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Synthetic studies on taxanes: A domino-enyne metathesis/Diels-Alder approach to the AB-ring

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Abstract

A domino enyne cross-metathesis/intramolecular Diels-Alder reaction has been successfully used to synthesize a bicyclo[5.3.1] undecene, corresponding to AB-ring of taxol without the gem dimethyl group.

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Authors and Affiliations

  1. Department of Chemistry, Indian Institute of Technology Bombay, Mumbai, 400 076, India

    Krishna P. Kaliappan, Velayutham Ravikumar & Sandip A. Pujari

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  1. Krishna P. Kaliappan
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  2. Velayutham Ravikumar
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  3. Sandip A. Pujari
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Correspondence to Krishna P. Kaliappan.

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Kaliappan, K.P., Ravikumar, V. & Pujari, S.A. Synthetic studies on taxanes: A domino-enyne metathesis/Diels-Alder approach to the AB-ring. J Chem Sci 120, 205–216 (2008). https://doi.org/10.1007/s12039-008-0024-1

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