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Synthesis, characterization, crystal structure determination, catalytic activity and thermal study of a new oxidovanadium(IV) Schiff base complex: production of V2O5 nano-particles

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Abstract

A new oxidovanadium(IV) Schiff base complex, VOL2 (1), containing furfuryl pendant group was synthesized by the reaction of the related bidentate O, N-type Schiff base ligand and VO(acac)2 in the ratio of 2:1 in methanol in the reflux conditions. The Schiff base ligand and its vanadyl complex were characterized by 1H-NMR and FT-IR spectra and elemental analysis. The crystal structure of 1 was also determined the single-crystal X-ray analysis. It showed that the metal center located in a distorted tetragonal pyramidal (N2O3) geometry in which the two bidentate Schiff base ligands were coordinated to the vanadium(IV) ion in four equatorial positions, and one oxygen atom in its axial position. The catalytic activity of the vanadyl Schiff base complex was elucidated in the epoxidation of cyclooctene as a model substrate. Different reaction parameters were investigated in this reaction and the results showed that it was an effective and selective catalyst in these optimal conditions. Thermogravimetric analysis of 1 showed that it was decomposed in two stages by losing two methoxy groups and other organic residuals, respectively, in the temperature range of 253–532 °C. In addition, the vanadyl Schiff base complex (1) was thermally decomposed in air at 660 °C and the XRD pattern of the obtained solid showed the formation of the V2O5 nano-particles with the average size of 52 nm.

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References

  1. M. Shebl, Spectrochim Acta A. 70, 850 (2008)

    Article  Google Scholar 

  2. M. Hobady, T.D. Smith, Coord. Chem. Rev. 9, 311 (1973)

    Article  Google Scholar 

  3. P. Przybylski, A. Huczynski, K. Pyta, B. Brzezinski, F. Bartl, Curr. Org. Chem. 13, 124 (2009)

    Article  CAS  Google Scholar 

  4. A.A. Khandar, S.A. Hosseini-Yazdi, S.A. Zarei, Inorg. Chim. Acta 358, 3211 (2005)

    Article  CAS  Google Scholar 

  5. P.K. Mascharak, Coordin. Chem. Rev. 225, 201 (2002)

    Article  CAS  Google Scholar 

  6. J.G. Muller, L.A. Kayser, S.J. Paikoff, V. Duarte, N. Tang, R.J. Perez, S.E. Rokita, C.J. Burrows, Coord. Chem. Rev. 761, 185 (1999)

    Google Scholar 

  7. D.P. Kessissoglou, Coordin. Chem. Rev. 837, 185 (1999)

    Google Scholar 

  8. V.E. Kaasjager, L. Puglisi, E. Bouwman, W.L. Driessen, J. Reedijk, Inorg. Chim. Acta 310, 183 (2000)

    Article  CAS  Google Scholar 

  9. A.S. Al-Shihri, Spectrochim. Acta A 60, 1189 (2004)

    Article  Google Scholar 

  10. H. Sigel, A. Sigel (eds.), Vanadium and its Role in Life, Metal Ions in Biological Systems, vol. 31 (Marcel Dekker, New York, 1995)

    Google Scholar 

  11. D.C. Crans, J.J. Smee, E. Gaidamauskas, L. Yang, Chem. Rev. 104, 849 (2004)

    Article  CAS  Google Scholar 

  12. A.S. Tracey, G.R. Willsky, E.S. Takeuchi, Vanadium Chemistry, Biochemistry, Pharmacology and Practical Applications (CRC Press, Boca Raton, 2007)

    Google Scholar 

  13. D. Rehder, Bioinorganic Vanadium Chemistry (Wiley and Sons, Chichester, 2008)

    Book  Google Scholar 

  14. A. Butler, J.V. Walker, Chem. Rev. 93, 1937 (1993)

    Article  CAS  Google Scholar 

  15. C.R. Cornman, E.P. Zovinka, M.H. Meixner, Inorg. Chem. 34, 5099 (1995)

    Article  CAS  Google Scholar 

  16. D. Rehder, Angew. Chem. Int. Ed. 30, 148 (1991)

    Article  Google Scholar 

  17. K.H. Thompson, B.D. Liboiron, Y. Sun, K.D.D. Bellman, V. Karunaratne, G. Rawji, J. Wheeler, K. Sutton, S. Bhanot, S.B.C. Cassidy, J.H. McNeill, V.G. Yuen, C. Orvig, J. Biol. Inorg. Chem. 8, 66 (2003)

    Article  CAS  Google Scholar 

  18. H. Yasui, Y. Adachi, A. Katoh, H. Sakurai, J. Biol. Inorg. Chem. 12, 843 (2007)

    Article  CAS  Google Scholar 

  19. Y. Shechter, I. Goldwaser, M. Mironchik, M. Fridkin, D. Gefel, Coord. Chem. Rev. 237, 3 (2003)

    Article  CAS  Google Scholar 

  20. A.M.B. Bastos, J.G. da Silva, P.I.S. Maia, V.M. Deflon, A.A. Batista, A.V.M. Ferreira, L.M. Botion, E. Niquet, H. Beraldo, Polyhedron 27, 1787 (2008)

    Article  CAS  Google Scholar 

  21. R.R. Eady, Coord. Chem. Rev. 237, 23 (2003)

    Article  CAS  Google Scholar 

  22. K.H. Thompson, J.H. McNeill, C. Orvig, Chem. Rev. 99, 2561 (1999)

    Article  CAS  Google Scholar 

  23. J.A.L. da Silva, J.J.R. Fraústo da Silva, A.J.L. Pombeiro, Coord. Chem. Rev. 255, 2232 (2011)

    Article  Google Scholar 

  24. G. Licini, V. Conte, A. Coletti, M. Miriam, C. Zonta, Coord. Chem. Rev. 255, 2345 (2011)

    Article  CAS  Google Scholar 

  25. S. Mohebbi, D.M. Boghaei, A.H. Sarvestani, Appl. Catal. A: Gen. 278, 263 (2005)

    Article  CAS  Google Scholar 

  26. W. Zhang, A. Basak, Y. Kosugi, Y. Hoshino, H. Yamamoto, Angew. Chem. Int. Ed. Engl. 44, 2005 (4389)

    Google Scholar 

  27. M. Bagherzadeh, M. Amini, J. Coord. Chem. 63, 3849 (2010)

    Article  CAS  Google Scholar 

  28. P.J. Figiel, J.M. Sobczak, J.J. Ziolkowski, Chem. Commun. 2, 244 (2004)

    Article  Google Scholar 

  29. E. Battistel, R. Tassinari, M. Fornaroli, L. Bonoldi, J. Mol. Catal. A Chem. 202, 107 (2003)

    Article  CAS  Google Scholar 

  30. G.B. Shul’pin, G. Suss-Fink, J. Chem. Soc., Perkin Trans. 2, 1459 (1995)

    Google Scholar 

  31. T.S. Smith II, V.L. Pecoraro, Inorg. Chem. 41, 6754 (2002)

    Article  CAS  Google Scholar 

  32. R. Ando, T. Yagyu, M. Maeda, Inorg. Chim. Acta 357, 2237 (2004)

    Article  CAS  Google Scholar 

  33. G. Grivani, A.D. Khalaji, V. Tahmasebi, K. Gotoh, H. Ishida, Polyhedron 31, 265 (2012)

    Article  CAS  Google Scholar 

  34. G. Grivani, G. Bruno, H.A. Rudbari, A.D. Khalaji, P. Pourteimouri, Inorg. Chem. Commun. 18, 15 (2012)

    Article  CAS  Google Scholar 

  35. M.C. Burla, M. Camalli, B. Carrozzini, G. Cascarano, C. Giacovazzo, G. Polidori, R. Spagna, SIR2002: the program. J. Appl. Cryst. 36, 1103 (2003)

    Article  CAS  Google Scholar 

  36. V. Petricek, M. Dusek, L. Palatinus, Jana2006. Structure determination software programs. Institute of Physics, Praha, Czech Republic (2008)

  37. L.J. Farrugia, J. Appl. Cryst. 30, 65 (1997)

    Article  Google Scholar 

  38. R. Ando, S. Mori, M. Hayashi, T. Yagyu, M. Maeda, Inorg. Chim. Acta 357, 1177 (2004)

    Article  CAS  Google Scholar 

  39. A.A. Nejo, G.A. Kolawole, A.R. Opoku, J. Wolowska, P. O’Brien, Inorg. Chim. Acta. 362, 3993 (2009)

    Google Scholar 

  40. C.J. Chang, J.A. Labinger, H.B. Gray, Inorg. Chem. 36, 5927 (1997)

    Article  CAS  Google Scholar 

  41. G. Grivani, S. Delkhosh, K. Fejfarová, M. Dušek, A.D. Khalaji, Inorg. Chem. Commun. 27, 82 (2013)

    Article  CAS  Google Scholar 

  42. G. Grivani, V. Tahmasebi, A.D. Khalaji, K. Fejfarov, M. Dušek, Polyhedron 51, 54 (2013)

    Article  CAS  Google Scholar 

  43. S. Rayati, M. Koliaei, F. Ashouri, S. Mohebbi, A. Wojtczak, A. Kozakiewicz, Appl. Catal. A Gen. 346, 65 (2008)

    Article  CAS  Google Scholar 

  44. F. Madeira, S. Barroso, S. Namorado, P.M. Reis, B. Royo, A.M. Martins, Inorg. Chim. Acta 383, 152 (2012)

    Article  CAS  Google Scholar 

  45. V. Conte, A. Coletti, B. Floris, G. Licini, C. Zonta, Coord. Chem. Rev. 255, 2165 (2011)

    Article  CAS  Google Scholar 

  46. P. Adão, J.C. Pessoa, R.T. Henriques, M.L. Kuznetsov, F. Avecilla, M.R. Maurya, U. Kumar, I. Correia, Inorg. Chem. 48, 3542 (2009)

    Article  Google Scholar 

  47. S. Rayati, N. Torabi, A. Ghaemi, S. Mohebbi, A. Wojtczak, A. Kozakiewicz, Inorg. Chim. Acta 361, 1239 (2008)

    Article  CAS  Google Scholar 

  48. M.R. Maurya, A. Arya, P. Adão, J.C. Pessoa, Appl Catal A Gen 351, 239 (2008)

    Article  CAS  Google Scholar 

  49. M.R. Maurya, A. Kumar, J. Mol. Catal. A Chem. 250, 190 (2006)

    Article  CAS  Google Scholar 

  50. M.R. Maurya, A.K. Chandrakar, S. Chand, J. Mol. Catal. A Chem. 270, 225 (2007)

    Article  CAS  Google Scholar 

  51. J.H. Kim, Y.C. Hong, H.S. Uhm, Surf. Coat. Tech. 201, 5114 (2007)

    Article  CAS  Google Scholar 

  52. L. Li, Z. Yan, J. Nat. Gas Chem. 14, 35 (2005)

    Google Scholar 

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Acknowledgments

We acknowledge Damghan University (DU) and Golestan University (GU) for partial support of this work and the project Praemium Academiae of the Academy of Sciences (ASCR).

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Authors and Affiliations

  1. School of Chemistry, Damghan University, 36715-364, Damghan, Iran

    Gholamhossein Grivani, Vida Tahmasebi & Shadi Delkhosh

  2. Institute of Physics ASCR, v.v.i., Na Slovance 2, 182 218, Prague 8, Czech Republic

    Karla Fejfarová & Michal Dušek

  3. Department of Chemistry, Faculty of Science, Golestan University, Gorgan, Iran

    Aliakbar Dehno Khalaji

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  1. Gholamhossein Grivani
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  2. Aliakbar Dehno Khalaji
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Correspondence to Gholamhossein Grivani.

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Grivani, G., Khalaji, A.D., Fejfarová, K. et al. Synthesis, characterization, crystal structure determination, catalytic activity and thermal study of a new oxidovanadium(IV) Schiff base complex: production of V2O5 nano-particles. J IRAN CHEM SOC 11, 953–962 (2014). https://doi.org/10.1007/s13738-013-0361-y

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