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Preparation and structure of nylon 4/6 random-copolymer nanofibers

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Abstract

Nylon 4/6 copolymers were synthesized by a melt-condensation method using ɛ-caprolactam and 2-pyrrolidone as monomers and 6-aminocaproic acid as a catalyst. Their structures and morphologies were studied using wide and small angle X-ray scatterings, differential scanning calorimetry, and scanning electron microscopy. The nylon 4 units were included into the nylon 6 chain up to 25 mol%. Random introduction of the small amount of the nylon 4 units to the nylon 6 decreased the crystallinities. The synthesized copolymers were successfully electrospun into nanofiber mats with diameter ranges of 90–130 nm, and their structures were compared to those of the films. The copolymers adopted the crystal structure of the pure nylon 6 with mixed nylon 4 and 6 units in the amorphous region, although the crystal structures of the nanofiber mats and the films were the γ and α forms of nylon 6, respectively. The crystallinity of the nanofiber mats decreased compared to those of the films. The water absorption of the nylon 4/6 copolymers increased as the mol% of nylon 4 increased in the copolymers.

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Reference

  1. D. M. Lincoln, R. A. Vaia, and R. Krishnamoorti, Macromolecules, 37, 4554 (2004).

    Article  CAS  Google Scholar 

  2. D. M. Lincoln, R. A. Vaia, Z. G. Wang, and B. S. Hsiao, Polymer, 42, 1621 (2000).

    Article  Google Scholar 

  3. D. M. Lincoln, R. A. Vaia, Z. G. Wang, B. S. Hsiao, and R. Krishnamoorti, Polymer, 42, 9975 (2001).

    Article  CAS  Google Scholar 

  4. N. S. Murthy, S. M. Aharoni, and A. B. Szollosi, J. Polym. Sci. Part B: Polym. Phys., 23, 2549 (1985).

    CAS  Google Scholar 

  5. S. M. Aharoni, n-Nylons: Their Synthesis, Structure, and Properties, John Wiley & Sons, New York, 1997.

    Google Scholar 

  6. Y. Li and W. A. Goddard III, Macromolecules, 35, 8440 (2002).

    Article  CAS  Google Scholar 

  7. J. Y. Cheng, C. A. Ross, H. I. Smith, and E. L. Thomas, Adv. Mater., 18, 2505 (2006).

    Article  CAS  Google Scholar 

  8. J. Doshi and D. H. Reneker, J. Electrostatics, 35, 151 (1995).

    Article  CAS  Google Scholar 

  9. H. Fong and D. H. Reneker, in Structure Formation in Polymeric Fibers, D. R. Salem, Ed., Hanser Gardner, Cincinnati, 2001, pp 225–246.

    Google Scholar 

  10. R. Jaeger, M. M. Bergshoef, C. M. I. Batlle, H. Schonherr, and G. J. Vancso, Macromol. Symp., 127, 141 (1998).

    Article  CAS  Google Scholar 

  11. M. Bognitzki, W. Czado, T. Frese, A. Schaper, M. Hellwig, M. Steinhart, A. Greiner, and J. H. Wendorff, Adv. Mater., 13, 70 (2001).

    Article  CAS  Google Scholar 

  12. J. M. Deitzel, J. Kleinmeyer, D. Harris, and N. C. B. Tan, Polymer, 42, 261 (2001).

    Article  CAS  Google Scholar 

  13. J. M. Deitzel, J. D. Kleinmeyer, J. K. Hirvonen, and N. C. B. Tan, Polymer, 42, 8163 (2001).

    Article  CAS  Google Scholar 

  14. V. E. Kalayci, P. K. Patra, A. Buer, S. C. Ugbolue, Y. K. Kim, and S. B. Warner, J. Adv. Mater., 36, 43 (2004).

    Google Scholar 

  15. R. Dersch, T. Liu, A. K. Schaper, A. Greiner, and J. H. Wendorff, J. Polym. Sci. Part A: Polym. Chem., 41, 545 (2003).

    Article  CAS  Google Scholar 

  16. J. S. Stephens, D. B. Chase, and J. F. Rabolt, Macromolecules, 37, 877 (2004).

    Article  CAS  Google Scholar 

  17. Y. Liu and C. Pellerin, Macromolecules, 39, 8886 (2006).

    Article  CAS  Google Scholar 

  18. M. W. Frey and L. Li, Journal of Engineered Fibers and Fabrics, 2, 31 (2007).

    CAS  Google Scholar 

  19. K. Saeed, S. Y. Park, S. Haider, and J. B. Baek, Nanoscale Res. Lett., 4, 39 (2009).

    Article  CAS  Google Scholar 

  20. S. D. Vrieze, B. D. Schoenmaker, O. Ceylan, J. Depuydt, L. L. Van, H. Rahier, G. V. Assche, and K. D. Clerck, J. Appl. Polym. Sci., 119, 2984 (2011).

    Article  Google Scholar 

  21. D. H. Reneker and I. Chun, Nanotechnology, 7, 216 (1996).

    Article  CAS  Google Scholar 

  22. R. Dersch, T. Liu, A. K. Schaper, A. Greiner, and J. H. Wendorff, J. Polym. Sci. Part A: Polym. Chem., 41, 545 (2003).

    Article  CAS  Google Scholar 

  23. M. M. Bergshoef and G. J. Vancso, Adv. Mater., 11, 1362 (1999).

    Article  CAS  Google Scholar 

  24. H. Fong, W. D. Liu, C. S. Wang, and R. A. Vaia, Polymer, 43, 775 (2002).

    Article  CAS  Google Scholar 

  25. V. Miri, S. Elkoun, F. Peurton, C. Vanmansart, J. M. Lefebvre, P. Krawczak, and R. Seguela, Macromolecules, 41, 9234 (2008).

    Article  CAS  Google Scholar 

  26. H. Arimoto, M. Ishibashi, M. Hirai, and Y. Chatani, J. Polym. Sci., 3, 317 (1965).

    CAS  Google Scholar 

  27. Y. Liu, L. Cui, G. Fangxiao, Y. Gao, N. E. Hedin, L. Zhu, and H. Fong, Macromolecules, 40, 6283 (2007).

    Article  CAS  Google Scholar 

  28. C. Ibanes, M. D. Boissieu, L. David, and R. Seguela, Polymer, 47, 5071 (2006).

    Article  CAS  Google Scholar 

  29. M. N. Sanjeeva, G. R. Hatfield, and J. H. Glans, Macromolecules, 23, 1342 (1990).

    Article  Google Scholar 

  30. S. Y. Park, Y. H. Cho, and R. A. Vaia, Macromolecules, 38, 1729 (2005).

    Article  CAS  Google Scholar 

  31. C. B. Giller, D. B. Chase, J. F. Rabolt, and C. M. Snively, Polymer, 51, 4225 (2010).

    Article  CAS  Google Scholar 

  32. L. Juan, F. Zhengping, T. Lifang, G. A. Juan, and L. Fu, J. Appl. Polym. Sci. Part B: Polym. Phys., 44, 1499 (2006).

    Article  Google Scholar 

  33. Y. Junchun, T. Bounphanh, and A. Ove, Macromolecules, 43, 10512 (2010).

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Polymer Science, Kyungpook National University, Daegu, 702-701, Korea

    Muhammad Omer, Tahseen Kamal & Soo-Young Park

  2. Department of Textile Engineering, Pusan National University, Pusan, 609-735, Korea

    Hyun-Hok Cho & Dong-Kook Kim

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  1. Muhammad Omer
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  2. Tahseen Kamal
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  3. Hyun-Hok Cho
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  4. Dong-Kook Kim
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  5. Soo-Young Park
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Correspondence to Soo-Young Park.

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Omer, M., Kamal, T., Cho, HH. et al. Preparation and structure of nylon 4/6 random-copolymer nanofibers. Macromol. Res. 20, 810–815 (2012). https://doi.org/10.1007/s13233-012-0121-3

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  • DOI: https://doi.org/10.1007/s13233-012-0121-3

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