Abstract
Chemical treatment is an often-followed route to improve the physical and mechanical properties of natural fiber reinforced polymer matrix composites. In this study, the effect of chemical treatment on physical and mechanical properties of jute fiber reinforced polypropylene (PP) biocomposites with different fiber loading (5, 10, 15, and 20 wt%) were investigated. Before being manufactured jute fiber/PP composite, raw jute fiber was chemically treated with succinic anhydride for the chemical reaction with cellulose hydroxyl group of fiber and to increase adhesion and compatibility to the polymer matrix. Jute fiber/PP composites were fabricated using high voltage hot compression technique. Fourier Transform Infrared spectroscopy (FTIR) and Scanning Electron Microscopy (SEM) tests were employed to evaluate the morphological properties of composite. Succinic anhydride underwent a chemical reaction with raw jute fiber which was confirmed through FTIR results. SEM micrographs of the fractured surface area were taken to study the fiber/matrix interface adhesion and compatibility. Reduced fiber agglomeration and improved interfacial bonding was observed under SEM in the case of treated jute fiber/PP composites. The mechanical properties of jute/PP composite in terms of Tensile strength and Young’s modulus was found to be increased with fiber loading up to 15 wt% and decreased at 20 wt%. Conversely, flexural strength and flexural modulus increased with fiber loading up to 10 wt% and start decreasing at 15 wt%. The treated jute/PP composite samples had higher hardness (Rockwell) and lower water absorption value compared to that of the untreated ones.
Similar content being viewed by others
References
P. J. Po ec, M. J. Hine, I. M. Bonner, and D. C. Ward, Compos. Sci. Technol., 70, 45 (2010).
K. Dey, N. Sharmin, R. A. Khan, S. Nahar, A. J. Parsons, and C. D. Rudd, J. Thermoplast. Compos. Mater., 24, 695 (2011).
A. Ruhul, M. E. Khan, H. T. Haque, M. A. Khan, H. U. Zaman, K. J. Fatema, M. D. Al-Mamun, A. Khan, and M. A. Ahmad, J. Thermoplast. Compos. Mater., 23, 665 (2010).
H. S. Yang, H. J. Kim, H. J. Park, B. J. Lee, and T. S. Hwang, Compos. Struct., 72, 429 (2006).
M. R. Rahman, M. M. Huque, M. N. Islam, and M. Hasan, Compos. Part A-Appl. S., 39, 1739 (2008).
A. C. Karmaker, J. Mat. Sci. Lett., 16, 462 (1997).
P. Ghosh, D. Dev, and A. K. Samanta, J. Appl. Polym. Sci., 68, 1139 (1998).
H. U. Zaman, M. A. Khan, R. A. Khan, M. A. Rahman, L. R. Das, and M. Al-Mamun, Fiber. Polym., 11, 455 (2010).
A. K. Rana, A. Mandal, and S. Bandyopadhyay, Compos. Sci. Technol., 63, 801 (2003).
B. A. Acha, M. M. Reboredo, and N. E. Marcovich, Compos. Part A-Appl. S., 38, 1507 (2007).
M. M. Thwe and K. Liao, Compos. Part A-Appl. S., 33, 43 (2002).
M. R. Rahman, M. Hasan, M. M. Huque, and M. N. Islam, J. Thermoplast. Compos. Mat., 22, 365 (2009).
P. Wambua, J. Ivens, and I. Verpoest, Compos. Sci. Technol., 63, 259 (2003).
H. G. B. Premlal, H. Ismail, and A. A. Baharin, Polym. Test., 21, 833 (2002).
E. T. H. Vink, K. R. Rabago, D. A. Glassner, and P. R. Gruber, Polym. Degrad. Satab., 80, 403 (2003).
D. Ray, B. K. Sarkar, S. Das, and A. K. Rana, Compos. Sci. Technol., 62, 911 (2002).
M. R. Rahman, M. Hasan, M. M. Huque, and M. N. Islam, Reinforc. Plast. Compos., 29, 445 (2010).
M. A. Kabir, M. M. Huque, M. R. Islam, and A. K. Bledzki, Compos. Sci. Technol., 66, 952 (2010).
F. Vilaseca, J. A. Mendez, A. Pelach, M. Llop, N. Canigueral, J. Girones, X. Turon, and P. Mutje, Proc. Biochem., 42, 329 (2007).
M. M. Haque, M. Hasan, M. S. Islam, and M. E. Ali, Biores. Technol., 100, 4903 (2009).
M. M. Haque, M. S. Islam, M. S. Islam, M. N. Islam, M. M. Huque, and M. Hasan, Reinforc. Plast. Compos., 29, 1734 (2010).
B. K. Sarkar and D. Ray, Compos. Sci. Technol., 64, 2213 (2004).
J. Gassan and A. K. Bledzki, Compos. Sci. Technol., 59, 1303 (1999).
N. Chand and U. K. Dwivedi, Wea., 261, 1057 (2006).
H. Wang, L. Huang, and Y. Lu, Fiber. Polym., 10, 442 (2009).
E. T. H. Vink, K. R. Rabago, D. A. Glassner, and P. R. Gruber, Polym. Degrad. Satabl., 80, 403 (2003).
M. N. Islam, M. R. Rahman, M. M. Haque, and M. M. Huque, Compos. Part A-Appl. S., 41, 192 (2010).
H. U. Zaman, A. Khan, R. A. Khan, T. H. Mubarak, A. Khan, M. Shahruzzaman, M. M. Rahman, M. Al-Mamun, and P. Poddar, Fiber. Polym., 11, 258 (2010).
B. Öztürk, Fiber. Polym., 11, 464 (2010).
ASTM Standard D 638-01, Standard Test Methods for Tensile Properties of Plastics, ASTM, USA, 2002.
ASTM Standard D 790-00, Standard Test Methods for Flexural Properties of Unreinforced and Reinforced Plastics and Electrical Insulating Materials, ASTM, USA, 2002.
ASTM Standard D 785-98, Standard Test Method for Rockwell Hardness of Plastics and Electrical Insulating Materials, ASTM, USA, 2002.
M. R. Rahman, M. M. Huque, M. N. Islam, and M. Hasan, J. Thermoplast. Compos. Mat., 22, 365 (2009).
M. S. Islam, S. Hamdan, M. R. Rahman, I. Jusoh, and A. S. Ahmed, Mat. Desig., 32, 2221 (2011).
M. S. Islam, S. Hamdan, Z. A. Talib, A. S. Ahmed, and M. R. Rahman, Compos. Sci. Technol., 72, 1995 (2012).
M. S. Islam, S. Hamdan, I. Jusoh, M. R. Rahman, and A. S. Ahmed, Mat. Desig., 33, 419 (2012).
A. K. Mohanty and M. Misra, Polym. Plast. Technol. Eng., 34, 729 (1995).
A. K. Mohanty, Mubarak A Khan, and G. Hinrichsen, Compos. Sci. Technol., 60, 1115 (2000).
I. M. D. Rosa, J. M. Kenny, D. Puglia, and C. S. F. Sarasini, Compos. Sci. Technol., 70, 116 (2010).
M. N. Islam, M. M. Haque, and M. M. Huque, Ind. Eng. Chem. Res., 48, 10491 (2009).
A. Karmarkar, S. S. Chauhan, J. M. Modak, and M. Chanda, Compos. Part A-Appl. S., 38, 227 (2007).
T. T. L. Doan, S. L. Gao, and E. Mader, Compos. Sci. Technol., 66, 952 (2006).
M. A. M. M. Idrus, S. Hamdan, M. S. Islam, A. A. Roslee, and H. R. Sobuz, J. Appl. Polym. Sci., 129, 1534 (2013).
A. K. Bledzki, A. A. Mamuna, and J. Volk, Compos. Sci. Technol., 70, 840 (2010).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ahmed, A.S., Islam, M.S., Hassan, A. et al. Impact of succinic anhydride on the properties of jute fiber/polypropylene biocomposites. Fibers Polym 15, 307–314 (2014). https://doi.org/10.1007/s12221-014-0307-8
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12221-014-0307-8