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Anionic Polymerization of Ethyl 2-Cyanoacrylate Initiated by 1,3-Dimethylimidazolium (phosphonooxy-)oligosulfanide

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Abstract

The possibility of initiating anionic polymerization in the presence of 1,3-dimethylimidazolium (phosphonooxy-)oligosulfanide is shown by the example of the synthesis of poly(ethyl 2-cyanoacrylate). The structure of the synthesized poly(ethyl 2-cyanoacrylate) was characterized by 13C nuclear magnetic resonance (NMR), 1H NMR, and matrix-assisted laser desorption ionization-time of flight methods on positively and negatively charged ions. It is shown that the chains of synthesized poly(ethyl 2-cyanoacrylate) have a terminal group containing sulfur and phosphorus atoms. The presence of sulfur and phosphorus atoms in the terminal group confirms the initiation of anionic polymerization as a result of nucleophilic attack by (phosphonooxy-)oligosulfanide-anion by electrophilic ethyl 2-cyanoacrylate.

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Acknowledgment

This research was funded by D. Mendeleev University of Chemical Technology of Russia, grant number 2020-040.

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Authors and Affiliations

  1. Institute of Chemistry and Problems of Sustainable Development, Dmitry Mendeleev University of Chemical Technology of Russia, 12047, Moscow, Russia

    Natalia Tarasova, Efrem Krivoborodov, Alexey Zanin, Ekaterina Pascal, Valerie Dyatlov & Yaroslav Mezhuev

  2. Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry, Russian Academy of Sciences, 119017, Moscow, Russia

    Natalia Tarasova

  3. V. N. Orekhovich Research Institute of Biomedical Chemistry, Russian Academy of Medical Sciences, 119121, Moscow, Russia

    Ilya Toropygin

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  1. Natalia Tarasova
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  2. Efrem Krivoborodov
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  3. Alexey Zanin
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  4. Ilya Toropygin
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  5. Ekaterina Pascal
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  6. Valerie Dyatlov
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  7. Yaroslav Mezhuev
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Correspondence to Alexey Zanin.

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Tarasova, N., Krivoborodov, E., Zanin, A. et al. Anionic Polymerization of Ethyl 2-Cyanoacrylate Initiated by 1,3-Dimethylimidazolium (phosphonooxy-)oligosulfanide. Macromol. Res. 29, 847–850 (2021). https://doi.org/10.1007/s13233-021-9104-6

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  • DOI: https://doi.org/10.1007/s13233-021-9104-6

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