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Effect of current collector on electrochemical performance of alloy anodes of lithium ion batteries

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Abstract

In this work tin-cobalt-carbon alloy was prepared by high energy ball milling and Cu foil was treated by electro-deposition method. The results show that alloy materials coated on surface-treated Cu foil display high discharge capacity and cycling performance than those coated on original Cu foil because of improved contact ability and buffer effect on large volume changes of alloy materials. After 50 cycles the alloy materials coated on surface-treated Cu foil retain discharge capacity of 450 mAh/g.

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References

  1. Winter M., and Besenhard J.O., Electrochemical lithiation of tin and tin-based intermetallics and composites, Electrochim. Acta, 1999, 45: 31.

    Article  CAS  Google Scholar 

  2. Courtney I.A., and Dahn J.R., Electrochemical and In situ X-ray diffraction studies of the reaction of lithium with tin oxide composites, J. Electrochem. Soc., 1997, 144 (6): 2045.

  3. Noh M., Kim Y. Kim M.G., Lee H., Kim H., Kwon Y., Lee Y., and Cho J., Monomer-capped tin metal nanoparticles for anode materials in lithium secondary batteries, Chem. Mater., 2005, 17(13): 3320.

    Article  CAS  Google Scholar 

  4. Hassoun J., Panero S., Mulas G., and Scrosati B., An electrochemical investigation of a Sn-Co-C ternary alloy as a negative electrode in Li-ion batteries, J. Power Sources, 2007, 171: 928.

    Article  CAS  Google Scholar 

  5. Hassoun J., Panero S., Mulas G., and Scrosati B., Ternary Sn-Co-C Li-ion battery electrode material prepared by high energy ball billing, Electrochem. Commun., 2007, 9: 2075.

    Article  CAS  Google Scholar 

  6. Fan Q., Chupas P.J., and Whittingham M.S., Characterization of amorphous and crystalline tin-cobalt anodes, Electrochem. Solid State Lett. 2007, 10(12): A274.

    Article  CAS  Google Scholar 

  7. Tamura N., Kato Y., Mikami A., Kamino M., Matsuta S., and Fujitani S., Study on Sn-Co alloy anodes for lithium secondary batteries I. amorphous system, J. Electrochem. Soc., 2006, 153(8): A1626.

    Article  CAS  Google Scholar 

  8. Tamura N., Kato Y., Mikami A., Kamino M., Matsuta S., and Fujitani S., Study on Sn-Co alloy anodes for lithium secondary batteries II. nanocomposite system. J. Electrochem. Soc., 2006, 153(12): A2227.

    Article  CAS  Google Scholar 

  9. Tamura N., Fujimoto M., Kamino M., and Fujitani S., Mechanical stability of Sn-Co alloy anodes for lithium secondary batteries. Electrochim. Acta, 2004, 49: 1949.

    Article  CAS  Google Scholar 

  10. Yin J., Wada M., Kitano Y., Tanase S., Kajita O., and Sakai T., Nanostructured Ag-Fe-Sn/Carbon nanotubes composites as anode materials for advanced lithium-ion batteries, J. Electrochem. Soc., 2005, 152: A1341.

    Article  CAS  Google Scholar 

  11. Hassoun J., Derrien G., Panero S., and Scrosati B., A nanostructured Sn-C composite lithium battery electrode with unique stability and high electrochemical performance, Adv. Mater. 2008, 20: 3169.

    Article  CAS  Google Scholar 

  12. Jung Y.S., Lee K.T., Ryu J.H., Im D., and Oh S.M., Sn-carbon core-shell powder for anode in lithium secondary batteries, J. Electrochem. Soc., 2005, 152(7): A1452.

    Article  CAS  Google Scholar 

  13. Todd A.D.W., Mar R.E., and Dahn J.R., Tin-transition metalcarbon systems for lithium-ion battery negative electrodes, J. Electrochem. Soc., 2007, 154(6): A597.

    Article  CAS  Google Scholar 

  14. Todd A.D.W., Mar R.E., and Dahn J.R., Combinatorial study of tin-transition metal alloys as negative electrodes for lithium-ion batteries, J. Electrochem. Soc., 2006, 153(10): A1998.

    Article  CAS  Google Scholar 

  15. Zhang J., and Xia Y., Co-Sn alloys as negative electrode materials for rechargeable lithium batteries, J. Electrochem. Soc., 2006, 153(8): A1466.

    Article  CAS  Google Scholar 

  16. Ionica-Bousquet C.M., Lippens P.E., Aldon L., Olivier-Fourcade J., and Jumas J.C., In situ 119Sn Mossbauer effect study of Li-CoSn2 electrochemical system, Chem. Mater., 2006, 18: 6442.

    Article  CAS  Google Scholar 

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Correspondence to Jianhua Xia.

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Xia, J., Liu, Z., Li, D. et al. Effect of current collector on electrochemical performance of alloy anodes of lithium ion batteries. Rare Metals 30 (Suppl 1), 48–51 (2011). https://doi.org/10.1007/s12598-011-0235-3

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  • DOI: https://doi.org/10.1007/s12598-011-0235-3

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