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Establishment of an effective activated peroxide system for low-temperature cotton bleaching using synthesized tetramido macrocyclic iron complex

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Abstract

In this study, the tetramido macrocyclic iron complex (Fe-TAML) was successfully synthesized, and then it was characterized using 1H nuclear magnetic resonance (1H NMR), electrospray ionization mass spectrometry (EIS-MS) and elemental analysis. An activated peroxide system was established for low-temperature bleaching of cotton by combining the synthesized catalyst (Fe-TAML) with hydrogen peroxide. Experimental results showed that the Fe-TAML/H2O2 bleaching system exhibited effective bleaching performance in the use of 2 μM Fe-TAML, 20 g/l H2O2, 1 g/l NaHCO3, 2 g/l scouring agent and 2 g/l wetting agent at 60 °C for 60 min. In comparison with the conventional bleaching system, the Fe-TAML/H2O2 system provided bleached cotton with a superior degree of whiteness, higher tensile strength and acceptable water absorbency. The application of Fe-TAML was expanded and the activated peroxide system may provide a green approach for the cotton bleaching.

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Authors and Affiliations

  1. Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, 310018, P.R. China

    Deyou Yu, Minghua Wu & Junxiong Lin

  2. Engineering Research Center for Eco-Dyeing and Finishing of Textiles, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, 310018, P.R. China

    Junxiong Lin

Authors
  1. Deyou Yu
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  2. Minghua Wu
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  3. Junxiong Lin
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Correspondence to Minghua Wu.

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Yu, D., Wu, M. & Lin, J. Establishment of an effective activated peroxide system for low-temperature cotton bleaching using synthesized tetramido macrocyclic iron complex. Fibers Polym 18, 1741–1748 (2017). https://doi.org/10.1007/s12221-017-7023-0

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  • DOI: https://doi.org/10.1007/s12221-017-7023-0

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