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Synthesis, characterization and spectrochemical studies on a few binuclear µ-oxo molybdenum(V) complexes of pyrimidine derived Schiff base ligands

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Abstract

Ten new binuclear singly oxo-bridged molybdenum complexes (complexes 1–10) were prepared using five pyrimidine derived Schiff base ligands and two Mo(V) precursors (NH4)2MoOCl5 and (NH4)2MoOBr5. The ligands are prepared by the condensation of 4,6-dimethyl 2-hydrazino pyrimidine with salicylaldehyde (for HL1), o-hydroxy acetophenone (for HL2) and substituted salicylaldehydes (for HL3, HL4 and HL5) respectively. These ligands are already reported as good donors for Mo(VI) state. The µ-oxo Mo(V) complexes reported here bears a distorted octahedral geometry around each Mo atom with either N2O2Cl or N2O2Br chromophores. Fine variations in the spectroscopic behaviour of the complexes are observed in accordance with the varying electron donating properties of the ligands. All the complexes are unstable in solution and X-ray quality crystal of complex 1 could be isolated. All the complexes are characterized by IR and UV-Vis spectra.

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References

  1. Mendel R R 2005 J. Chem. Soc., Dalton Trans. 3404

  2. Hille R 1996 Chem. Rev. 96 2757

    Article  CAS  Google Scholar 

  3. Hille R 2002 Trends Biochem. Sci. 27 360

    Article  CAS  Google Scholar 

  4. Stiefel E I 1996 Science 272 1599

    Article  CAS  Google Scholar 

  5. Howard J B and Rees D C 1996 Chem. Rev. 96 2965

    Article  CAS  Google Scholar 

  6. Einsle O, Tezcan F A, Andrade S L A, Schmid B, Yoshida M, Howard J B and Rees D C 2002 Science 297 1696

    Article  CAS  Google Scholar 

  7. Ridge J P, Aguey-Zinsou K-F, Bernhardt P V, Hanson G R and McEwan A G, 2004 FEBS Lett. 563 197

    Article  CAS  Google Scholar 

  8. Ridge J P and Aguey-Zinsou K-F 2002 Biochemistry 41 15762

    Article  CAS  Google Scholar 

  9. Bernhardt P V, Brereton I M, Hanson G R, McEwan A G, McAlpine A S, McEwan A G and Bailey S 1998 J. Mol. Biol. 275 613

    Article  Google Scholar 

  10. Dutta S K, McConville D B, Youngs W J and Chaudhury M 1997 Inorg. Chem. 36 2517

    Article  CAS  Google Scholar 

  11. Laughlin L J and Young C G 1996 Inorg. Chem. 35 1050

    Article  CAS  Google Scholar 

  12. Kirk M L 2003 ACS Symp. Ser. 858 340

    Article  CAS  Google Scholar 

  13. Enemark J H, Astashkin A V and Raitsimring A M 2003 ACS Symp. Ser. 858 179

    Article  CAS  Google Scholar 

  14. George G N 1997 J. Biol. Inorg. Chem. 2 790

    Article  CAS  Google Scholar 

  15. Spence J T 1983 Coord. Chem. Rev. 48 59

    Article  CAS  Google Scholar 

  16. Harlan E W and Berg J M, Holm R H 1986 J. Am. Chem. Soc. 108 6992 and references therein

    Article  CAS  Google Scholar 

  17. Purohit S., Koley A P, Prasad L S and Manoharan P T 1989 Inorg. Chem. 28 3735

    Article  CAS  Google Scholar 

  18. Mondal J U, Zamora J G, Kinon M D and Schultz F A 2000 Inorg. Chim. Acta 309 147

    Article  CAS  Google Scholar 

  19. Bustos C, Burckhardt O, Schrebler R, Carrillo D, Arif A M, Cowley A H and Nunn C M 1990 Inorg.Chem. 29 3996

    Article  CAS  Google Scholar 

  20. Dinda R, Sengupta P, Ghosh S P, Mayer-Figge H and Sheldrick W S 2002 J. Chem. Soc. Dalton Trans. 4434

  21. Haupt E TK, Wontorra C, Rehder D and Müller A 2005 Chem. Commun. 3912

  22. Gheller S F, Bradbury J R, Mackay M F and Wedd A G 1981 Inorg. Chem. 20 3899

    Article  CAS  Google Scholar 

  23. Yamanouchi K, Yamada S and Emmark J H 1984 Inorg. Chim. Acta 85 129

    Article  CAS  Google Scholar 

  24. Craig J A, Harlan E W, Synder B S, Whitener M A and Holm R H 1989 Inorg. Chem. 28 2082

    Article  CAS  Google Scholar 

  25. La Desbois O, Zamkotsian F, Faure R, Feneau-Dupont J and Declerq J-P 1995 Organometallics 14 2145

    Article  Google Scholar 

  26. Cai L-Z, Song L-J, Zeng H-Y, Dong Z-C, Guo G-C and Huang J-S 2003 Inorg. Chim. Acta 344 61

    Article  CAS  Google Scholar 

  27. Allen F H 2002 Acta Crystallogr. B58 380

    CAS  Google Scholar 

  28. Joshi V S, Nandi M, Zhang H, Haggerty B S and Sarkar A 1993 Inorg. Chem. 32 1301

    Article  CAS  Google Scholar 

  29. Chang C S J and Enemark J H 1991 Inorg. Chem. 30 683

    Article  CAS  Google Scholar 

  30. Hatton A D, Malin G, Turner S M and Liss P S 1996 in Proceedings of the International Symposium on DMSP and Related Sulfonium Compounds (eds) R P Kiene and A L Mobile p 405

  31. Sambasivarao D, Dawson H A, Zhang G, Shaw G, Hu J and Weiner J H 2001 J. Biol. Chem. 276 20167

    Article  CAS  Google Scholar 

  32. Baird D M, Falzone S and Haky J E 1989 Inorg. Chem. 28 4562

    Article  Google Scholar 

  33. Gupta S, Barik A K, Pal S, Hazra A, Roy S, Butcher R J and Kar S K 2007 Polyhedron 26 133

    Article  CAS  Google Scholar 

  34. James R G and Wardlaw W 1927 J. Chem. Soc. 2145

  35. Chiswell B and Lions F 1961 Aust. J. Chem. 22 71

    Article  Google Scholar 

  36. Gupta S, Pal S, Barik A K, Roy S, Hazra A, Mandal T N, Butcher R J and Kar S K 2009 Polyhedron 28 711

    Article  CAS  Google Scholar 

  37. Kemp W 1987 Organic spectroscopy (Hamshire: Macmillan) p. 565

    Google Scholar 

  38. Nakamoto K 1986 Infrared and Raman spectra of inorganic and coordination compounds (New York: Wiley) p. 241

    Google Scholar 

  39. Biradar N S and Havinale B R 1976 Inorg. Chim. Acta 17 157

    Article  CAS  Google Scholar 

  40. Pickett C, Kumar S, Vella P A and Zubieta J 1982 Inorg. Chem. 21 908

    Article  CAS  Google Scholar 

  41. Cendric M, Vrdoljak V, Strukan N, Tepes P, Novak P, BrbotSaranovic A, Giester G and Kemenar B 2002 Eur. J. Inorg. Chem. 2128

  42. Purohit S and Ghosh S P 1988 J. Chem. Res. (s) 158

  43. Hahn R, Kusthardt U and Scherer W 1993 Inorg. Chim. Acta 210 177

    Article  CAS  Google Scholar 

  44. Bernard K B, Bruck M, Huber S, Grittini C, Enemark J H, Gable R W and Wedd A G 1997 Inorg. Chem. 36 637

    Article  Google Scholar 

  45. Craig J A, Harlan E W, Snyder B S, Whitener M A and Holm R H 1989 Inorg. Chem. 28 2082

    Article  CAS  Google Scholar 

  46. Berg J M and Holm R H 1984 J. Am. Chem. Soc. 106 3035

    Article  CAS  Google Scholar 

  47. Pramanik N R, Ghosh S P, Roychowdhury T K, Ray S, Butcher R J and Mandal S S 2004 Polyhedron 23 1595

    Article  CAS  Google Scholar 

  48. Bernard K B, Bruck M, Huber S, Grittini C, Enemark J H, Gable R W and Wedd A G 1997 Inorg Chem. 36 637

    Article  Google Scholar 

  49. CindriĆ M, Matković-Čalogović D, Vrdoljak V and Kamenar B 1998 Inorg. Chem. Commun. 1 237

    Article  Google Scholar 

  50. Yang W, Lu C, Lin X, Wu C, Wu D and Zhuang H 2001 Inorg.Chem.Commun. 4 285

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, University College of Science, 92 A.P.C. Road, Kolkata, 700 009, India

    Samik Gupta, Somnath Roy, Tarak Nath Mandal, Sangita Ray & Susanta Kumar Kar

  2. Department of Chemistry, Haldia Government College, Debhog, Purba, Midnapur, 721 657, India

    Kinsuk Das

  3. Department of Chemistry, Howard University, 2400 Sixth Street, N.W., Washington, DC, 20059, USA

    Ray J. Butcher

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  1. Samik Gupta
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  2. Somnath Roy
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  3. Tarak Nath Mandal
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  4. Kinsuk Das
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  5. Sangita Ray
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  6. Ray J. Butcher
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  7. Susanta Kumar Kar
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Correspondence to Susanta Kumar Kar.

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Gupta, S., Roy, S., Mandal, T.N. et al. Synthesis, characterization and spectrochemical studies on a few binuclear µ-oxo molybdenum(V) complexes of pyrimidine derived Schiff base ligands. J Chem Sci 122, 239–245 (2010). https://doi.org/10.1007/s12039-010-0028-5

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  • DOI: https://doi.org/10.1007/s12039-010-0028-5

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