Abstract
In this work tin-cobalt-carbon alloy was prepared by high energy ball milling and Cu foil was treated by electro-deposition method. The results show that alloy materials coated on surface-treated Cu foil display high discharge capacity and cycling performance than those coated on original Cu foil because of improved contact ability and buffer effect on large volume changes of alloy materials. After 50 cycles the alloy materials coated on surface-treated Cu foil retain discharge capacity of 450 mAh/g.
Similar content being viewed by others
References
Winter M., and Besenhard J.O., Electrochemical lithiation of tin and tin-based intermetallics and composites, Electrochim. Acta, 1999, 45: 31.
Courtney I.A., and Dahn J.R., Electrochemical and In situ X-ray diffraction studies of the reaction of lithium with tin oxide composites, J. Electrochem. Soc., 1997, 144 (6): 2045.
Noh M., Kim Y. Kim M.G., Lee H., Kim H., Kwon Y., Lee Y., and Cho J., Monomer-capped tin metal nanoparticles for anode materials in lithium secondary batteries, Chem. Mater., 2005, 17(13): 3320.
Hassoun J., Panero S., Mulas G., and Scrosati B., An electrochemical investigation of a Sn-Co-C ternary alloy as a negative electrode in Li-ion batteries, J. Power Sources, 2007, 171: 928.
Hassoun J., Panero S., Mulas G., and Scrosati B., Ternary Sn-Co-C Li-ion battery electrode material prepared by high energy ball billing, Electrochem. Commun., 2007, 9: 2075.
Fan Q., Chupas P.J., and Whittingham M.S., Characterization of amorphous and crystalline tin-cobalt anodes, Electrochem. Solid State Lett. 2007, 10(12): A274.
Tamura N., Kato Y., Mikami A., Kamino M., Matsuta S., and Fujitani S., Study on Sn-Co alloy anodes for lithium secondary batteries I. amorphous system, J. Electrochem. Soc., 2006, 153(8): A1626.
Tamura N., Kato Y., Mikami A., Kamino M., Matsuta S., and Fujitani S., Study on Sn-Co alloy anodes for lithium secondary batteries II. nanocomposite system. J. Electrochem. Soc., 2006, 153(12): A2227.
Tamura N., Fujimoto M., Kamino M., and Fujitani S., Mechanical stability of Sn-Co alloy anodes for lithium secondary batteries. Electrochim. Acta, 2004, 49: 1949.
Yin J., Wada M., Kitano Y., Tanase S., Kajita O., and Sakai T., Nanostructured Ag-Fe-Sn/Carbon nanotubes composites as anode materials for advanced lithium-ion batteries, J. Electrochem. Soc., 2005, 152: A1341.
Hassoun J., Derrien G., Panero S., and Scrosati B., A nanostructured Sn-C composite lithium battery electrode with unique stability and high electrochemical performance, Adv. Mater. 2008, 20: 3169.
Jung Y.S., Lee K.T., Ryu J.H., Im D., and Oh S.M., Sn-carbon core-shell powder for anode in lithium secondary batteries, J. Electrochem. Soc., 2005, 152(7): A1452.
Todd A.D.W., Mar R.E., and Dahn J.R., Tin-transition metalcarbon systems for lithium-ion battery negative electrodes, J. Electrochem. Soc., 2007, 154(6): A597.
Todd A.D.W., Mar R.E., and Dahn J.R., Combinatorial study of tin-transition metal alloys as negative electrodes for lithium-ion batteries, J. Electrochem. Soc., 2006, 153(10): A1998.
Zhang J., and Xia Y., Co-Sn alloys as negative electrode materials for rechargeable lithium batteries, J. Electrochem. Soc., 2006, 153(8): A1466.
Ionica-Bousquet C.M., Lippens P.E., Aldon L., Olivier-Fourcade J., and Jumas J.C., In situ 119Sn Mossbauer effect study of Li-CoSn2 electrochemical system, Chem. Mater., 2006, 18: 6442.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Xia, J., Liu, Z., Li, D. et al. Effect of current collector on electrochemical performance of alloy anodes of lithium ion batteries. Rare Metals 30 (Suppl 1), 48–51 (2011). https://doi.org/10.1007/s12598-011-0235-3
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12598-011-0235-3