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Thermodynamic and Electrochemical Analysis of Synergistic Corrosion Inhibition Performance of Natural Polysaccharides with Metal Halides on Mild Steel in Hydrochloric Acid Solution

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Abstract

The effect of synergistic corrosion inhibition efficiency of Azadirachta indica gum with halides (KCl, KBr and KI) on mild steel in 1 mol L−1 HCl was studied using conventional weight loss and electrochemical studies. The temperature (303–328 ± 1 K) and time (1, 2, 3, 4, 6 and 24 h) effect on the inhibition of corrosion has also been tested. The inhibition efficiency of gum exudates of Azadirachta indica considerably increased with the presence of halide ions at all temperature ranges studied. Corrosion kinetic parameters and thermodynamic adsorption parameters were calculated and discussed in detail. The mode of adsorption of inhibitor on the mild steel surface was examined by FT-IR spectroscopy.

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Authors and Affiliations

  1. Nehru Institute of Engineering and Technology, Coimbatore, Tamil Nadu, 641105, India

    T. Brindha

  2. Nehru Institute of Technology, Coimbatore, Tamil Nadu, India

    K. Parimalagandhi

  3. PSG College of Arts and Science, Coimbatore, Tamil Nadu, 641104, India

    J. Mallika

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  1. T. Brindha
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  2. K. Parimalagandhi
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  3. J. Mallika
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Correspondence to T. Brindha.

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Brindha, T., Parimalagandhi, K. & Mallika, J. Thermodynamic and Electrochemical Analysis of Synergistic Corrosion Inhibition Performance of Natural Polysaccharides with Metal Halides on Mild Steel in Hydrochloric Acid Solution. J Bio Tribo Corros 6, 3 (2020). https://doi.org/10.1007/s40735-019-0296-7

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  • DOI: https://doi.org/10.1007/s40735-019-0296-7

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