Abstract
Heat-resistant composites are widely used as high-temperature engineering materials. Polymer materials are often used as the matrix of the composites due to their good processability and adhesion to different substrates. In order to improve the thermal stability of silicone rubber (SR) matrix, CE/SR composites were prepared from cyanate ester (CE) prepolymer and silicone. The chemical structure, morphology and thermal stability of the obtained CE/SR composites were analyzed by Fourier transform infrared spectroscopy, scanning electron microscopy and thermogravimetric analysis (TGA). SEM images of the cross sections of CE/SR show that a two-phase microstructure consisting of continuous SR and dispersed CE can be formed by successively curing of silicone and CE prepolymer. TGA analysis results show that CE modified SR has higher heat resistance than SR, and the thermal stability of CE/SR composites is better than that of pure SR and pure CE in the temperature range of 300–500 °C. The composite of KL and CE/SR was prepared to further improve the heat resistance.
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References
Peng, JG, Luo, SZ, Yuan, M, “Research on oxidation behavior of 304 austenitic stainless steel at high temperature.” Baosteel Technology, 25 29–32 (in Chinese) (2007)
Teng, KP, Shao, HH, “Preparation and properties of Ni-nano Al2O3 composite plating on 304 stainless steel.” Corrosion Science and Protection Technology, 24 46–50 (in Chinese) (2012)
Du, Y, Wang, C, Zhu, SL, Wang, FH, “High temperature oxidation and electrochemical corrosion behavior of Al nano-particle modified silicone coating on 304 stainless steel.” Chinese Journal of Materials Research, 12 942–948 (in Chinese) (2019)
Min, CY, Huang, YD, Liu, L, “Effect of nanosized ferric oxide on the thermostability of methylsilicone resin.” Journal of Materials Science, 42 8695–8699 (2007)
Sim, LC, Ramanan, SR, Ismail, H, et al. “Thermal characterization of Al2O3 and ZnO reinforced silicone rubber as thermal pads for heat dissipation purposes.” Thermochimica Acta, 430 155–165 (2005)
Wang, C, Jiang, F, Wang, F, “Corrosion inhibition of 304 stainless steel by nano-sized Ti/silicone coatings in an environment containing NaCl and water vapor at 400–600°C.” Oxidation of Metals, 62 1–13 (2004)
Li, ZX, Bai, L, Zheng, JP, “Effect of π–π interaction between carbon nanotubes and phenyl groups on the thermal stability of silicone rubber.” Journal of Thermal Analysis and Calorimetry, 131 2503–2512 (2018)
Yan, FY, Zhang, XB, Liu, F, Li, XH, Zhang, ZJ, “Adjusting the properties of silicone rubber filled with nanosilica by changing the surface organic groups of nanosilica.” Composites Part B-Engineering, 75 47–52 (2015)
Huang, YH, Mu, QH, Su, ZT, “High and low temperature resistance of phenyl silicone rubber.” IOP Conference Series: Materials Science and Engineering. 1048 012001 (2021)
Yu, L, Zhou, ST, Zou, HW, Liang, M, “Thermal stability and ablation properties study of aluminum silicate ceramic fiber and acicular wollastonite filled silicone rubber composite.” Journal of Applied Polymer Science, 131 (1). https://doi.org/10.1002/app.39700 (2014)
Zhang, YX, Zhou, YX, Wu, C, Zhang, L, Teng, CY, Nie, Z, “Charge transport dynamics and the effects on electrical tree degradation under DC voltages in thermally aged silicone rubber.” Journal of Physics D: Applied Physics, 53 415501 (2020)
Celina, MC, “Review of polymer oxidation and its relationship with materials performance and lifetime prediction.” Polymer Degradation and Stability, 98 2419–2429 (2013)
Jia, M, Wu, C, Li, W, et al. “Synthesis and characterization of a silicone resin with silphenylene units in Si-O-Si backbones.” Journal of Applied Polymer Science, 114 971–977 (2009)
Sun, JT, Huang, YD, Cao, HL, et al. “Synthesis of heat-resistant silicone resin and studies on its thermal and curing properties.” Journal of Aeronautical Materials, 25 (1) 25–35 (2005)
Kuo, CFJ, Chen, JB, “Study on the synthesis and application of silicone resin containing phenyl group.” Journal of Sol-Gel Science and Technology, 76 66–73 (2015)
Xu, X, Liu, J, Chen, P, Wei, D, Yong, G, Lu, X, Xiao, H, “The effect of ceria nanoparticles on improving heat resistant properties of fluorosilicone rubber.” Journal of Applied Polymer Science, 133 44117 (2016)
Haber, RT, Browning, AR, Graves, BR, Davis, WP, Wiggins, JS, “A molecular dynamics study of monomer melt properties of cyanate ester monomer melt properties.” Polymers, 14 1219 (2022)
Guan, QB, Yuan, L, Zhang, Y, Gu, AJ, Liang, GZ, “Improving the mechanical, thermal, dielectric and flame retardancy properties of cyanate ester with the encapsulated epoxy resin-penetrated aligned carbon nanotube bundle.” Composites Part B: Engineering, 123 81–91 (2017)
Kareem, AA, “Thermal and electrical properties of polyimide/PANI nanofiber composites prepared via in situ polymerization.” Materials Science-Poland, 36 (2) 283–287 (2018)
Rasheed, HK, Kareem, AA, “The potential barrier and thermal stability dependence on PI thickness of Al/PI/c-Si Schottky diode.” Iraqi Journal of Science, 61 (12) 3235–3241 (2020)
Kareem, AA, Rasheed, HK, Nasir, EM, “Influence methods of preparation on the thermal stability of polyimide/silica dust.” Polymer Bulletin, 79 6617–6626 (2021)
Farid, M, Purniawan, A, Susanti, D, Rasyida, A, Ramadani, M, “Effect of nanocellulose on acoustical and thermal insulation properties of silicone rubber composite.” Materials Science Forum, 964 156–160 (2019)
Zhu, L, Chen, X, Shi, R, Zhang, H, Han, R, Cheng, X, Zhou, C, “Tetraphenylphenyl-modified damping additives for silicone rubber: experimental and molecular simulation investigation.” Materials Design, 202 109551 (2021)
Zha, JW, Dang, ZM, Li, WK, Zhu, YH, Chen, G, “Effect of micro-Si3N4-nano-Al2O3, sub>3 co-filled particles on thermal conductivity, dielectric and mechanical properties of silicone rubber composites.” IEEE Transactions on Dielectrics & Electrical Insulation, 21 1989–1996 (2014)
Xu, Y, Gao, Q, Liang, H, Zheng, K, “Effects of functional graphene oxide on the properties of phenyl silicone rubber composites.” Polymer Testing, 54 168–175 (2016)
Yao, Y, Lu, GQ, Boroyevich, D, Ngo, KDT, “Effect of Al2O3 fibers on the hightemperature stability of silicone elastomer.” Polymer, 55 4232–4240 (2014)
Tanaka, T, Kozako, M, Fuse, N, Ohki, Y, “Proposal of a multi-core model for polymer nanocomposite dielectrics.” IEEE Transactions on Dielectrics & Electrical Insulation, 12 669–681 (2005)
Nazir, MT, Phung, BT, Hoffman, M, Yu, S, Li, S, “Micro-AlN/nano-SiO2 co-filled silicone rubber composites with high thermal stability and excellent dielectric properties.” Materials Letters, 209 421–424 (2017)
Halim, ZAA, Ahmad, N, Yajid, MAM, Hamdan, H, “Thermal insulation performance of silicone rubber/silica aerogel composite.” Materials Chemistry and Physics, 276 125365 (2022)
Ge, L, Liu, Q, “Preparation and characterization of diene rubbers/silica composites via reactions of hydroxyl groups and blocked polyisocyanates.” Polymers, 14 461 (2022)
Liu, YF, Shi, YH, Zhang, D, Li, JL, Huang, GS, “Preparation and thermal degradation behavior of room temperature vulcanized silicone rubber-g-polyhedral oligomeric silsesquioxanes.” Polymers, 54 6140 (2013)
Jankovi, BZ, Jankovic, MM, Marinovic-Cincovic, MM, Todorovic, DJ, Sarap, NB, “Thermal analysis testing and natural radioactivity characterization of kaolin as building material.” Journal of Thermal Analysis and Calorimetry, 133 481–487 (2018)
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Funding was provided by Beijing Municipal Education Commission, (Grant No. KZ202210005004).
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Wen, Q., Yang, Xj., He, Dy. et al. Thermal stability of cyanate ester modified silicone rubber as matrix of heat-resistant composite coatings. J Coat Technol Res 20, 2113–2123 (2023). https://doi.org/10.1007/s11998-023-00808-0
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DOI: https://doi.org/10.1007/s11998-023-00808-0