is well expected, and the compounds are stable within narrow chemical potential ranges as shown by recent density functional theory (DFT) simulations [26].
The ternary phase diagram of the Cs–Pb–Br system shown in Fig. 1b demonstrates that the three different perovskite-like structures can be produced using only CsBr and PbBr2 precursors. The different phases in Cs–Pb–Br system are grown by varying the precursor ratio (CsBr: PbBr2). As shown in Ref. [43], slight change of the crystal growth conditions and controlled precursor ratios can produce the low-dimensional phases CsPb2Br5 and Cs4PbBr6.
The 3D perovskite CsPbBr3 is the only compound in Cs–Pb–Br system that produces inherent green PL emission. This perovskite material was found unstable in moisture environment, and its instability has been used successfully to transform it into the lower dimension but stable phases CsPb2Br5 [20, 23] and Cs4PbBr6 [44] in water environment. The water-induced transformation of CsPbBr3 into CsPb2Br5 occurs in a sequential dissolution–recrystallization process under PbBr2-rich conditions [20]. Thus, synthesized CsPb2Br5 emits green photoluminescence (PL) with high PL quantum yield [20], but another approach using water was capable of growing non-emissive single crystals [23]. These observations hint that the green PL in CsPb2Br5 is likely due to highly luminescent CsPbBr3 nanocrystal remnants.
Zhang et al. [44] have grown successfully a millimeter-sized Cs4PbBr6 bulk single crystal in concentrated CsBr aqueous solution that lacks green luminescence emission [44]. In the same work, they also demonstrate that vacuum annealing treatment activates green PL in original nongreen-luminescent Cs4PbBr6 crystals, which was attributed to the possible formation of CsPbBr3. A reversible phase transformation between CsPbBr3 and CdPb2Br5 nanosheets under intense laser light has been demonstrated in Ref. [45]. Therefore, the narrow phase stability regions in the ternary phase diagram and the possibility of partially reversible phase transformations strongly support the expectations for foreign phase inclusions in the Cs–Pb–Br compounds.
2.1 Luminescent State in 2D Wide Bandgap CsPb2Br5
CsPb2Br5 is a layered lead halide structure with Pb-Br framework separated by Cs layers (Fig. 2a). 2D CsPb2Br5 has also attracted a lot of attention recently due to many conflicting reports on its luminescence although it was synthesized and studied long ago [41, 46]. Zhang et al. [21] were the first to report the beneficial effect of CsPb2Br5 to 3D all-inorganic perovskite CsPbBr3: the attachment of CsPb2Br5 nanoparticles to CsPbBr3 nanocrystals enhanced PL of CsPbBr3 by several folds and external quantum efficiency of CsPbBr3 light-emitting diodes (LEDs) by 50%. Figure 2b, c shows that more than 90% of CsPbBr3 are covered by CsPb2Br5 nanoparticles, but the PL and PLQY of CsPb2Br5/CsPbBr3 are nearly the same as those of pure CsPbBr3 nanocrystals. Figure 2d, e shows that these nanoparticles are not single phase, and high-resolution TEM reveals that they are CsPb2Br5/CsPbBr3 nanocomposites with dark smaller CsPb2Br5 nanocrystals attached to larger CsPbBr3 nanoparticles [21].
Shortly after that, Wang and co-workers reported nearly 90% quantum efficiency of pure CsPb2Br5 nanoplatelets and subsequently expanded their emission wavelength to whole visible spectrum using ion exchange with I and Cl [19] (Fig. 3). Note that the purity of the initial CsPb2Br5 and ion-exchanged nanocrystals was verified by XRD and high-resolution TEM. Since then, many groups reported strong visible photoluminescence, high-efficiency LEDs, photodetectors and even lasing action in CsPb2Br5 microplates [20, 47,48,49,50,51,52,53,54]. Highly luminescent CsPb2Br5 nanowires with mixed halides are also synthesized recently [55].
Despite numerous reports, the claim of highly luminescent CsPb2Br5 has been met with skeptics. Li et al. [22] synthesized CsPb2Br5 nanosheets from CsPbBr3 nanocubes. They have found that as the reaction goes on, both absorption and PL near 520 nm disappear, and the final product of CsPb2Br5 nanosheets displays no PL at all (Fig. 4). They also performed DFT simulation. The results (Fig. 4c, d) agree with the observation that CsPb2Br5 is an indirect wide band gap semiconductor [22].
The non-emissive nature of CsPb2Br5 can be best verified from transparent large-sized sheets in Fig. 5a, b [12, 13]. Emissive macro- or micro-CsPb2Br5 typically exhibits a characteristic yellow color as shown in Fig. 3a. Different colors of CsPb2Br5 sheets in Fig. 5b are due to their thickness-dependent optical interference under ambient or white light. As CsPb2Br5 can be produced by converting CsPbBr3 particles, CsPbBr3 particles can be recovered from CsPb2Br5 as well. Figure 5c shows the evolution of XRD patterns when high-purity CsPb2Br5 (black) was annealed at 220 °C (red) and 400 °C (blue). As the annealing temperature increases, X-ray pattern of CsPbBr3 particles begins to appear. This observation is also confirmed by TEM. Figure 5d, e shows CsPbBr3 particles attached on CsPb2Br5 in sample annealed at 400 °C. The change can also be seen in the PL spectra. The redshift of the PL band with annealing temperature is due to increasing size of CsPbBr3 particles [14]. Clearly, embedded CsPbBr3 particles in CsPb2Br5 can be a source for green PL emission in otherwise non-emissive pure CsPb2Br5. However, the same group has changed their mind and considered green emission as an intrinsic property of CsPb2Br5 after synthesizing and analyzing green emissive CsPb2Br5. Due to this reason, the mechanism for the green emission in CsPb2Br5 remains controversial. Many groups are aware of this controversy but are not able to support either of these two opposing claims [56,57,58].
2.2 Luminescent State in 0D Wide Bandgap Cs4PbBr6 Perovskite
In Cs4PbBr6, PbBr6 octahedrons are isolated by surrounding Cs ions and each octahedron behaves as a single molecular quantum dot (Fig. 6a inset), so Cs4PbBr6 is called 0D perovskite [15]. On the other hand, the crystallization of Cs4PbBr6 in a structure with translational symmetry and fixed orientation of PbBr6 octahedrons to each other clearly indicate that the spacing between PbBr6 is not enough to completely deactivate the interaction between them [16]. These interactions are better suppressed in the organic 0D metal halide hybrids [59, 60], which are closer to a quantum dot material. DFT calculations of an isolated Cs4PbBr6 structure, however, yield an energy gap close to those of bulk Cs4PbBr6 [61], which justifies the assignment of Cs4PbBr6 to 0D materials. Specifically, Cs4PbBr6 has attracted a lot of attention because of the high PL quantum efficiency reported in Ref. [11]. Figure 6 shows that Cs4PbBr6 also emits green light with a wavelength very close to that of CsPbBr3, but the PLQY is more than two orders of magnitude larger. Because Cs4PbBr6 is purified by dissolving CsPbBr3 contamination using dimethyl sulfoxide (DMSO), and no X-ray of CsPbBr3 is detected, the green emission is considered as an intrinsic property of Cs4PbBr6 [11]. Such strong green emission was initially attributed to the high exciton binding energy in isolated PbBr6 [11]. Later, an alternative explanation suggests that the green emission is due to a phonon-assisted transfer of photoexcited electrons to a charge-transfer state of Pb ions in the host lattice distorted by atomic displacements involved in the phonon [62]. Recently, the group published a series of papers and attributed the PL to intrinsic Br vacancies [26, 62,63,64,65]. Their theory has been supported by DFT calculations [26, 63] and other groups [25, 66,67,68,69].
The claim that the green PL emission is an intrinsic property of Cs4PbBr6 is also supported by the synthesis of large-sized single crystals (Fig. 7a, b). However, many other researchers do not agree with their observations and explanation [30,31,32, 44, 71]. Because the emission wavelength overlaps with that of CsPbBr3 very well, it has been believed that the strong PL originates from embedded CsPbBr3 nanocrystals. This alternative idea of non-intrinsic luminescent property is supported by the synthesis of non-emissive Cs4PbBr6, both large-sized single crystals (Fig. 7c) and nanocrystals [30, 44, 62, 71]. Opposing simulations also show that the Br vacancies cannot produce such deep-level defect states [5, 15, 16, 33]. As the strongest experimental evidences, both sides show high-resolution TEM images. Figure 7d–g compares TEM images of emissive and non-emissive Cs4PbBr6 nanocrystals. Both types of nanocrystals exhibit clean single crystal structure, and no CsPbBr3 inclusion is found. On the other hand, CsPbBr3/Cs4PbBr6 nanocomposites have been frequently synthesized and observed, and they exhibit strong PLQY as expected [16, 34, 70, 72].
2.3 Bright Edge States in 2D Ruddlesden–Popper (R–P) Perovskites
Corner-sharing PbBr6 octahedrons as those in CsPbBr3 are definitely the structures that can produce visible PL. This has also been confirmed by the PL properties of two-dimensional (2D) R–P lead halide perovskites [10]. The observed crystal edge bright PL emission, different from that of the bulk one, in these materials is very instructive with demonstrated effects of PbBr6 framework relaxation at the surface of perovskite crystals.
A surface is an inevitable termination of periodic lattices of any single crystals even when we are only interested in their bulk properties. For 2D materials, edges will become surfaces and introduce surface defects as they terminate their 2D expansion. A surface will typically introduce detrimental or unwanted effects to the bulk materials so that surface treatment or passivation is crucial for the desired function or performance of materials. Because of this reason, it was very surprising that the edges of 2D organic–inorganic perovskites provide a deep-level luminescent center that also enhances the performance of solar cells [10].
In 2017, Blancon et al. [10] reported that 2D R–P perovskites (BA)2(MA)n−1PbnI3n+1 exhibit a low energy photoluminescence in the edge of exfoliated flakes when n is 3 or larger (Fig. 8a–c). Their emission energy is ~ 300 meV below the band gap of (BA)2(MA)n−1PbnI3n+1. Unlike conventional deep-level defect states, they can quickly dissociate photoexcited excitons and prevent electron–hole from non-radiative recombination [10]. By fabricating 2D platelets vertically and having edges directly connected to the electrodes, the researchers have demonstrated 12% efficiency of 2D perovskite cells [10]. However, the nature of the edge states was not totally understood, and even their chemical composition and microscopic structure have not been experimentally identified in their initial report [10].
It was not until a year later that a theory paper was published and offered a model to explain the edge states [73]. The calculation shows that when n > 2, the strain caused by the interface between inorganic and organic spacers will be relaxed to the edge lattices, causing a large lattice distortion (Fig. 9a). The distortion is large enough to create new localized state with energy much lower than the band gap [73]. However, there is still no experimental confirmation of the lattice distortion on the edge. A related paper was just published and reports the effect of organic spacer on the distortion of inorganic lattice in the surface of monolayer R–P perovskites [74]. Figure 9b–e demonstrates the sensitivity of electronic band structure to the Pb-I lattices and surface lattice relaxation. The edge emission was just confirmed in a very latest work [75]. But as shown in Fig. 9f–g [75], the edge emission is not due to the intrinsic strain; rather, it is induced by water molecules. Furthermore, the edge emission can also be observed when n = 2. Again, these are just experimental observations, and the underlying structure and mechanism are still not clear and require further research.
3 Problems and Challenges in Revealing the Origin of Luminescence Centers in Lead Halide Perovskites
The current problems in identifying the origin of PL from in-gap luminescence centers are due to relatively large inconsistency in the results of both computational simulations and experimental characterization of lead halide perovskites. The basic properties of lead halide perovskites and expected intrinsic point defects have been studied extensively by using DFT. The first attempts of calculating the band structure of lead halide perovskites using local density functionals (LDA) and generalized gradient approximation (GGA) as GGA-PBE produced band gap values in accordance with the experimental ones. The top of valence band in Cs–Pb–Br 0D, 2D and 3D materials is composed of p-orbitals of Br with contribution from s-orbitals of Pb, whereas the bottom of conduction band is completely based on p-orbitals of Pb. Lead is a heavy metal known to possess strong spin–orbital coupling (SOC). The must-have inclusion of SOC in GGA-PBE calculations, however, results in a strong underestimate of band gap values in these materials. This also influences significantly the energy calculations of the native point defects (vacancies, interstitials and antisites) and defect complexes. The energy-level positions of different defects with respect to the band gap edges change with activating SOC. This makes quite dubious the assignment of certain defects as deep in-gap luminescence centers. The analysis of this problem has found its first solution in 2015 when Du [76] showed that the local density functionals used without SOC produce correct band gap values due to error cancelations [77], whereas inclusion of SOC involves self-interacting errors and requires the use of screened hybrid functionals as Heyd–Scuseria–Ernzerhof (HSE) to reproduce correctly both the band gap and the energy position of defects. Kang and Wang [5] presented the first complete calculations of the formation energy of all type point defects in CsPbBr3 using HSE + SOC. The formation energy of defects was calculated taking into account the Fermi energy and atomic chemical potentials of constituents [78, 79]. Although this work seems to deliver solid results, a few details are alarming and indicate that it may not be the final word on solving problems of modeling defects in lead halide perovskites.
The HSE functional includes a portion of non-local Hartree–Fock (HF) exchange in addition to local GGA-PBE one. The HSE functional partitions the Coulomb operator for a pair of charges into two ranges: short (SR) \(= \left[ {1 - erf\left( {\omega r} \right)} \right]/r\) and long (LR) \(= erf\left( {\omega r} \right)/r\) that are defined and controlled by the range-separation parameter ω set empirically to 0.15 Bohr−1 in the so-called HSE03 [80] version and to 0.11 Bohr−1 in the HSE06 version. HSE incorporates 25% SR HF exchange (mixing parameter, a = 0.25), no LR HF exchange, 75% SR and full LR PBE exchange, and 100% PBE correlation. Test calculations using HSE03 [80] with a = 0.25 and ω = 0.15 Bohr−1 have reproduced well the band gap of a large number of semiconductors [81], that is, HSE is believed to be a universal functional. The band gap of CsPbBr3, however, is calculated correctly using HSE + SOC only with HF exchange portion a set to 0.43 [5]. Recent extension of HSE + SOC to calculations of 2D CsPb2Br3 and 3D Cs4PbBr6 shows that there are no universal HSE06 parameters a and ω that produce the band gaps correctly for all Cs–Pb–Br compounds [26]. The band gap of CsPb2B5 and Cs4PbBr6 is calculated to be close to the experimental one for a = 0.2 [26], that is, different from both a = 0.43 for CsPbBr3 and most importantly different from a = 0.25 of the original HSE06 that has been claimed to be a universal for correct calculations of band gaps in semiconductors. One yet unexplored path is to repeat these calculations with fixed original a = 0.25 in HSE functional and varying the screen parameter ω and then find a physical reason for different screening parameters in Cs–Pb–Br compounds.
The DFT results of defect formation energy calculations of CsPbBr3, CsPb2Br5 and Cs4PbBr6 and the defect energy levels with respect to the energy band gap in these compounds are shown in Fig. 10 [26]. The defect formation energy was calculated in a similar way as in Ref. [5], but the results for some of the defects in CsPbBr3 are different in the two papers. No critical analysis has been done so far on whether this is the most reliable and realistic approach for calculations of the defect formation energy. Apart from the supercell size-independent errors in these calculations as the choice of DFT functional and the choice of exchange correlation potentials discussed above, there are a number of supercell size-dependent errors, e.g., in Ref. [82], that have not been explored yet in the Cs–Pb–Br compounds. There is a need for a more rigorous approach to defect property calculations for the Cs–Pb–Br system in accordance with analyses and prescriptions given in Ref. [83].
The origin of green PL in Cs4PbBr6 is attributed to Br vacancies, VBr (as in Ref. [26]). As shown in Fig. 10c, however, VBr (0/+ 1) cannot be involved in the green PL emission observed in CsPb2Br5. The only candidates for defect mediated PL in CsPb2Br5 are the antisites PbBr and CsBr. Another computational study of CsPb2Br5 [33], however, predicts the positions of unoccupied and occupied levels of VBr (0) to lay at ~ 0.25 and ~ 0.5 eV, respectively, below the conduction band edge. The puzzle of the very similar green PL in CsPb2Br5 and Cs4PbBr6 due to defects remains unsolved. These notes show the complexity involved in the modeling of Cs–Pb–Br compounds and their native point defects and the degree of confidence one may have in the DFT results.
The arguments in favor of green PL in CsPb2Br5 and Cs4PbBr6 due to CsPbBr3 nanocrystal inclusions are better justified experimentally than those in support of native point defects. Indeed, the studies of CsPbBr3 absorption and emission spectra variation with nanocrystal size clearly show a quantum dot size effects with a PL peak position shift from 2.35 eV in bulk crystals to 2.7 eV in ~ 4-nm crystal [28, 84].
The results in Fig. 11 show that typically observed green PL luminescence at 2.35–2.5 eV in CsPb2Br5 and Cs4PbBr6 may well be due to CsPbBr3 nanocrystal inclusions in these wide band gap semiconductors. One way to move forward in revealing the nature of luminescence centers is to provide stronger experimental evidence on the nature of PL centers in Cs–Pb–Br system although this is also challenging as we discuss it below.
4 Designing Combined Experimental Characterization Approaches for Better Consistency
Structure–property relation is the major goal of materials science and engineering. Specifically for the Cs–Pb–Br system one of the important properties is the photoluminescence, while its structure is determined by XRD, TEM and Raman spectroscopy. The last one is an indirect structure-related technique. The major reasons for these structure–property controversies or challenges are the difference in probing length scale and sensitivity. XRD is an average technique and has relatively low phase detection sensitivity. It is sensitive to the minority phase domain size, which below a few hundred nanometers usually diminishes and broadens the related XRD peaks, whereas PL can be emitted even from quantum dots and single molecular inclusions. TEM can provide detailed atomic structures, but there are two major difficulties. The first is that the size of PL and TEM probes are orders of magnitude different. TEM can only probe a much smaller sample, on the order of 100 nm in size; however, micro-PL still require a micrometer-sized sample. The second reason is that perovskite-like materials are very sensitive to electron beams and can get damaged easily, so the structure of perovskite is hard to be studied and advanced low-dose TEM is needed [65].
Raman is a well-established and sensitive technique to identify a material. In addition, Raman is compatible with PL and requires a small sample amount, so Raman can serve both the structure determination and property related to PL. For instance, the non-resonant Raman scattering is structure related, but at resonance it may probe electronic states that concurrently take part in PL. Raman and PL have been separately used in characterizing the luminescent centers, but they were only used for qualitative study, and a combined and calibrated Raman–PL has been missing. The key to such quantitative Raman–PL analysis is the calibrations of both Raman and PL using well-known reference materials. Note that PL is very sensitive to material quality, so a reference sample should be carefully chosen for the combined Raman and PL. For instance, CsPbBr3 nanocrystals can have a PLQY of 60–90% [27,28,29], but the PLQY of CsPbBr3 micropowders can be as low as 0.1%. CsPbBr3 nanocrystals should be used to confirm whether they are the source for green emission. So far, a successful application of combined Raman/PL mapping of the same sample area of CsPb2Br5 was reported in Ref. [23]. In that study, the Raman spectroscopy distinguishes the single crystalline part of CsPb2Br5 [77], which turned out to be non-emissive, from the polycrystalline part that produces green PL.
The optical absorption spectra of Cs–Pb–Br compounds can indicate indirectly, but not for certain, whether the samples are PL emissive or not. A promising alternative approach reported in Ref. [31, 85] uses TEM for structural characterization and energy loss spectroscopy (EELS) in the low-loss region as equivalent of optical absorption in CsPbBr3 and CsPbBr3/Cs4PbBr6. The results of TEM–EELS characterization of CsPbBr3/Cs4PbBr6 nanocrystals are shown in Fig. 12. The main limitations of the EELS technique are the effect of sample thickness, relatively low sensitivity and energy resolution in the low-loss region when compared to optical spectroscopy.
The ultimate technique for structure–property relation is combined TEM-PL on a single nanocrystal [86]. The Raman scattering from ultra-small amount of highly luminescence compounds could be too weak to be detectable. A major challenge is to avoid electron beam-induced damages to perovskites. High-resolution TEM imaging has been used by competing sides to support their arguments, but no such combined study was reported. The observation of CsPbBr3/Cs4PbBr6 nanocomposites certainly cannot exclude possible defect luminescent states; although no apparent CsPbBr3 nanocrystal was found in some single crystals of emissive Cs4PbBr6, PL from the same nanocrystal was actually not demonstrated [19, 51, 55]. More importantly, PL should be performed before and after TEM imaging to ensure no damage has occurred. To reveal the origin of edge states in R–P perovskites [10, 75], the next step is to reproduce the reported results and further determine the factors that are responsible for the edge states. Besides the reported TEM and AFM [75], noninvasive techniques such as Raman and FTIR should be used to identify the structural and chemical changes to the edge lattices [85, 87]. Note that nanometer scale versions of Raman and FTIR are already available to probe local structures [88, 89].
PL, Raman, XRD and TEM are passive techniques; new techniques that can apply external stimulus such as mechanical, electrical, or magnetic force to probe the dynamic response of luminescent centers and distinguish point defect from CsPbBr3 nanocrystals are needed. The challenges and controversies in perovskites have also brought us a great opportunity to test new theory, develop new experimental techniques and eventually provide us new understanding and insight to develop and engineer better materials for a wide range of optoelectronic device applications.
References
Y.X. Zhao, K. Zhu, Organic-inorganic hybrid lead halide perovskites for optoelectronic and electronic applications. Chem. Soc. Rev. 45(3), 655–689 (2016). https://doi.org/10.1039/c4cs00458b
J. Huang, Y. Yuan, Y. Shao, Y. Yan, Understanding the physical properties of hybrid perovskites for photovoltaic applications. Nat. Rev. Mater. 2, 17042 (2017). https://doi.org/10.1038/natrevmats.2017.42
J.W. Xiao, L. Liu, D.L. Zhang, N. De Marco, J.W. Lee, O. Lin, Q. Chen, Y. Yang, The emergence of the mixed perovskites and their applications as solar cells. Adv. Energy Mater. 7, 1700491 (2017). https://doi.org/10.1002/aenm.201700491
H.M. Zhu, Y.P. Fu, F. Meng, X.X. Wu, Z.Z. Gong et al., Lead halide perovskite nanowire lasers with low lasing thresholds and high quality factors. Nat. Mater. 14, 636–642 (2015). https://doi.org/10.1038/nmat4271
J. Kang, L.W. Wang, High defect tolerance in lead halide perovskite CsPbBr3. J. Phys. Chem. Lett. 8, 489–493 (2017). https://doi.org/10.1021/acs.jpclett.6b02800
H.R. Lin, C.K. Zhou, Y. Tian, T. Siegrist, B.W. Ma, Low-dimensional organometal halide perovskites. ACS Energy Lett. 3, 54–62 (2018). https://doi.org/10.1021/acsenergylett.7600926
D. Han, C.M. Dai, S.Y. Chen, Calculation studies on point defects in perovskite solar cells. J. Semicond. 38, 011006 (2017). https://doi.org/10.1088/1674-4926/38/1/011006
S. Gonzalez-Carrero, R.E. Galian, J. Perez-Prieto, Organometal halide perovskites: bulk low-dimension materials and nanoparticles. Part. Part. Syst. Charact. 32, 709–720 (2015). https://doi.org/10.1002/ppsc.201400214
K. Hong, Q.V. Le, S.Y. Kim, H.W. Jang, Low-dimensional halide perovskites: review and issues. J. Mater. Chem. C 6, 2189–2209 (2018). https://doi.org/10.1039/c7tc05658c
J.C. Blancon, H. Tsai, W. Nie, C.C. Stoumpos, L. Pedesseau et al., Extremely efficient internal exciton dissociation through edge states in layered 2D perovskites. Science 355, 1288–1291 (2017). https://doi.org/10.1126/science.aal4211
M.I. Saidaminov, J. Almutlaq, S. Sarmah, I. Dursun, A.A. Zhumekenov et al., Pure Cs4PbBr6: highly luminescent zero dimensional perovskite solids. ACS Energy Lett. 1, 840–845 (2016). https://doi.org/10.1021/acsenergylett.6b00396
I. Dursun, M.D. Bastiani, B. Turedi, B. Alamer, A. Shkurenko et al., CsPb2Br5 single crystals: synthesis and characterization. Chemsuschem 10, 3746–3749 (2017). https://doi.org/10.1002/cssc.201701131
Z. Zhang, Y. Zhu, W. Wang, W. Zheng, R. Lin, F. Huang, Growth, characterization and optoelectronic applications of pure-phase large-area CsPb2Br5 flake single crystals. J. Mater. Chem. C 6, 446–451 (2018). https://doi.org/10.1039/c7tc04834c
J. Li, H.J. Zhang, S. Wang, D.B. Long, M.K. Li et al., Synthesis of all-inorganic CsPb2Br5 perovskite and determination of its luminescence mechanism. RSC Adv. 7, 54002–54007 (2017). https://doi.org/10.1039/c7ra10693a
Q.A. Akkerman, A.L. Abdelhady, L. Manna, Zero-dimensional cesium lead halides: history, properties, and challenges. J. Phys. Chem. Lett. 9, 2326–2337 (2018). https://doi.org/10.1021/acs.jpclett.8b00572
D. Han, H.L. Shi, W.M. Ming, C.K. Zhou, B.W. Ma et al., Unraveling luminescence mechanisms in zero-dimensional halide perovskites. J. Mater. Chem. C 6, 6398–6405 (2018). https://doi.org/10.1039/c8tc01291a
X.Z. Min, P.C. Zhu, S. Gu, J. Zhu, Research progress of low-dimensional perovskites: synthesis, properties and optoelectronic applications. J. Semicond. 38, 011004 (2017). https://doi.org/10.1088/1674-4926/38/1/011004
R. Guo, Z.A. Zhu, A. Boulesbaa, F. Hao, A. Puretzky et al., Synthesis and photoluminescence properties of 2D phenethylammonium lead bromide perovskite nanocrystals. Small Methods 1, 1700245 (2017). https://doi.org/10.1002/smtd.201700245
K.H. Wang, L. Wu, L. Li, H.B. Yao, H.S. Qian, S.H. Yu, Large-scale synthesis of highly luminescent perovskite-related CsPb2Br5 nanoplatelets and their fast anion exchange. Angew. Chem. Int. Ed. 55, 8328–8332 (2016). https://doi.org/10.1002/anie.201602787
B. Turedi, K.J. Lee, I. Dursun, B. Alamer, Z.N. Wu et al., Water-induced dimensionality reduction in metal-halide perovskites. J. Phys. Chem. C 122, 14128–14134 (2018). https://doi.org/10.1021/acs.jpcc.8b01343
X.L. Zhang, B. Xu, J.B. Zhang, Y. Gao, Y.J. Zheng, K. Wang, X.W. Sun, All-inorganic perovskite nanocrystals for high-efficiency light emitting diodes: dual-phase CsPbBr3–CsPb2Br5 composites. Adv. Funct. Mater. 26, 4595–4600 (2016). https://doi.org/10.1002/adfm.201600958
G.P. Li, H. Wang, Z.F. Zhu, Y.J. Chang, T. Zhang, Z.H. Song, Y. Jiang, Shape and phase evolution from CsPbBr3 perovskite nanocubes to tetragonal CsPb2Br5 nanosheets with an indirect bandgap. Chem. Commun. 52, 11296–11299 (2016). https://doi.org/10.1039/c6cc05877a
Y. Wang, C. Wang, X. Su, V.G. Hadjiev, H.A.C. Benavides et al., Bright luminescent surface states on the edges of wide-bandgap two-dimensional lead halide perovskite. arXiv: 180311490 (2018)
K.J.L.B. Turedi, I. Dursun, B. Alamer, Z. Wu, E. Alarousu et al., Water-induced dimensionality reduction in metal-halide perovskites. J. Phys. Chem. C 122, 14128–14134 (2018). https://doi.org/10.1021/acs.jpcc.8b01343
S. Seth, A. Samanta, Photoluminescence of zero-dimensional perovskites and perovskite-related materials. J. Phys. Chem. Lett. 9, 176–183 (2018). https://doi.org/10.1021/acs.jpclett.7b02931
J. Yin, H. Yang, K. Song, A.M. El-Zohry, Y. Han, O.M. Bakr, J.L. Bredas, O.F. Mohammed, Point defects and green emission in zero-dimensional perovskites. J. Phys. Chem. Lett. 9, 5490–5495 (2018). https://doi.org/10.1021/acs.jpclett.8b02477
J.Z. Song, J.H. Li, X.M. Li, L.M. Xu, Y.H. Dong, H.B. Zeng, Quantum dot light-emitting diodes based on inorganic perovskite cesium lead halides (CsPbX3). Adv. Mater. 27, 7162 (2015). https://doi.org/10.1002/adma.201502567
L. Protesescu, S. Yakunin, M.I. Bodnarchuk, F. Krieg, R. Caputo et al., Nanocrystals of cesium lead halide perovskites (CsPbX3, X = Cl, Br, and I): novel optoelectronic materials showing bright emission with wide color gamut. Nano Lett. 15, 3692–3696 (2015). https://doi.org/10.1021/nl5048779
H.C. Wang, S.Y. Lin, A.C. Tang, B.P. Singh, H.C. Tong et al., Mesoporous silica particles integrated with all-inorganic CsPbBr3 perovskite quantum-dot nanocomposites (MP-PQDs) with high stability and wide color gamut used for backlight display. Angew. Chem. Int. Ed. 55, 7924–7929 (2016). https://doi.org/10.1002/anie.201603698
Z.K. Liu, Y. Bekenstein, X.C. Ye, S.C. Nguyen, J. Swabeck et al., Ligand mediated transformation of cesium lead bromide perovskite nanocrystals to lead depleted Cs4PbBr6 nanocrystals. J. Am. Chem. Soc. 139, 5309–5312 (2017). https://doi.org/10.1021/jacs.7b01409
C. de Weerd, J.H. Lin, L. Gomez, Y. Fujiwara, K. Suenaga, T. Gregorkiewicz, Hybridization of single nanocrystals of Cs4PbBr6 and CsPbBr3. J. Phys. Chem. C 121, 19490–19496 (2017). https://doi.org/10.1021/acs.jpcc.7b05752
L. Yang, D.M. Li, C. Wang, W. Yao, H. Wang, K.X. Huang, Room-temperature synthesis of pure perovskite-related Cs4PbBr6 nanocrystals and their ligand-mediated evolution into highly luminescent CsPbBr3 nanosheets. J. Nanopart. Res. 19, 258 (2017). https://doi.org/10.1007/s11051-017-3959-7
F. Iyikanat, E. Sari, H. Sahin, Thinning CsPb2Br5 perovskite down to monolayers: Cs-dependent stability. Phys. Rev. B 96, 155442 (2017). https://doi.org/10.1103/PhysRevB.96.155442
J.W. Xu, W.X. Huang, P.Y. Li, D.R. Onken, C.C. Dun et al., Imbedded nanocrystals of CsPbBr3 in Cs4PbBr6: kinetics, enhanced oscillator strength, and application in light-emitting. Adv. Mater. 29, 1703703 (2017). https://doi.org/10.1002/adma.1703703
Y. Bekenstein, B.A. Koscher, S.W. Eaton, P.D. Yang, A.P. Alivisatos, Highly luminescent colloidal nanoplates of perovskite cesium lead halide and their oriented assemblies. J. Am. Chem. Soc. 137, 16008–16011 (2015). https://doi.org/10.1021/jacs.5b11199
D.D. Zhang, S.W. Eaton, Y. Yu, L.T. Dou, P.D. Yang, Solution-phase synthesis of cesium lead halide perovskite nanowires. J. Am. Chem. Soc. 137, 9230–9233 (2015). https://doi.org/10.1021/jacs.5b05404
C.K. Zhou, Y. Tian, M.C. Wang, A. Rose, T. Besara et al., Low-dimensional organic tin bromide perovskites and their photoinduced structural transformation. Angew. Chem. Int. Ed. 56, 9018–9022 (2017). https://doi.org/10.1002/anie.201702825
H.L.C. Zhou, Q. He, L. Xu, M. Worku, M. Chaaban et al., Low dimensional metal halide perovskites and hybrids. Mater. Sci. Eng. R137, 38–65 (2019). https://doi.org/10.1016/j.mser.2018.12.001
P. Zhang, G.D. Zhang, L. Liu, D.X. Ju, L.Z. Zhang, K. Cheng, X.T. Tao, Anisotropic optoelectronic properties of melt-grown bulk CsPbBr3 single crystal. J. Phys. Chem. Lett. 9, 5040–5046 (2018). https://doi.org/10.1021/acs.jpclett.8b01945
M.Z. Zhang, Z.P. Zheng, Q.Y. Fu, P.J. Guo, S. Zhang et al., Determination of defect levels in melt-grown all-inorganic perovskite CsPbBr3 crystals by thermally stimulated current spectra. J. Phys. Chem. C 122, 10309–10315 (2018). https://doi.org/10.1021/acs.jpcc.8b01532
M. Rodova, J. Brozek, K. Knizek, K. Nitsch, Phase transitions in ternary caesium lead bromide. J. Therm. Anal. Calorim. 71, 667–673 (2003). https://doi.org/10.1023/a:1022836800820
F.J. Ye, W.Q. Yang, D.Y. Luo, R. Zhu, Q.H. Gong, Applications of cesium in the perovskite solar cells. J. Semicond. 38, 011003 (2017). https://doi.org/10.1088/1674-4926/38/1/011003
Q.S. Sun, C.L. Ni, Y.C. Yu, S. Attique, S.Y. Wei et al., Design principle of all-inorganic halide perovskite-related nanocrystals. J. Mater. Chem. C 6, 12484–12492 (2018). https://doi.org/10.1039/c8tc04254c
Z.J. Zhang, Y.M. Zhu, W.L. Wang, W. Zheng, R.C. Lin et al., Aqueous solution growth of millimeter-sized nongreen-luminescent wide bandgap Cs4PbBr6 bulk crystal. Cryst. Growth Des. 18, 6393–6398 (2018). https://doi.org/10.1021/acs.cgd.8b00817
W. Shen, L.F. Ruan, Z.T. Shen, Z.T. Deng, Reversible light-mediated compositional and structural transitions between CsPbBr3 and CsPb2Br5 nanosheets. Chem. Commun. 54, 2804–2807 (2018). https://doi.org/10.1039/c8cc00139a
M. Cola, V. Massarot, R. Riccardi, C. Sinistri, Binary systems formed by lead bromide with (Li, Na, K, Rb, Cs and Tl)Br: a DTA and diffractometric study. Zeitschrift für Naturforschung A A 26(8), 1328–1332 (1971). https://doi.org/10.1515/zna-1971-0812
X.S. Tang, Z.P. Hu, W. Yuan, W. Hu, H.B. Shao et al., Perovskite CsPb2Br5 microplate laser with enhanced stability and tunable properties. Adv. Opt. Mater. 5, 1600788 (2017). https://doi.org/10.1002/adom.201600788
L. Ruan, W. Shen, A. Wang, A. Xiang, Z. Deng, Alkyl-thiol ligands induced shape and crystalline phase controlled synthesis of stable perovskite-related CsPb2Br5 nanocrystals at room temperature. J. Phys. Chem. Lett. 8, 3853–3860 (2017). https://doi.org/10.1021/acs.jpclett.7b01657
P.Z. Li, C.B. Hu, L. Zhou, J.T. Jiang, Y.Z. Cheng, M.L. He, X.J. Liang, W.D. Xiang, Novel synthesis and optical characterization of CsPb2Br5 quantum dots in borosilicate glasses. Mater. Lett. 209, 483–485 (2017). https://doi.org/10.1016/j.matlet.2017.08.079
C.J. Qin, T. Matsushima, A.S.D. Sandanayaka, Y. Tsuchiya, C. Adachi, Centrifugal-coated quasi-two-dimensional perovskite CsPb2Br5 films for efficient and stable light-emitting diodes. J. Phys. Chem. Lett. 8, 5415–5421 (2017). https://doi.org/10.1021/acs.jpclett.7b02371
J.F. Lv, L.L. Fang, J.Q. Shen, Synthesis of highly luminescent CsPb2Br5 nanoplatelets and their application for light-emitting diodes. Mater. Lett. 211, 199–202 (2018). https://doi.org/10.1016/j.matlet.2017.09.106
C. Han, C.L. Li, Z.G. Zang, M. Wang, K. Sun, X.S. Tang, J.H. Du, Tunable luminescent CsPb2Br5 nanoplatelets: applications in light-emitting diodes and photodetectors. Photonics Res. 5, 473–480 (2017). https://doi.org/10.1364/prj.5.000473
P.Z. Li, Y.Z. Cheng, L. Zhou, X.Q. Yu, J.T. Jiang, M.L. He, X.J. Liang, W.D. Xiang, Photoluminescence properties and device application dots in glasses of CsPb2Br5 quantum dots in glasses. Mater. Res. Bull. 105, 63–67 (2018). https://doi.org/10.1016/j.materresbull.2018.04.028
K.W. Wu, A. Bera, C. Ma, Y.M. Du, Y. Yang, L. Li, T. Wu, Temperature-dependent excitonic photoluminescence of hybrid organometal halide perovskite films. Phys. Chem. Chem. Phys. 16, 22476–22481 (2014). https://doi.org/10.1039/c4cp03573a
L.F. Ruan, J. Lin, W. Shen, Z.T. Deng, Ligand-mediated synthesis of compositionally related cesium lead halide CsPb2X5 nanowires with improved stability. Nanoscale 10, 7658–7665 (2018). https://doi.org/10.1039/c8nr00883c
F. Palazon, S. Dogan, S. Marras, F. Locardi, I. Nelli et al., From CsPbBr3 nano-inks to sintered CsPbBr3–CsPb2Br5 films via thermal annealing: implications on optoelectronic properties. J. Phys. Chem. C 121, 11956–11961 (2017). https://doi.org/10.1021/acs.jpcc.7b03389
B. Qiao, P.J. Song, J.Y. Cao, S.L. Zhao, Z.H. Shen et al., Water-resistant, monodispersed and stably luminescent CsPbBr3/CsPb2Br5 core-shell-like structure lead halide perovskite nanocrystals. Nanotechnology 28, 445602 (2017). https://doi.org/10.1088/1361-6528/aa892e
S.K. Balakrishnan, P.V. Kamat, Ligand assisted transformation of cubic CsPbBr3 nanocrystals into two-dimensional CsPb2Br5 nanosheets. Chem. Mater. 30, 74–78 (2017). https://doi.org/10.1021/acs.chemmater.7b04142
C.K. Zhou, Y. Tian, Z. Yuan, H.R. Lin, B.H. Chen et al., Highly efficient broadband yellow phosphor based on zero-dimensional tin mixed-halide perovskite. ACS Appl. Mater. Interfaces 9, 44579–44583 (2017). https://doi.org/10.1021/acsami.7b12862
C.K. Zhou, H.R. Lin, Y. Tian, Z. Yuan, R. Clark et al., Luminescent zero-dimensional organic metal halide hybrids with near-unity quantum efficiency. Chem. Sci. 9, 586–593 (2018). https://doi.org/10.1039/c7sc04539e
J. Yin, P. Maity, M. De Bastiani, I. Dursun, O.M. Bakr, J.L. Bredas, O.F. Mohammed, Molecular behavior of zero-dimensional perovskites. Sci. Adv. 3, e1701793 (2017). https://doi.org/10.1126/sciadv.1701793
J. Yin, Y.H. Zhang, A. Bruno, C. Soci, O.M. Bakr, J.L. Bredas, O.F. Mohammed, Intrinsic lead ion emissions in zero-dimensional Cs4PbBr6 nanocrystals. ACS Energy Lett. 2, 2805–2811 (2017). https://doi.org/10.1021/acsenergylett.7b01026
M. De Bastiani, I. Dursun, Y.H. Zhang, B.A. Alshankiti, X.H. Miao et al., Inside perovskites: quantum luminescence from bulk Cs4PbBr6 single crystals. Chem. Mater. 29, 7108–7113 (2017). https://doi.org/10.1021/acs.chemmater.7b02415
J. Almutlaq, J. Yin, O.F. Mohammed, O.M. Bakr, The benefit and challenges of zero-dimensional perovskites. J. Phys. Chem. Lett. 9, 4131–4138 (2018). https://doi.org/10.1021/acs.jpclett.8b00532
Y. Zhang, L. Sinatra, E. Alarousu, J. Yin, A.M. El-Zohry, O.M. Bakr, O.F. Mohammed, Ligand-free nanocrystals of highly emissive Cs4PbBr6 perovskite. J. Phys. Chem. C 122, 6493–6498 (2018). https://doi.org/10.1021/acs.jpcc.8b01735
J.H. Cha, J.H. Han, W. Yin, C. Park, Y. Park et al., Photoresponse of CsPbBr3 and Cs4PbBr6 perovskite single crystals. J. Phys. Chem. Lett. 8, 565–570 (2017). https://doi.org/10.1021/acs.jpclett.6b02763
D.Q. Chen, Z.Y. Wan, X. Chen, Y.J. Yuan, J.S. Zhong, Large-scale room-temperature synthesis and optical properties of perovskite-related Cs4PbBr6 fluorophores. J. Mater. Chem. C 4, 10646–10653 (2016). https://doi.org/10.1039/c6tc04036e
S. Seth, A. Samanta, Fluorescent phase-pure zero-dimensional perovskite-related Cs4PbBr6 microdisks: synthesis and single-particle imaging study. J. Phys. Chem. Lett. 8, 4461–4467 (2017). https://doi.org/10.1021/acs.jpclett.7b02100
Z.J. Zhang, W. Zheng, R.C. Lin, F. Huang, One-step on-chip synthesis of highly-luminescent Cs4PbBr6 microcrystal. Mater. Lett. 232, 118–121 (2018). https://doi.org/10.1016/j.matlet.2018.08.083
W.K. Wang, D.F. Wang, F. Fang, S. Wang, G.H. Xu, T.J. Zhang, CsPbBr3/Cs4PbBr6 nanocomposites: formation mechanism, large-scale and green synthesis, and application in white light-emitting diodes. Cryst. Growth Des. 18, 6133–6141 (2018). https://doi.org/10.1021/acs.cgd.8b01013
Q.A. Akkerman, S. Park, E. Radicchi, F. Nunzi, E. Mosconi et al., Nearly monodisperse insulator Cs4PbX6 (X = Cl, Br, I) nanocrystals, their mixed halide compositions, and their transformation into CsPbX3 nanocrystals. Nano Lett. 17, 1924–1930 (2017). https://doi.org/10.1021/acs.nanolett.6b05262
X.M. Chen, F. Zhang, Y. Ge, L.F. Shi, S. Huang et al., Centimeter-sized Cs4PbBr6 crystals with embedded CsPbBr3 nanocrystals showing superior photoluminescence: nonstoichiometry induced transformation and light-emitting applications. Adv. Funct. Mater. 28, 1706567 (2018). https://doi.org/10.1002/adfm.201706567
M. Kepenekian, B. Traore, J.C. Blancon, L. Pedesseau, H. Tsai et al., Concept of lattice mismatch and emergence of surface states in two-dimensional hybrid perovskite quantum wells. Nano Lett. 18, 5603–5609 (2018). https://doi.org/10.1021/acs.nanolett.8b02078
K. Leng, I. Abdelwahab, I. Verzhbitskiy, M. Telychko, L.Q. Chu et al., Molecularly thin two-dimensional hybrid perovskites with tunable optoelectronic properties due to reversible surface relaxation. Nat. Mater. 17, 908 (2018). https://doi.org/10.1038/s41563-018-0164-8
E. Shi, S. Deng, B. Yuan, Y. Gao, Akriti et al., Extrinsic and dynamic edge states of two-dimensional lead halide perovskites. ACS Nano (2019). https://doi.org/10.1021/acsnano.8b07631
M.H. Du, Density functional calculations of native defects in CH3NH3Pbl3: effects of spin-orbit coupling and self-interaction error. J. Phys. Chem. Lett. 6, 1461–1466 (2015). https://doi.org/10.1021/acs.jpclett.5b00199
E. Mosconi, A. Amat, M.K. Nazeeruddin, M. Gratzel, F. De Angelis, First-principles modeling of mixed halide organometal perovskites for photovoltaic applications. J. Phys. Chem. C 117, 13902–13913 (2013). https://doi.org/10.1021/jp4048659
S.B. Zhang, S.H. Wei, Nitrogen solubility and induced defect complexes in epitaxial GaAs: N. Phys. Rev. Lett. 86, 1789–1792 (2001). https://doi.org/10.1103/PhysRevLett.86.1789
S.H. Wei, S.B. Zhang, Chemical trends of defect formation and doping limit in II–VI semiconductors: the case of CdTe. Phys. Rev. B 66, 155211 (2002). https://doi.org/10.1103/PhysRevB.66.155211
J. Heyd, G.E. Scuseria, M. Ernzerhof, Hybrid functionals based on a screened Coulomb potential. J. Chem. Phys. 118, 8207–8215 (2003). https://doi.org/10.1063/1.1564060
J. Heyd, J.E. Peralta, G.E. Scuseria, R.L. Martin, Energy band gaps and lattice parameters evaluated with the Heyd–Scuseria–Ernzerhof screened hybrid functional. J. Chem. Phys. 123, 174101 (2005). https://doi.org/10.1063/1.2085170
C.W.M. Castleton, A. Hoglund, S. Mirbt, Density functional theory calculations of defect energies using supercells. Model. Simul. Mater. Sci. Eng. 17, 084003 (2009). https://doi.org/10.1088/0965-0393/17/8/084003
C. Freysoldt, B. Grabowski, T. Hickel, J. Neugebauer, G. Kresse, A. Janotti, C.G. Van de Walle, First-principles calculations for point defects in solids. Rev. Mod. Phys. 86, 253 (2014). https://doi.org/10.1103/RevModPhys.86.253
M.C. Brennan, J.E. Herr, T.S. Nguyen-Beck, J. Zinna, S. Draguta, S. Rouvimov, J. Parkhill, M. Kuno, Origin of the size-dependent stokes shift in CsPbBr3 perovskite nanocrystals. J. Am. Chem. Soc. 139, 12201–12208 (2017). https://doi.org/10.1021/jacs.7b05683
V.G. Hadjiev, C. Wang, Y. Wang, X. Su, H.A. Calderon et al., Phonon fingerprints of CsPb2Br5. J. Phys.: Condes. Matter 30, 405703 (2018). https://doi.org/10.1088/1361-648X/aadeb4
J.M. Bao, D.C. Bell, F. Capasso, J.B. Wagner, T. Martensson, J. Tragardh, L. Samuelson, Optical properties of rotationally twinned InP nanowire heterostructures. Nano Lett. 8, 836–841 (2008). https://doi.org/10.1021/nl072921e
Z. Zhu, V.G. Hadjiev, Y.G. Rong, R. Guo, B. Cao et al., Interaction of organic cation with water molecule in perovskite MAPbI3: from dynamic orientational disorder to hydrogen bonding. Chem. Mater. 28, 7385–7393 (2016). https://doi.org/10.1021/acs.chemmater.6b02883
A. Dazzi, C.B. Prater, AFM-IR: Technology and applications in nanoscale infrared spectroscopy and chemical imaging. Chem. Rev. 117, 5146–5173 (2017). https://doi.org/10.1021/acs.chemrev.6b00448
G. Kolhatkar, J. Plathier, A. Ruediger, Nanoscale investigation of materials, chemical reactions, and biological systems by tip enhanced Raman spectroscopy—a review. J. Mater. Chem. C 6, 1307–1319 (2018). https://doi.org/10.1039/c7tc05688e
Acknowledgements
JM Bao acknowledges support from the Robert A. Welch Foundation (E-1728) and National Science Foundation (EEC-1530753). VG Hadjiev’s work was supported by the State of Texas through the Texas Center for superconductivity at the University of Houston.
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
Open Access This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
About this article
Cite this article
Bao, J., Hadjiev, V.G. Origin of Luminescent Centers and Edge States in Low-Dimensional Lead Halide Perovskites: Controversies, Challenges and Instructive Approaches. Nano-Micro Lett. 11, 26 (2019). https://doi.org/10.1007/s40820-019-0254-4
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s40820-019-0254-4