Skip to main content

Advertisement

Log in

I–P2O5 diagrams as an indicator of depositional environment in marine sediments: preliminary findings (Sri Lanka)

  • Original Article
  • Published:
Environmental Earth Sciences Aims and scope Submit manuscript

Abstract

The concentrations of Br and I in marine sediments have been used to categorize the sedimentary environments of different coastal regions of the world with respect to organic matter contents. The present study uses the concentrations of Br, I and P2O5 of different marine settings as a new proxy to interpret the depositional environments. A total of 150 coastal lagoon sediment samples (suspended sediments, surface sediments and sediment cores) were analyzed for Br, I and P2O5 concentrations by X-ray fluorescence spectrometry. They were compared with the Br, I and P2O5 concentrations of the 2004 Indian Ocean tsunami sediments. Sediments from various sources are separately clustered in I–Br plot and a trivial negative correlation is found for the whole plot. A similar correlation pattern exists in the I–P2O5 diagram. This correlation is explained by the distribution of marine plants (higher and lower) in different sedimentary environments of the coastal profile. Therefore, the concentration of I and its relation to P2O5 can be used as a tool to identify sediment depositional environments in marine settings.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  • Adikaram M, Pitawala A, Ishiga H, Jayawardana D (2017) Chemical composition and possible sources of suspended particulate matter in the peripheral environments of Batticaloa lagoon, Sri Lanka. Reg Stud Mar Sci 16:294–303

    Article  Google Scholar 

  • Algeo TJ, Lyons TW (2006) Mo-total organic carbon covariation in modern anoxic marine environments: implications for analysis of paleo-redox and paleo-hydrographic conditions. Paleoceanography 21:23. https://doi.org/10.1029/2004PA001112 PA1016

    Article  Google Scholar 

  • Al-Mutaz IS (2000) Water desalination in the Arabian Gulf region. In: Goosen MFA, Shayya WH (eds) Water management, purification and conservation in arid climates. Water purification basel. Technomic Publishing, pp 245–265

  • Butler EC, Smith JD, Fisher NS (1981) Influence of phytoplankton on iodine speciation in seawater. Limnol Oceanogr 26:382–386

    Article  Google Scholar 

  • Chagué-GoffC Fyfe WS (1996) Geochemical and petrographical characteristics of a domed bog, Nova Scotia: a modern analog for temperate coal deposits. Org Geochem 24:141–158

    Article  Google Scholar 

  • Chandrapala L, Wimalasuriya M (2003) Satellite measurements supplemented with meteorological data to operationally estimate evaporation in Sri Lanka. Agric Water Manag 58:89–107

    Article  Google Scholar 

  • Cooray PG (1984) An introduction to the geology of Sri Lanka (Ceylon), 2nd edn. National museum publication, Colombo, pp 81–289

    Google Scholar 

  • Cooray PG (1994) The Precambrian of Sri Lanka, a historical overview. Precambrian Res 66:3–18

    Article  Google Scholar 

  • Cooray PG, Katupotha KNJ (1991) Geological evolution of the coastal zone of Sri Lanka. In: Proceedings of symposium on causes of coastal erosion in Sri Lanka, Colombo, pp 5–26

  • Dahanayake K, Kulasena N (2008) Recognition of diagnostic criteria for recent-and paleo-tsunami sediments from Sri Lanka. Mar Geol 254:180–186

    Article  Google Scholar 

  • Dean WE (1974) Loss on ignition as a method for estimating organic and carbonate content in sediments: reproducibility and comparability of results. J Paleolimnol 25:101–110

    Google Scholar 

  • Dean WE, Arthur MA (1989) Iron-sulfur-carbon relationships in organic-carbon-rich sequences I: cretaceous western interior seaway. Am J Sci 289:708–743

    Article  Google Scholar 

  • Gilleaudeau GJ, Kah LC (2015) Heterogeneous redox conditions and a shallow chemocline in the Mesoproterozoicocean: evidence from carbon–sulfur–iron relationships. Precambrian Res 257:94–108

    Article  Google Scholar 

  • Gribble GW (1998) Naturally occurring organohalogen compounds. Acc Chem Res 31:141–152

    Article  Google Scholar 

  • Harvey GR (1980) A study of the chemistry of iodine and bromine in marine sediments. Mar Chem 8:327–332

    Article  Google Scholar 

  • Heiri O, Lotter AF, Lemcke G (2001) Loss on ignition as a method for estimating organic and carbonate content in sediments: reproducibility and comparability of results. J Paleolimnol 25:101–110

    Article  Google Scholar 

  • Ishiga H, Sano E (2015) Examination of tidal flat environment from geochemical analysis of suspended solids in relation to tidal change and Zontera Marina in Kasaoka Bay, Seto Inland sea, Southwest Japan. Geosci Rept Shimane Univ 33:39–47

    Google Scholar 

  • Ishiga H, Shiohara H, Sano E (2010) Geochemical compositions of sediments from the tidal flat of Kasaoka Bay and neighboring areas of Okayama prefecture, Japan. Geosci Rept Shimane Univ 29:33–39

    Google Scholar 

  • Ishiga H, Sakaya M, Sakamoto M, Hatanaka Y, Iwanaga A (2015) Geochemical evaluation of material circulation in the biomass of Zontera Marina (submerged plant) at the tidal flat in Ise and Matsusaka areas, Mie prefecture, Japan. Geosci Rept Shimane Univ 33:49–58

    Google Scholar 

  • Jayawardana DT, Ishiga H, Pitawala HMTGA (2012) Geochemistry of surface sediments in tsunami-affected Sri Lankan lagoons regarding environmental implications. Int J Environ Sci Technol 9:41–55

    Article  Google Scholar 

  • Kröner A, Rojas-Agramontea Y, Kehelpannala KVW, Zacka T, Hegner E, Genge HY, Wonge J, Barth M (2012) Age, Nd–Hf isotopes, and geochemistry of the Vijayan Complex of eastern and southern Sri Lanka: a Grenville-age magmatic arc of unknown derivation. Precambrian Res 234:288–321

    Article  Google Scholar 

  • Leri AC, Hakala JA, Marcus MA, Lanzirotti A, Reddy CM, Myneni SC (2010) Natural organobromine in marine sediments: new evidence of biogeochemical Br cycling. Global Biogeochem Cycles 24(4):GB4017

    Google Scholar 

  • Leventhal JS (1983) An interpretation of carbon and sulfur relationships in Black Sea sediments as indicators of environments of deposition. Geochim Cosmochim Acta 47:133–137

    Article  Google Scholar 

  • Lu Z, Jenkyns HC, Rickaby RE (2010) Iodine to calcium ratios in marine carbonate as a paleo-redox proxy during oceanic anoxic events. Geology 38(12):1107–1110

    Article  Google Scholar 

  • Malcolm SJ, Price NB (1984) The behavior of iodine and bromine in estuarine surface sediments. Mar Chem 15(3):263–271

    Article  Google Scholar 

  • Matsumoto D, Shimamoto T, Hirose T, Gunatilake J, Wickramasooriya A, DeLile J, Young S, Rathnayaka C, Ranasooriya J, Murayama M (2010) Thickness and grain-size distribution of the 2004 Indian Ocean tsunami deposits in Periya Kalapuwa Lagoon, eastern Sri Lanka. Sediment Geol 230(3):95–104

    Article  Google Scholar 

  • Mayer LM, Schick LL, Allison MA, Ruttenberg KC, Bentley SJ (2007) Marine vs. terrigenous OM in Louisiana coastal sediments: the uses of bromine: organic carbon ratios. Mar Chem 107(2):244–254

    Article  Google Scholar 

  • Menzel DW (1974) Primary productivity, dissolved and particulate organic matter, and the sites of oxidation of organic matter. In: Goldberg ED (ed) The sea. Wiley, New York, pp 659–678

    Google Scholar 

  • Moreno J, Fatela F, Leorri E, Araújo MF, Moreno F, De la Rosa J, Freitas MC, Valente T, Corbett DR (2015) Bromine enrichment in marsh sediments as a marker of environmental changes driven by Grand Solar Minima and anthropogenic activity (Caminha, NW of Portugal). Sci Total Environ 506:554–566

    Article  Google Scholar 

  • Muramatsu Y, Yoshida S, Fehn U, Amachi S, Ohmomo Y (2004) Studies with natural and anthropogenic iodine isotopes: iodine distribution and cycling in the global environment. J Environ Radioact 74(1):221–232

    Article  Google Scholar 

  • Ogasawara M (1987) Trace element analysis of rock samples by X-ray fluorescence spectrometry, using Rh anode tube. Bull Geol Survey Jpn 38(2):57–68

    Google Scholar 

  • Okamoto R, Yamashita M, Sakaya M, Ishiga H (2015) Multi element geochemical analysis of water quality, suspended solids, sediments and Zontera Marina for evaluation of the tidal flat environment in Matsunaga bay and surrounding areas in Bongo Nada of Seto Inland sea, Japan. Geosci Rept Shimane Univ 33:59–74

    Google Scholar 

  • Pedersen TF, Price NB (1980) The geochemistry of iodine and bromine in sediments of the Panama Basin. J Mar Res 38:397–411

    Google Scholar 

  • Price NB, Calvert SE (1973) The geochemistry of iodine in oxidized and reduced recent marine sediments. Geochim Cosmochim Acta 37(9):2149–2158

    Article  Google Scholar 

  • Price NB, Calvert SE (1977) The contrasting geochemical behaviors of iodine and bromine in recent sediments from the Namibian shelf. Geochim Cosmochim Acta 41(12):1769–1775

    Article  Google Scholar 

  • Ratnayake AS, Sampei Y, Ratnayake NP, Roser BP (2017) Middle to late Holocene environmental changes in the depositional system of the tropical brackish Bolgoda Lake, coastal southwest Sri Lanka. Palaeogeogr Palaeoclimatol Palaeoecol 465:122–137

    Article  Google Scholar 

  • Reimer PJ, Bard E, Bayliss A, Beck JW, Blackwell PG, Ramsey CB, Buck CE, Cheng H, Edwards RL, Friedrich M, Grootes PM, Guilderson TP, Haflidason H, Hajdas I, Hatte C, Heaton TJ, Hoffmann DL, Hogg AG, Hughen KA, Kaiser KF, Kromer B, Manning SW, Niu M, Reimer RW, Richards DA, Scott EM, Southon JR, Staff RA, Turney CSM, van der Plicht J (2013) IntCal13 and Marine13 radiocarbon age calibration curves 0–50,000 years cal BP. Radiocarbon 55(4):1869–1887. https://doi.org/10.2458/azu_js_rc.55.16947

    Article  Google Scholar 

  • Rowe H, Ruppel S, Rimmer S, Loucks R (2009) Core-based chemostratigraphy of the Barnett Shale, Permian Basin, Texas. Gulf Coast Assoc Geol Soc Trans 59:675–686

    Google Scholar 

  • Sampei Y, Matsumoto E, Kamei T, Tokuoka T (1997) Sulfur and organic carbon relationship in sediments from coastal brackish lakes in the Shimane peninsula district, southwest Japan. Geochem J 31(4):245–262

    Article  Google Scholar 

  • Schlichting RB, Peterson CD (2006) Mapped overland distance of paleo-tsunami high-velocity inundation in back-barrier wetlands of the central Cascadia margin, USA. J Geol 114(5):577–592

    Article  Google Scholar 

  • Tantanasarit C, Englande AJ, Babel S (2013) Nitrogen, phosphorus and silicon uptake kinetics by marine diatom Chaetoceroscalcitrans under high nutrient concentrations. J Exp Mar Biol Ecol 446:67–75

    Article  Google Scholar 

  • Tribovillard N, Algeo TJ, Baudin F, Riboulleau A (2012) Analysis of marine environmental conditions based onmolybdenum–uranium covariation—applications to mesozoic paleoceanography. Chem Geol 324:46–58

    Article  Google Scholar 

  • Tsunogai S, Henmi T (1971) Iodine in the surface water of the ocean. J Oceanogr Soc Jpn 27:67–72

    Article  Google Scholar 

  • Wong GTF (1976) Dissolved inorganic and particulate iodine in the oceans. In: Ph.D. Thesis, Massachusetts Institute of Technology, Woods Hole Oceanographic Institution, pp 183–230

  • Zhang J, Fan T, Algeo TJ, Li Y, Zhang J (2016) Paleo-marine environments of the early Cambrian Yangtze Platform. Palaeogeogr Palaeoclimatol Palaeoecol 443:66–79

    Article  Google Scholar 

Download references

Acknowledgements

The authors highly appreciate the staff of The Shimane University, Japan, for providing access to the XRF facility. Head of the Department of Geology, University of Peradeniya and Head of the Department of Physical Sciences, South Eastern University of Sri Lanka are also acknowledged for providing the laboratory facilities. Dr. Carla Eichler of Texas Tech University, USA, and Ms. G. Wijewardane of University of Melbourne, Australia, are acknowledged for correcting the manuscript.

Funding

The research was financially supported by University Grant Commission, Sri Lanka (Grant No. UGC/DRIC/PG/2014AUG/SEUSL/01).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Madurya Adikaram.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Adikaram, M., Pitawala, A., Ishiga, H. et al. I–P2O5 diagrams as an indicator of depositional environment in marine sediments: preliminary findings (Sri Lanka). Environ Earth Sci 76, 817 (2017). https://doi.org/10.1007/s12665-017-7167-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s12665-017-7167-7

Keywords

Navigation