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Light-controlled synthesis of uniform platinum nanodendrites with markedly enhanced electrocatalytic activity

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Abstract

We report a fast in situ seeding approach based on zinc(II) porphyrin (ZnP) under white light irradiation, leading to uniform spherical platinum nanodendrites with tunable sizes. The platinum nanodendrites exhibit significantly improved electrocatalytic activities toward oxygen reduction reaction (ORR) and methanol oxidation reaction (MOR) compared with commercial platinum black.

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References

  1. Wu, H.; Chan, G.; Choi, J. W.; Ryu, I.; Yao, Y.; McDowell, M. T.; Lee, S. W.; Jackson, A.; Yang, Y.; Hu, L. B.; et al. Stable cycling of double-walled silicon nanotube battery anodes through solid-electrolyte interphase control. Nat. Nanotechnol. 2012, 7, 309–314.

    Google Scholar 

  2. Merlet, C.; Rotenberg, B.; Madden, P. A.; Taberna, P. L.; Simon, P.; Gogotsi, Y.; Salanne, M. On the molecular origin of supercapacitance in nanoporous carbon electrodes. Nat. Mater. 2012, 11, 306–310.

    Article  CAS  Google Scholar 

  3. Lubner, C. E.; Applegate, A. M.; Knorzer, P.; Ganago, A.; Bryant, D. A.; Happe, T.; Golbeck, J. H. Solar hydrogen-producing bionanodevice outperforms natural photosynthesis. Proc. Natl. Acad. Sci. USA 2011, 108, 20988–20991.

    Article  CAS  Google Scholar 

  4. Wu, G.; More, K. L.; Johnston, C. M.; Zelenay, P. High-performance electrocatalysts for oxygen reduction derived from polyaniline, iron, and cobalt. Science 2011, 332, 443–447.

    Article  CAS  Google Scholar 

  5. Hochbaum, A. I.; Yang, P. D. Semiconductor nanowires for energy conversion. Chem. Rev. 2010, 110, 527–546.

    Article  CAS  Google Scholar 

  6. Somorjai, G. A.; Park, J. Y. Molecular surface chemistry by metal single crystals and nanoparticles from vacuum to high pressure. Chem. Soc. Rev. 2008, 37, 2155–2162.

    Article  CAS  Google Scholar 

  7. Rycenga, M.; Cobley, C. M.; Zeng, J.; Li, W. Y.; Moran, C. H.; Zhang, Q.; Qin, D.; Xia, Y. N. Controlling the synthesis and assembly of silver nanostructures for plasmonic applications. Chem. Rev. 2011, 111, 3669–3712.

    Article  CAS  Google Scholar 

  8. Huang, X. H.; Neretina, S.; El-Sayed, M. A. Gold nanorods: From synthesis and properties to biological and biomedical applications. Adv. Mater. 2009, 21, 4880–4910.

    Article  CAS  Google Scholar 

  9. Lim, B.; Jiang, M. J.; Camargo, P. H. C.; Cho, E. C.; Tao, J.; Lu, X. M.; Zhu, Y. M.; Xia, Y. N. Pd-Pt bimetallic nanodendrites with high activity for oxygen reduction. Science 2009, 324, 1302–1305.

    Article  CAS  Google Scholar 

  10. Talapin, D. V.; Nelson, J. H.; Shevchenko, E. V.; Aloni, S.; Sadtler, B.; Alivisatos, A. P. Seeded growth of highly luminescent CdSe/CdS nanoheterostructures with rod and tetrapod morphologies. Nano Lett. 2007, 7, 2951–2959.

    Article  CAS  Google Scholar 

  11. Zhang, J.; Langille, M. R.; Mirkin, C. A. Synthesis of silver nanorods by low energy excitation of spherical plasmonic seeds. Nano Lett. 2011, 11, 2495–2498.

    Article  CAS  Google Scholar 

  12. Sajanlal, P. R.; Pradeep, T. Electric-field-assisted growth of highly uniform and oriented gold nanotriangles on conducting glass substrates. Adv. Mater. 2008, 20, 980–983.

    Article  CAS  Google Scholar 

  13. Jana, N. R.; Gearheart, L.; Murphy, C. J. Wet chemical synthesis of silver nanorods and nanowires of controllable aspect ratio. Chem. Commun. 2001, 617–618.

    Google Scholar 

  14. Jana, N. R.; Gearheart, L.; Murphy, C. Seed-mediated growth approach for shape-controlled synthesis of spheroidal and rod-like gold nanoparticles using a surfactant template. Adv. Mater. 2001, 13, 1389–1393.

    Article  CAS  Google Scholar 

  15. Medforth, C. J.; Wang, Z. C.; Martin, K. E.; Song, Y. J.; Jacobsen, J. L.; Shelnutt, J. A. Self-assembled porphyrin nanostructures. Chem. Commun. 2009, 7261–7277.

    Google Scholar 

  16. Garcia, R. M.; Song, Y.; Dorin, R. M.; Wang, H.; Li, P.; Qiu, Y.; van Swol, F.; Shelnutt, J. A. Light-driven synthesis of hollow platinum nanospheres. Chem. Commun. 2008, 2535–2537.

    Google Scholar 

  17. Song, Y. J.; Yang, Y.; Medforth, C. J.; Pereira, E.; Singh, A. K.; Xu, H. F.; Jiang, Y. B.; Brinker, C. J.; van Swol, F.; Shelnutt, J. A. Controlled synthesis of 2-D and 3-D dendritic platinum nanostructures. J. Am. Chem. Soc. 2004, 126, 635–645.

    Article  CAS  Google Scholar 

  18. Song, Y. J.; Garcia, R. M.; Dorin, R. M.; Wang, H. R.; Qiu, Y.; Shelnutt, J. A. Synthesis of platinum nanocages by using liposomes containing photocatalyst molecules. Angew. Chem. Int. Ed. 2006, 45, 8126–8130.

    Article  CAS  Google Scholar 

  19. Wang, H.; Song, Y.; Medforth, C. J.; Shelnutt, J. A. Interfacial synthesis of dendritic platinum nanoshells templated on benzene nanodroplets stabilized in water by a photocatalytic lipoporphyrin. J. Am. Chem. Soc. 2006, 128, 9284–9285.

    Article  CAS  Google Scholar 

  20. Song, Y. J.; Steen, W. A.; Pena, D.; Jiang, Y. B.; Medforth, C. J.; Huo, Q. S.; Pincus, J. L.; Qiu, Y.; Sasaki, D. Y.; Miller, J. E.; et al. Foamlike nanostructures created from dendritic platinum sheets on liposomes. Chem. Mater. 2006, 18, 2335–2346.

    Article  CAS  Google Scholar 

  21. Debe, M. K. Electrocatalyst approaches and challenges for automotive fuel cells. Nature 2012, 486, 43–51.

    Article  CAS  Google Scholar 

  22. Subbaraman, R.; Tripkovic, D.; Strmcnik, D.; Chang, K. C.; Uchimura, M.; Paulikas, A. P.; Stamenkovic, V.; Markovic, N. M. Enhancing hydrogen evolution activity in water splitting by tailoring Li+-Ni(OH)2-Pt interfaces. Science 2011, 334, 1256–1260.

    Article  CAS  Google Scholar 

  23. Velmurugan, J.; Zhan, D.; Mirkin, M. V. Electrochemistry through glass. Nat. Chem. 2010, 2, 498–502.

    Article  CAS  Google Scholar 

  24. Watzky, M. A.; Finke, R. G. Transition metal nanocluster formation kinetic and mechanistic studies. A new mechanism when hydrogen is the reductant: Slow, continuous nucleation and fast autocatalytic surface growth. J. Am. Chem. Soc. 1997, 119, 10382–10400.

    Article  CAS  Google Scholar 

  25. Richoux, M.-C.; Harriman, A. Influence of electrostatic forces upon the efficiency of charge separation for the zinc porphyrin/methyl viologen system. J. Chem. Soc., Faraday Trans. 1982, 78, 1873–1885.

    Article  CAS  Google Scholar 

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Correspondence to Yujiang Song.

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These two authors contributed equally to this work

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Si, W., Li, J., Li, H. et al. Light-controlled synthesis of uniform platinum nanodendrites with markedly enhanced electrocatalytic activity. Nano Res. 6, 720–725 (2013). https://doi.org/10.1007/s12274-013-0349-z

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  • DOI: https://doi.org/10.1007/s12274-013-0349-z

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