Skip to main content

Advertisement

Log in

Research progress of the electrochemical impedance technique applied to the high-capacity lithium-ion battery

  • Invited Review
  • Published:
International Journal of Minerals, Metallurgy and Materials Aims and scope Submit manuscript

Abstract

The world’s energy system is changing dramatically. Li-ion battery, as a powerful and highly effective energy storage technique, is crucial to the new energy revolution for its continuously expanding application in electric vehicles and grids. Over the entire lifetime of these power batteries, it is essential to monitor their state of health not only for the predicted mileage and safety management of the running electric vehicles, but also for an “end-of-life” evaluation for their repurpose. Electrochemical impedance spectroscopy (EIS) has been widely used to diagnose the health state of batteries quickly and nondestructively. In this review, we have outlined the working principles of several electrochemical impedance techniques and further evaluated their application prospects to achieve the goal of nondestructive testing of battery health. EIS can scientifically and reasonably perform real-time monitoring and evaluation of electric vehicle power batteries in the future and play an important role in vehicle safety and battery gradient utilization.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. W.D. Li, E.M. Erickson, and A. Manthiram, High-nickel layered oxide cathodes for lithium-based automotive batteries, Nat. Energy, 5(2020), No. 1, p. 26.

    Article  CAS  Google Scholar 

  2. W. Huang, D.T. Boyle, Y.Z. Li, Y.B. Li, A. Pei, H. Chen, and Y. Cui, Nanostructural and electrochemical evolution of the solid-electrolyte interphase on CuO nanowires revealed by cryogenic-electron microscopy and impedance spectroscopy, ACS Nano, 13(2019), No. 1, p. 737.

    Article  CAS  Google Scholar 

  3. V.V. Viswanathan and M. Kintner-Meyer, Second use of transportation batteries: Maximizing the value of batteries for transportation and grid services, IEEE Trans. Veh. Technol., 60(2011), No. 7, p. 2963.

    Article  Google Scholar 

  4. D.M. Cheng, J. Zhou, J. Li, C.G. Du, and H. Zhang, Analysis in power battery gradient utilization of electric vehicle, Adv. Mater. Res., 347–353(2011), p. 555.

    Article  Google Scholar 

  5. J. Vetter, P. Novák, M.R. Wagner, C. Veit, K.C. Möller, J.O. Besenhard, M. Winter, M. Wohlfahrt-Mehrens, C. Vogler, and A. Hammouche, Ageing mechanisms in lithium-ion batteries, J. Power Sources, 147(2005), No. 1–2, p. 269.

    Article  CAS  Google Scholar 

  6. J. Groot, State-of-health Estimation of Li-ion Batteries: Cycle Life Test Methods [Dissertation], Chalmers University of Technology, 2012.

  7. C. Schlasza, P. Ostertag, D. Chrenko, R. Kriesten, and D. Bouquain, Review on the aging mechanisms in Li-ion batteries for electric vehicles based on the FMEA method, 2014 IEEE Transp. Electrif. Conf. Expo Components, Syst. Power Electron.-From Technol. to Bus. Public Policy, ITEC 2014, (2014), p. 1.

  8. J. Neubauer and A. Pesaran, The ability of battery second use strategies to impact plug-in electric vehicle prices and serve utility energy storage applications, J. Power Sources, 196(2011), No. 23, p. 10351.

    Article  CAS  Google Scholar 

  9. E. Locorotondo, V. Cultrera, L. Pugi, L. Berzi, M. Pasquali, N. Andrenacci, G. Lutzemberger, and M. Pierini, Electrical lithium battery performance model for second life applications, [in] 2020 IEEE International Conference on Environment and Electrical Engineering and 2020 IEEE Industrial and Commercial Power Systems Europe (EEEIC/I&CPS Europe), Madrid, Spain, 2020, doi: https://doi.org/10.1109/EEEIC/ICPSEurope49358.2020.9160496.

  10. H.F. Dai, X.Z. Wei, and Z.C. Sun, State and parameter estimation of a HEV Li-ion battery pack using adaptive kalman filter with a new SOC-OCV concept, [in] 2009 International Conference on Measuring Technology and Mechatronics Automation, Zhangjiajie, 2009, p. 375.

  11. G. Nagasubramanian, Two- and three-electrode impedance studies on 18650 Li-ion cells, J. Power Sources, 87(2000), No. 1–2, p. 226.

    Article  CAS  Google Scholar 

  12. J. Li, E. Murphy, J. Winnick, and P.A. Kohl, Studies on the cycle life of commercial lithium ion batteries during rapid charge-discharge cycling, J. Power Sources, 102(2001), No. 1–2, p. 294.

    Article  CAS  Google Scholar 

  13. E. Locorotondo, V. Cultrera, L. Pugi, L. Berzi, M. Pasquali, N. Andrenacci, G. Lutzemberger, and M. Pierini, Impedance spectroscopy characterization of lithium batteries with different ages in second life application, [in] 2020 IEEE International Conference on Environment and Electrical Engineering and 2020 IEEE Industrial and Commercial Power Systems Europe (EEE-IC/I&CPS Europe), Madrid, Spain, 2020, doi: https://doi.org/10.1109/EEE-IC/ICPSEurope49358.2020.9160616.

  14. L. Berzi, V. Cultrera, M. Delogu, M. Dolfi, E. Locorotondo, F. Del Pero, S. Morosi, L. Pugi, and A. Tanturli, A model for system integration of second life battery, renewable energy generation and mobile network station, [in] 2020 IEEE International Conference on Environment and Electrical Engineering and 2020 IEEE Industrial and Commercial Power Systems Europe (EEEIC/I&CPS Europe), Madrid, Spain, 2020, doi: https://doi.org/10.1109/EEEIC/ICPSEurope49358.2020.9160747.

  15. T. Osaka, T. Momma, D. Mukoyama, and H. Nara, Proposal of novel equivalent circuit for electrochemical impedance analysis of commercially available lithium ion battery, J. Power Sources, 205(2012), p. 483.

    Article  CAS  Google Scholar 

  16. D. Mukoyama, T. Momma, H. Nara, and T. Osaka, Electrochemical impedance analysis on degradation of commercially available lithium ion battery during charge-discharge cycling, Chem. Lett., 41(2012), No. 4, p. 444.

    Article  CAS  Google Scholar 

  17. N. Togasaki, T. Yokoshima, Y. Oguma, and T. Osaka, Prediction of overcharge-induced serious capacity fading in nickel cobalt aluminum oxide lithium-ion batteries using electrochemical impedance spectroscopy, J. Power Sources, 461(2020), art. No. 228168.

  18. S.S. Zhang, K. Xu, and T.R. Jow, EIS study on the formation of solid electrolyte interface in Li-ion battery, Electrochim. Acta, 51(2006), No. 8–9, p. 1636.

    Article  CAS  Google Scholar 

  19. F. Huet, A review of impedance measurements for determination of the state-of-charge or state-of-health of secondary batteries, J. Power Sources, 70(1998), No. 1, p. 59.

    Article  CAS  Google Scholar 

  20. T. Hang, D. Mukoyama, H. Nara, N. Takami, T. Momma, and T. Osaka, Electrochemical impedance spectroscopy analysis for lithium-ion battery using Li4Ti5O12 anode, J. Power Sources, 222(2013), p. 442.

    Article  CAS  Google Scholar 

  21. E. Barsoukov, J.H. Kim, J.H. Kim, C.O. Yoon, and H. Lee, Kinetics of lithium intercalation into carbon anodes: In situ impedance investigation of thickness and potential dependence, Solid State Ionics, 116(1999), No. 3–4, p. 249.

    Article  CAS  Google Scholar 

  22. H. Nara, T. Yokoshima, and T. Osaka, Technology of electrochemical impedance spectroscopy for an energy-sustainable society, Curr. Opin. Electrochem., 20(2020), p. 66.

    Article  CAS  Google Scholar 

  23. R. Srinivasan, B.G. Carkhuff, M.H. Butler, and A.C. Baisden, Instantaneous measurement of the internal temperature in lithium-ion rechargeable cells, Electrochim. Acta, 56(2011), No. 17, p. 6198.

    Article  CAS  Google Scholar 

  24. E. Azzarello, E. Masi, and S. Mancuso, Electrochemical impedance spectroscopy (EIS) study of LiNi1/3Co1/3Mn1/3O2 for Li-ion batteries, Int. J, Electrochem. Sci., 7(2012), p. 345.

    Google Scholar 

  25. D. Aurbach, K. Gamolsky, B. Markovsky, G. Salitra, Y. Gofer, U. Heider, R. Oesten, and M. Schmidt, The study of surface phenomena related to electrochemical lithium intercalation into LixMOy host materials (M=Ni, Mn), J. Electrochem. Soc., 147(2000), No. 4, p. 1322.

    Article  CAS  Google Scholar 

  26. S.S. Zhang, K. Xu, and T.R. Jow, Understanding formation of solid electrolyte interface film on LiMn2O4 electrode, J. Electrochem. Soc., 149(2002), No. 12, p. A1521.

    Article  CAS  Google Scholar 

  27. S.S. Zhang, K. Xu, and T.R. Jow, Formation of solid electrolyte interface in lithium nickel mixed oxide electrodes during the first cycling, Electrochem. Solid-State Lett., 5(2002), No. 5, p. A92.

    Article  CAS  Google Scholar 

  28. R. Mingant, J. Bernard, and V. Sauvant-Moynot, Novel state-of-health diagnostic method for Li-ion battery in service, Appl. Energy, 183(2016), p. 390.

    Article  CAS  Google Scholar 

  29. T. Yokoshima, D. Mukoyama, K. Nakazawa, Y. Gima, H. Isawa, H. Nara, T. Momma, and T. Osaka, Application of electrochemical impedance spectroscopy to ferri/ferrocyanide redox couple and lithium ion battery systems using a square wave as signal input, Electrochim. Acta, 180(2015), p. 922.

    Article  CAS  Google Scholar 

  30. S.M. Park and J.S. Yoo, Electrochemical impedance spectroscopy for better electrochemical measurements, Anal. Chem., 75(2003), No. 21, p. 455A.

    CAS  Google Scholar 

  31. B.Y. Chang, and S.M. Park, Fourier transform analysis of chronoamperometric currents obtained during staircase voltammetric experiments, Anal. Chem., 79(2007), No. 13, p. 4892.

    Article  CAS  Google Scholar 

  32. S.M. Park, J.S. Yoo, B.Y. Chang, and E.S. Ahn, Novel instrumentation in electrochemical impedance spectroscopy and a full description of an electrochemical system, Pure Appl. Chem., 78(2006), No. 5, p. 1069.

    Article  CAS  Google Scholar 

  33. T. Yokoshima, D. Mukoyama, H. Nara, S. Maeda, K. Nakazawa, T. Momma, and T. Osaka, Impedance measurements of kilowatt-class lithium ion battery modules/cubicles in energy storage systems by square-current electrochemical impedance spectroscopy, Electrochim. Acta, 246(2017), p. 800.

    Article  CAS  Google Scholar 

  34. S.M. Park and J.S. Yoo, Apparatus and Method for Measuring Electrochemical Impedance at High Speed, United States Patent, Appl. 6339334 B1, 2002.

  35. Y. Hoshi, N. Yakabe, K. Isobe, T. Saito, I. Shitanda, and M. Itagaki, Wavelet transformation to determine impedance spectra of lithium-ion rechargeable battery, J. Power Sources, 315(2016), p. 351.

    Article  CAS  Google Scholar 

  36. J. Hoja and G. Lentka, Method using square-pulse excitation for high-impedance spectroscopy of anticorrosion coatings, IEEE Trans. Instrum. Meas., 60(2011), No. 3, p. 957.

    Article  Google Scholar 

  37. M. Itagaki, M. Ueno, Y. Hoshi, and I. Shitanda, Simultaneous determination of electrochemical impedance of lithium-ion rechargeable batteries with measurement of charge-discharge curves by wavelet transformation, Electrochim. Acta, 235(2017), p. 384.

    Article  CAS  Google Scholar 

  38. J.H. Zhang, Impedance measurement and analysis for battery based on wavelet transformation, J. Jiamusi Univ. (Natural Science Edition), 36(2018), No. 1, p. 144.

    Google Scholar 

  39. M. Itagaki, Y. Gamano, Y. Hoshi, and I. Shitanda, Determination of electrochemical impedance of lithium ion battery from time series data by wavelet transformation-uncertainty of resolutions in time and frequency domains, Electrochim. Acta, 332(2020), art. No. 135462.

  40. J. Wang, Y.Y. Yu, B. Li, P. Zhang, J.X. Huang, F. Wang, S.Y. Zhao, C.L. Gan, and J.B. Zhao, Thermal synergy effect between LiNi0.5Co0.2Mn0.3O2 and LiMn2O4 enhances the safety of blended cathode for lithium ion batteries, ACS Appl. Mater. Interfaces, 8(2016), No. 31, p. 20147.

    Article  CAS  Google Scholar 

  41. S. Lee and J. Kim, Discrete wavelet transform-based denoising technique for advanced state-of-charge estimator of a lithiumion battery in electric vehicles, Energy, 83(2015), p. 462.

    Article  Google Scholar 

  42. J. Huang, J.B. Zhang, Z. Li, S.L. Song, and N.N. Wu, Exploring differences between charge and discharge of LiMn2O4/Li half-cell with dynamic electrochemical impedance spectroscopy, Electrochim. Acta, 131(2014), p. 228.

    Article  CAS  Google Scholar 

  43. D. Chenvidhya, K. Kirtikara, and C. Jivacate, A new characterization method for solar cell dynamic impedance, Sol. Energy Mater. Sol. Cells, 80(2003), No. 4, p. 459.

    Article  CAS  Google Scholar 

  44. M. Itagaki, A. Ono, K. Watanabe, H. Katayama, and K. Noda, Analysis on organic film degradation by dynamic impedance measurements, Corros. Sci., 48(2006), No. 11, p. 3802.

    Article  CAS  Google Scholar 

  45. J. Huang, Z. Li, and J.B. Zhang, Dynamic electrochemical impedance spectroscopy reconstructed from continuous impedance measurement of single frequency during charging/discharging, J. Power Sources, 273(2015), p. 1098.

    Article  CAS  Google Scholar 

  46. T. Holm, S. Sunde, F. Seland, and D.A. Harrington, Understanding reaction mechanisms using dynamic electrochemical impedance spectroscopy: Methanol oxidation on Pt, Electrochim. Acta, 323(2019), art. No. 134764.

  47. J. Huang, H. Ge, Z. Li, and J.B. Zhang, Dynamic electrochemical impedance spectroscopy of a three-electrode lithium-ion battery during pulse charge and discharge, Electrochim. Acta, 176(2015), p. 311.

    Article  CAS  Google Scholar 

  48. H.L. Liang, S. Yuan, L.Y. Shi, Y. Zhao, Z.Y. Wang, and J.F. Zhu, Highly-ordered microstructure and well performance of LiNi0.6Mn0.2Co0.2O2 cathode material via the continuous microfluidic synthesis, Chem. Eng. J., 394(2020), art. No. 124846.

  49. M. Itagaki, N. Kobari, S. Yotsuda, K. Watanabe, S. Kinoshita, and M. Ue, In situ electrochemical impedance spectroscopy to investigate negative electrode of lithium-ion rechargeable batteries, J. Power Sources, 135(2004), No. 1–2, p. 255.

    Article  CAS  Google Scholar 

  50. M. Itagaki, N. Kobari, S. Yotsuda, K. Watanabe, S. Kinoshita, and M. Ue, LiCoO2 electrode/electrolyte interface of Li-ion rechargeable batteries investigated by in situ electrochemical impedance spectroscopy, J. Power Sources, 148(2005), p. 78.

    Article  CAS  Google Scholar 

  51. M. Darab, P.K. Dahlstrøm, M.S. Thomassen, F. Seland, and S. Sunde, Dynamic electrochemical impedance spectroscopy of Pt/C-based membrane-electrode assemblies subjected to cycling protocols, J. Power Sources, 242(2013), p. 447.

    Article  CAS  Google Scholar 

  52. T. Pongklang, D. Chenvidhya, K. Kirtikara, S. Chuangchote, and N. Silsirivanich, Voltage and frequency dependent impedances of dye-sensitized solar cell, Energy Procedia, 52(2014), p. 536.

    Article  CAS  Google Scholar 

  53. P. Shafiei Sabet, A.J. Warnecke, F. Meier, H. Witzenhausen, E. Martinez-Laserna, and D.U. Sauer, Non-invasive yet separate investigation of anode/cathode degradation of lithium-ion batteries (nickel-cobalt-manganese vs. graphite) due to accelerated aging, J. Power Sources, 449(2020), art. No. 227369.

  54. P. Shafiei Sabet and D.U. Sauer, Separation of predominant processes in electrochemical impedance spectra of lithium-ion batteries with nickel-manganese-cobalt cathodes, J. Power Sources, 425(2019), p. 121.

    Article  CAS  Google Scholar 

  55. Y. Zheng, Y.B. He, K. Qian, B.H. Li, X.D. Wang, J.L. Li, S.W. Chiang, C. Miao, F.Y. Kang, and J.B. Zhang, Deterioration of lithium iron phosphate/graphite power batteries under high-rate discharge cycling, Electrochim. Acta, 176(2015), p. 270.

    Article  CAS  Google Scholar 

  56. S.S. Zhang, K. Xu, and T.R. Jow, The low temperature performance of Li-ion batteries, J. Power Sources, 115(2003), No. 1, p. 137.

    Article  CAS  Google Scholar 

  57. Z.T. Dong, Y. Li, K.L. Ren, S.Q. Yang, Y.M. Zhao, Y.J. Yuan, L. Zhang, and S.M. Han, Enhanced electrochemical properties of LaFeO3 with Ni modification for MH-Ni batteries, Int. J. Miner. Metall. Mater., 25(2018), No. 10, p. 1201.

    Article  CAS  Google Scholar 

  58. M.A. Iqbal and M. Fedel, Ordering and disordering of in situ grown MgAl-layered double hydroxide and its effect on the structural and corrosion resistance properties, Int. J. Miner. Metall. Mater., 26(2019), No. 12, p. 1570.

    Article  CAS  Google Scholar 

  59. A. Xiao, W.T. Li, and B.L. Lucht, Thermal reactions of mesocarbon microbead (MCMB) particles in LiPF6-based electrolyte, J. Power Sources, 162(2006), No. 2, p. 1282.

    Article  CAS  Google Scholar 

  60. J.Y. Zhang, X.Q. Yang, G.Q. Zhang, Q.Q. Huang, C.R. Xiao, and C.X. Yang, Investigation on the root cause of the decreased performances in the overcharged lithium iron phosphate battery, Int. J. Energy Res., 42(2018), No. 7, p. 2448.

    Article  CAS  Google Scholar 

Download references

Acknowledgement

This work was financially supported by the State Grid Corporation Science and Technology Project of China (No. 520940180017).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Xin-dong Wang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, Lf., Geng, Mm., Ding, Xn. et al. Research progress of the electrochemical impedance technique applied to the high-capacity lithium-ion battery. Int J Miner Metall Mater 28, 538–552 (2021). https://doi.org/10.1007/s12613-020-2218-6

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12613-020-2218-6

Keywords

Navigation