Abstract
Steel corrosion is a costly problem. The Delhi Iron Pillar containing high amount of phosphorous withstood atmospheric corrosion for about 1600 years. In the present work, steels containing 0.13 wt% P, 0.05 wt% C, and varying amounts of silicon and nitrogen are prepared through the wrought route in order to investigate the combined effects of alloying additions of Si and N as well as thermomechanical processing on their mechanical properties. The effect of the alloying elements and processing on grain boundary segregation of phosphorous has been studied by EDS. The UTS values of the hot forged steels are found to be above 400 MPa, the elongation is above 30%, and the n values are above 0.3. The maximum impact energy obtained is 284 J in Fe–0.05C–0.13P–0.48Si–0.015N steel.
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H.K.D.H. Bhadeshia, D. Suh, Is a low-phosphorus content in steel a product requirement? Ironmak. Steelmak. 42, 259–267 (2015)
D. McLean, L. Northcott, Micro-examination and electrode potential measurements of temper-brittle steels. J. Iron Steel Inst. 158, 169–177 (1948)
M. Goodway, R.M. Fisher, Phosphorus in low carbon iron: its beneficial properties. Hist. Metall. 22, 21–23 (1988)
C.L. Briant, S.K. Banerji, The fracture behavior of quenched and tempered manganese steels. Metall. Trans. A 13, 827–836 (1982)
J.P. Materkowski, G. Krauss, Tempered martensite embrittlement in SAE 4340 steel. Metall. Mater. Trans. A 10, 1643–1651 (1979)
M. Tikkanen, The application of sintering theory in practice; Sintering-Theory and Practice, in Phys. Sinter. ed. by M.M. Ristic, 1973, pp. 441–453
J.W. Stewart, J.A. Charles, E.R. Wallach, Iron–phosphorus–carbon system: part 1—mechanical properties of low carbon iron–phosphorus alloys. Mater. Sci. Technol. 16, 275–282 (2000)
F.B. Pickering, Physical Metallurgy and the Design of Steels, 1978th edn. (Applied Science Publishers, London, 1978), p. 11
G. Wranglen, The “rustless” iron pillar at Delhi. Corros. Sci. 10, 761–770 (1970)
R. Balasubramaniam, On the corrosion resistance of the Delhi iron pillar. Corros. Sci. 42, 2013–2129 (2000)
H. Hu, Effects of phosphorus on the annealing texture, plastic anisotropy, and mechanical properties of low-carbon steels. Texture Cryst. Solids 2, 113–141 (1976)
S. Suzuki, M. Obata, K. Abiko, H. Kimura, Role of carbon in preventing alloys the intergranular fracture in iron–phosphorus. Trans. Iron Steel Inst. Jpn 25, 62–68 (1985)
G. Sahoo, R. Balasubramaniam, On the corrosion behaviour of phosphoric irons in simulated concrete pore solution. Corros. Sci. 50, 131–143 (2008)
G. Sahoo, R. Balasubramaniam, Mechanical behavior of novel phosphoric irons for concrete reinforcement applications. Scr. Mater. 56, 117–120 (2007)
B.E. Hopkins, H.R. Tipler, The effect of phosphorus on the tensile and notch impact properties of high purity iron and iron carbon alloys. J Iron Steel Inst. 188, 218–237 (1958)
R.G. Davies, Influence of silicon and phosphorous on the mechanical properties of both ferrite and dual-phase steels. Metall. Trans. A 10, 113–118 (1979)
B.K. Panigrahi, S. Srikanth, G. Sahoo, Effect of alloying elements on tensile properties, microstructure, and corrosion resistance of reinforcing bar steel. J. Mater. Eng. Perform. 18, 1102–1108 (2009)
B.K. Panigrahi, Microstructure–mechanical property relationships for a Fe/Mn/Cr rock bolt reinforcing steel. J. Mater. Eng. Perform. 19, 885–893 (2010)
B.K. Panigrahi, S.K. Jain, Impact toughness of high strength low alloy TMT reinforcement ribbed bar. Bull. Mater. Sci. 25, 319–324 (2002)
W.A. Spitzig, R.J. Sober, Effect of phosphorus on the mechanical properties of normalized 0.1 pct C, 1.0 pct Mn steel strip. Metall. Trans. A 8A, 651–655 (1977)
Gouthama, R. Balasubramaniam, Alloy design of ductile phosphoric iron: ideas from archaeometallurgy. Bull. Mater. Sci. 26(5), 483–491 (2003)
H. Erhart, H.J. Grabke, Site competition in grain boundary segregation of phosphorus and nitrogen in iron. Scr. Metall. 15, 531–534 (1981)
H. Liu, C. M. Abiko, K. Kimura, Effect of silicon on the grain boundary segregation of phosphorus and the phosphorus induced intergranular fracture in high purity Fe–Si–P alloys, in Strength of Metals and Alloys (ICSMA 8), Proceedings of 8th International Conference Strength Metal Alloy, Tampere, Finland, 22–26 August 1988, 1989, vol 3, pp. 1101–1106
J.W. Stewart, J.A. Charles, E.R. Wallach, Iron–phosphorus–carbon system: part 3—metallography of low carbon iron–phosphorus alloys. Mater. Sci. Technol. 16, 291–303 (2000)
R. Vogel, On the system iron–phosphorus–carbon. Arch Eisenhuttenwes 3, 369–381 (1929)
M. Durand-Charre, Microstructure of Steels and Cast Irons (Springer, Berlin, 2004), p. 265
ASTM E 23-12c, Standard test methods for notched bar impact testing of metallic materials, Standards, 1–25 (2013)
G. Sahoo, B. Singh, A. Saxena, Characterization of high phosphorous containing hot rolled weather resistant structural steels. Mater. Sci. Eng., A 628, 303–310 (2015)
ASTM A706, Standard specification for low-alloy steel deformed and plain bars for concrete, Annu. B. ASTM Stand. 1–6 (2016)
IS 1786, High strength deformed steel bars and wires for concrete reinforcement—(Fourth Revision) 1–10 (2008)
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The authors acknowledge Vaishnav Steel Private Limited, Muzaffarnagar, India, for providing their melting and casting facility for research purpose.
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Mehta, Y., Dabhade, V.V. & Chaudhari, G.P. Effect of Silicon and Nitrogen on the Microstructure and Mechanical Behavior of High-Phosphorous Steels. Metallogr. Microstruct. Anal. 5, 384–391 (2016). https://doi.org/10.1007/s13632-016-0298-5
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DOI: https://doi.org/10.1007/s13632-016-0298-5