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Dehulling and microwave pretreatment effects on the physicochemical composition and antioxidant capacity of virgin rapeseed oil

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Abstract

The effect of microwave heating (800 W) of whole and dehulled rapeseeds for 2 to 8 min was investigated in order to evaluate the impact of dehulling in conjunction with microwaving on the nutritional value, antioxidant activity and physicochemical properties of virgin rapeseed oil. Control oil produced from dehulled seeds (DRO) had higher amounts of bioactive compounds, such as tocochromanols and phytosterols, lower content of pigments, and higher content of primary and secondary oxidation products compared to oil pressed from whole seeds (WRO). Oils pressed from seeds that had previously undergone thermal treatment demonstrated gradual increase of oxidative stability, radical scavenging activity, moreover microwave treatment to caused darkening of oil, assessed in terms of changes in L*a*b* coordinates as well as browning index. Thermally-induced compositional changes were seen mainly in canolol, phytosterols, and carotenoids content, while only slight increase of tocopherols and phenolics was observed. The most pronounced effect of microwave pretreatment was noted for canolol formation—for 8-min MV exposure canolol quantity was approximately 7- and 23-fold higher, in comparison with control WRO and DRO samples, respectively (increase from 61.39 to 456.04 µg/g, and from 13.39 to 320.44 µg/g).

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Abbreviations

AHC:

Agglomerative cluster analysis

DRO:

Rapeseed oil pressed from dehulled seeds

HF:

Hydrophilic fraction

IP:

Induction period

LF:

Lipophilic fraction

MV:

Microwave

p-AnV:

p-anisidine value

PC‐8:

Plastochromanol‐8

PV:

Peroxide value

RSC:

Radical scavenging activity

WRO:

Rapeseed oil pressed from whole seeds

α-T:

Alpha tocopherol

β‐T:

Beta‐tocopherol

γ‐T:

Gamma‐tocopherol

δ‐T:

Delta‐tocopherol

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Correspondence to Agnieszka Rękas.

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Rękas, A., Siger, A., Wroniak, M. et al. Dehulling and microwave pretreatment effects on the physicochemical composition and antioxidant capacity of virgin rapeseed oil. J Food Sci Technol 54, 627–638 (2017). https://doi.org/10.1007/s13197-017-2486-y

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  • DOI: https://doi.org/10.1007/s13197-017-2486-y

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