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Effect of TiO2 nanoparticles on hydrogen evolution reaction activity of Ni coatings

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Abstract

The electrocatalytic activity of electrodeposited Ni and Ni–TiO2 coatings with regard to the alkaline hydrogen evolution reaction (HER) was investigated. The Ni coatings were electrodeposited from an acid chloride bath at different current densities, and their HER activities were examined in a 1.0-mol·L-1 KOH medium. The variations in the HER activity of the Ni coatings with changes in surface morphology and composition were examined via the electrochemical dissolution and incorporation of nanoparticles. Electrochemical analysis methods were used to monitor the HER activity of the test electrodes; this activity was confirmed via the quantification of gases that evolved during the analysis. The obtained results demonstrated that the Ni–TiO2 nanocomposite test electrode exhibited maximum activity toward the alkaline HER. The surface appearance, composition, and the phase structure of all developed coatings were analyzed using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD), respectively. The improvement in the electrocatalytic activity of Ni–TiO2 nanocomposite coating toward HER was attributed to the variation in surface morphology and increased number of active sites.

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References

  1. T.N. Veziroğlu and S. Şahin, 21st century’s energy: hydrogen energy system, Energy Convers. Manage., 49(2008), No. 7, p. 1820.

    Google Scholar 

  2. T.N. Vezir lu and F. Barbir, Hydrogen: the wonder fuel, Int. J. Hydrogen Energy, 17(1992), No. 6, p. 391.

    Article  Google Scholar 

  3. X.X. Zou and Y. Zhang, Noble metal-free hydrogen evolution catalysts for water splitting, Chem. Soc. Rev., 44(2015), No. 15, p. 5148.

    Article  Google Scholar 

  4. D. Pletcher, Electrocatalysis: present and future, J. Appl. Electrochem., 14(1984), No. 4, p. 403.

    Article  Google Scholar 

  5. F. Safizadeh, E. Ghali, and G. Houlachi, Electrocatalysis developments for hydrogen evolution reaction in alkaline solutions―A review, Int. J. Hydrogen Energy, 40(2015), No. 1, p. 256.

    Article  Google Scholar 

  6. D. Pletcher and X.H. Li, Prospects for alkaline zero gap water electrolysers for hydrogen production, Int. J. Hydrogen Energy. 36(2011), No. 23, p. 15089.

    Article  Google Scholar 

  7. B.V. Tilak, A.C. Ramamurthy, and B.E. Conway, High performance electrode materials for the hydrogen evolution reaction from alkaline media, J. Chem. Sci., 97(1986), No. 3-4, p. 359.

    Google Scholar 

  8. D.S.P. Cardoso, L. Amaral, D.M.F. Santos, B. Šljukić, C.A.C. Sequeira, D. Macciò, and A. Saccone, Enhancement of hydrogen evolution in alkaline water electrolysis by using nickel-rare earth alloys, Int. J. Hydrogen Energy, 40(2015), No. 12, p. 4295.

    Article  Google Scholar 

  9. L.J. Elias, K. Scott, and A.C. Hegde, Electrolytic synthesis and characterization of electrocatalytic Ni–W alloy, J. Mater. Eng. Perform., 24(2015), No. 11, p. 4182.

    Article  Google Scholar 

  10. L. Elias, P. Cao, and A.C. Hegde, Magnetoelectrodeposition of Ni–W alloy coatings for enhanced hydrogen evolution reaction, RSC Adv., 6(2016), No. 112, p. 111358.

    Article  Google Scholar 

  11. L. Elias and A.C. Hegde, Modification of Ni–P alloy coatings for better hydrogen production by electrochemical dissolution and TiO2 nanoparticles, RSC Adv., 6(2016), No. 70, p. 66204.

    Article  Google Scholar 

  12. N. Kanani, Electroplating: Basic Principles, Processes and Practice, Elsevier, Germany, 2004, p. 5.

    Google Scholar 

  13. L. Beneaand and A.I. Pavlov, Ni–TiO2 nanocomposite coatings as cathode material for hydrogen evolution reaction, J. Optoelectron. Adv. Mater., 7(2013), No. 11-12, p. 895.

    Google Scholar 

  14. P. Baghery, M. Farzam, A.B. Mousavi, and M. Hosseini, Ni–TiO2 nanocomposite coating with high resistance to corrosion and wear, Surf. Coat. Technol., 204(2010), No. 23, p. 3804.

    Article  Google Scholar 

  15. L. Elias and A.C. Hegde, Synthesis and characterization of Ni–P–Ag composite coating as efficient electrocatalyst for alkaline hydrogen evolution reaction, Electrochim. Acta, 219(2016), p. 377.

    Article  Google Scholar 

  16. C.T.J. Low, R.G.A. Wills, and F.C. Walsh, Electrodeposition of composite coatings containing nanoparticles in a metal deposit, Surf. Coat. Technol., 201(2006), No. 1-2, p. 371.

    Article  Google Scholar 

  17. A.A. Aal and H.B. Hassan, Electrodeposited nanocomposite coatings for fuel cell application, J. Alloys Compd., 477(2009), No. 1-2, p. 652.

    Article  Google Scholar 

  18. I.A. Raj, Nickel-based, binary-composite electrocatalysts for the cathodes in the energy-efficient industrial production of hydrogen from alkaline-water electrolytic cells, J. Mater. Sci., 28(1993), No. 16, p. 4375.

    Article  Google Scholar 

  19. C.Q. Li, X.H. Li, Z.X. Wang, and H.J. Guo, Nickel electrodeposition from novel citrate bath, Trans. Nonferrous Met. Soc. China, 17(2007), No. 6, p. 1300.

    Article  Google Scholar 

  20. E. Rudnik, M. Wojnicki, and G. Włoch, Effect of gluconate addition on the electrodeposition of nickel from acidic baths, Surf. Coat. Technol., 207(2012) 375.

    Article  Google Scholar 

  21. D. Gierlotka, E. Ro´winski, A. Budniok, and E.L. Giewka, Production and properties of electrolytic Ni–P–TiO2 composite layers, J. Appl. Electrochem., 27(1997), No. 12, p. 1349.

    Article  Google Scholar 

  22. I. Ruzybayev, E. Yassitepe, A. Ali, A.S. Bhatti, R.M. Mohamed, M. Islam, and S.I. Shah, Reactive pulsed laser deposited N–C codoped TiO2 thin films, Mater. Sci. Semicond. Process., 39(2015), p. 371.

    Article  Google Scholar 

  23. S. Javed, M. Mujahid, M. Islam, and U. Manzoor, Morphological effects of reflux condensation on nanocrystalline anatase gel and thin films, Mater. Chem. Phys., 132(2012), No. 2-3, p. 509.

    Article  Google Scholar 

  24. M. Islam and T. Shehbaz, Effect of synthesis conditions and post-deposition treatments on composition and structural morphology of medium-phosphorus electroless Ni–P films, Surf. Coat. Technol., 205(2011), No. 19, p. 4397.

    Article  Google Scholar 

  25. L. Elias and A.C. Hegde, Effect of including the carbon nanotube and graphene oxide on the electrocatalytic behavior of the Ni–W alloy for the hydrogen evolution reaction, New J. Chem., 41(2017), No. 22, p. 13912.

    Article  Google Scholar 

  26. M. Islam, M.R. Azhar, N. Fredj, and T.D. Burleigh, Electrochemical impedance spectroscopy and indentation studies of pure and composite electroless Ni–P coatings, Surf. Coat. Technol., 236(2013), p. 262.

    Article  Google Scholar 

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Acknowledgements

Dr. Liju Elias is thankful to National Institute of Technology Karnataka (NITK), Surathkal, India, for providing the facilities to conduct this research.

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Correspondence to Ampar Chitharanjan Hegde.

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Kullaiah, R., Elias, L. & Hegde, A.C. Effect of TiO2 nanoparticles on hydrogen evolution reaction activity of Ni coatings. Int J Miner Metall Mater 25, 472–479 (2018). https://doi.org/10.1007/s12613-018-1593-8

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  • DOI: https://doi.org/10.1007/s12613-018-1593-8

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