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Influence of Cr on the electronic properties of passive film on B30 alloy in NaOH solution

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Abstract

The influence of Cr on the electronic properties of the passive film on B30 alloy in NaOH solution was studied via electrochemical impedance spectra(EIS), potentiodynamic curve and Mott-Schottky plot. The Cr doped in the passive film on B30 alloy was detected by X-ray photoelectron spectroscopy(XPS). XPS results show that Cr2O3 appeared on the passive film, which implied the enhanced anti-corrosion of B30 alloy. The passive film showed a p-type semi-conductive character. The acceptor density(NA) was in an order of magnitude of 1022 cm−3, and N A decreased with the increment of Cr. EIS results show that the film resistance(R f) increased with increasing the amount of Cr. The diffusion coefficient(D 0) was calculated to be in a range of 10−16−10−17 cm−2/s on the basement of point defect model(PDM).

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References

  1. Kammlott G. W., Franey J. P., Gradel T. E., J. Electrochem. Soc., 1992, 131, 505

    Article  Google Scholar 

  2. Wojtas H., Virtanen S., Bohni H., Corro. Sci., 1995, 37, 793

    Article  CAS  Google Scholar 

  3. Sanderson M. D., Scully J. C., Corro. Sci., 1970, 10, 165

    Article  CAS  Google Scholar 

  4. Benedetti A. V., Sumodjo P. T. A., Nobe K., Caqbot P. L., Proud W. G., Electrochim. Acta, 1995, 40, 2657

    Article  CAS  Google Scholar 

  5. Rosatto S. S., Cabot P. L., Sumodjo P. T. A., Benedetti A. V., Electrochim. Acta, 2001, 46, 1043

    Article  CAS  Google Scholar 

  6. Manfeld F., Liu G., Xiao H., Tsai C. H., Little B. J., Corro. Sci., 1994, 36, 2063

    Article  Google Scholar 

  7. Druska P., Strehblow H. H., Corro. Sci., 1996, 38, 1369

    Article  CAS  Google Scholar 

  8. Milosev I., Metikos-Hukovic M., Electrochim. Acta, 1997, 42, 1537

    Article  CAS  Google Scholar 

  9. Milosev I., Metikos-Hukovic M., Corro. Sci., 1992, 48, 185

    Article  CAS  Google Scholar 

  10. De P. K., Bose A., Corro., 1993, 49, 135

    Article  CAS  Google Scholar 

  11. Cristiani P., Perboni G., Debenedetti A., Electrochim. Acta, 2008, 54, 100

    Article  CAS  Google Scholar 

  12. Yuan S. J., Pehkonen S. O., Corro. Sci., 2007, 49, 1276

    Article  CAS  Google Scholar 

  13. Schrader M. E., Appl. Sur. Sci., 1982, 10, 431

    Article  CAS  Google Scholar 

  14. Hurtado M. R. F., Sumodio P. T. A., Benedetti A. V., Electrochim. Acta, 2003, 48, 2791

    Article  CAS  Google Scholar 

  15. Swartzendnruber L. J., Bennett L. H., Scripta Metallurgica, 1968, 2, 93

    Article  Google Scholar 

  16. Popplewell J. M., Hart R. J., Ford J. A., Corro. Sci., 1973, 13, 295

    Article  CAS  Google Scholar 

  17. Wang Y. Z., Beccaria A. M., Poggi G., Corro. Sci., 1994, 36, 1277

    Article  CAS  Google Scholar 

  18. Druska P., Strehblow H. H., Golledge S., Corro. Sci., 1996, 38, 835

    Article  CAS  Google Scholar 

  19. Boudin S., Vignes J. L., Orang G. L., Da Cunha Belo M., Blondiaux G., Mikhailov S. M., Jacobs J. P., Brongersma H. H., Surf. Interface Anal., 1994, 22, 462

    Article  CAS  Google Scholar 

  20. Jabs T., Borthen P., Strehblow H. H., J. Electrochem. Soc., 1997, 144, 1231

    Article  CAS  Google Scholar 

  21. Lorang G., Jallerat N., Vu Quang K., Langeron J. P., Surf. Interface Anal., 1990, 16, 325

    Article  CAS  Google Scholar 

  22. Marcus P., Grimal J. M., Corro. Sci., 1992, 33, 805

    Article  CAS  Google Scholar 

  23. Haupt S., Strehblow H. H., Corro. Sci., 1995, 37, 37

    Google Scholar 

  24. Wu B. J., Liu X. Q., Xiao P., Wang S. G., Chem. Res. Chinese Universities, 2008, 24(24), 615

    Article  CAS  Google Scholar 

  25. Nakaoka N., Ueyama J., Ogura K., J. Electroanal. Chem., 2004, 571, 93

    Article  CAS  Google Scholar 

  26. Martini E. M. A., Muller I. L., Corro. Sci., 2000, 42, 443

    Article  CAS  Google Scholar 

  27. Wallinder D., Pan J., Lergraf C., Delblane-Bauer A., Corro. Sci., 1999, 41, 275

    Article  CAS  Google Scholar 

  28. Juttner K., Electrochim. Acta, 1990, 35, 1501

    Article  Google Scholar 

  29. Alves V. A., Brett Christopher M. A., Electrochim. Acta, 2002, 47, 2081

    Article  CAS  Google Scholar 

  30. Asami K., Hashimoto K., Shimodaira S., Corro. Sci., 1978, 18, 551

    Google Scholar 

  31. Schmuki P., J. Solid State Electrochem., 2002, 6, 145

    Article  CAS  Google Scholar 

  32. Lorang G., Da Cunha Belo M., Simoes A. M. P., Ferreira M. G. S., J. Electrochem. Soc., 1994, 141, 3347

    Article  CAS  Google Scholar 

  33. Atkins P. W., Physical Chemistry, Oxford University Press, Oxford, 1994

    Google Scholar 

  34. Morrison S. R., Electrochemistry at Semiconductor and Oxidized Electrodes, Plenum Press, New York, 1980

    Book  Google Scholar 

  35. Hakiki N. E., Da Cunha Belo M., J. Electrochem. Soc., 1996, 143, 3088

    Article  CAS  Google Scholar 

  36. Nogami G., J. Electrochem. Soc., 1982, 129, 2219

    Article  CAS  Google Scholar 

  37. Harrington S. P., Devine T. M., J. Electrochem. Soc., 2008, 155, C381

    Article  Google Scholar 

  38. Di Quarto F., Di Paola A., Sunseri C., J. Electrochem. Soc., 1980, 127, 1016

    Article  CAS  Google Scholar 

  39. Maximovitch S., Electrochim. Acta, 1996, 41, 2767

    Article  Google Scholar 

  40. Macdonald D. D., J. Electrochem. Soc., 1992, 139, 3434

    Article  CAS  Google Scholar 

  41. Macdonald D. D., Biaggio S. R., Song H. K., J. Electrochem. Soc., 1992, 139, 170

    Article  CAS  Google Scholar 

  42. Macdonald D. D., Macdonald M. U., J. Electrochem. Soc., 1990, 137, 2395

    Article  CAS  Google Scholar 

  43. Bojinov M., Electrochim. Acta, 1997, 42, 3489

    Article  CAS  Google Scholar 

  44. Baruffaldi C., Casellato U., Cattarin S., Musiani M., Tribollet B., Vercelli B., Electrochim. Acta, 2002, 47, 2989

    Article  CAS  Google Scholar 

  45. Azumi K., Ohtsuka T., Sato N., J. Electrochem. Soc., 1987, 134, 1352

    Article  CAS  Google Scholar 

  46. Segal R. L., Smart R., Tumer P. S., Surface and New Surface Chemistry of Oxide Materials, Elsevier, Amsterdam, 1988

    Google Scholar 

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Authors and Affiliations

  1. Xi’an Changqing Technology & Engineering Co., Ltd., Xi’an, 710018, P. R. China

    Yongbin Shang

  2. Oil & Gas Technology Institute, Changqing Oil Field Company, Xi’an, 710018, P. R. China

    Shuqin Xiao, Xiaolin Qiu & Yaming Wei

  3. National Engineering Laboratory for Exploration and Development of Low-permeability Oil & Gas Fields, Xi’an, 710018, P. R. China

    Shuqin Xiao, Xiaolin Qiu & Yaming Wei

Authors
  1. Yongbin Shang
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  2. Shuqin Xiao
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  3. Xiaolin Qiu
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  4. Yaming Wei
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Correspondence to Yongbin Shang.

Additional information

Supported by the Project of Enhanced Oil Recovery of Ground Technology Research of Changqing Oilfield, China (No.2012-E23).

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Shang, Y., Xiao, S., Qiu, X. et al. Influence of Cr on the electronic properties of passive film on B30 alloy in NaOH solution. Chem. Res. Chin. Univ. 31, 603–610 (2015). https://doi.org/10.1007/s40242-015-4469-8

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  • DOI: https://doi.org/10.1007/s40242-015-4469-8

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