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Hydrothermal synthesis, crystal structure and luminescence property of a three dimensional Sm(III) coordination polymer with 2,5-pyridinedicarboxylic acid

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Abstract

A novel three dimensional coordination polymer [Sm(2,5-pydc)(NO3)(H2O)] ⋅(H2O) (2,5-pydc = 2,5-pyridine dicarboxylate) (1) had been synthesized hydrothermally and characterized by elemental analysis, FT-IR and single-crystal X-ray diffraction analysis. This coordination polymer crystallized in the monoclinic space group P2/n with cell parameters a= 9.3610(4) Å, b= 8.3498(3) Å, c= 16.7159(8) Å, β= 106.31(0)∘, V= 1253.98(184) Å3. Thermogravimetric analysis revealed that complex 1 is stable up to 400∘C which on photoexcitation at 365 nm exhibited yellow emission at 583 nm.

A novel three dimensional coordination polymer, [Sm(2,5-pydc)(NO3)(H2O)]•H2O, built from dinuclear samarium(III) secondary building units exhibits yellow photoluminescence at 583 nm.

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Acknowledgements

We thank Dr. Abhijit Saha, UGC-DAE Consortium for Scientific Research, Kolkata Centre, India for assisting in PL measurements.

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Authors and Affiliations

  1. Department of Chemistry, GITAM University, Visakhapatnam, 530 045, A.P., India

    KRANTHI KUMAR GANGU, ANIMA S DADHICH & SARATCHANDRA BABU MUKKAMALA

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  1. KRANTHI KUMAR GANGU
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  2. ANIMA S DADHICH
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  3. SARATCHANDRA BABU MUKKAMALA
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Corresponding author

Correspondence to SARATCHANDRA BABU MUKKAMALA.

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Supplementary Information

CCDC 998830 contains the supplementary crystallographic data for coordination polymer 1. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html, or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: (+ 44) 1223-336-033; or e-mail: deposit@ccdc.cam.ac.uk. cif and Check-cif files are available at www.ias.ac.in/chemsci.

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GANGU, K.K., DADHICH, A.S. & MUKKAMALA, S.B. Hydrothermal synthesis, crystal structure and luminescence property of a three dimensional Sm(III) coordination polymer with 2,5-pyridinedicarboxylic acid. J Chem Sci 127, 2225–2230 (2015). https://doi.org/10.1007/s12039-015-0985-9

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  • DOI: https://doi.org/10.1007/s12039-015-0985-9

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