Abstract
We present recent developments in the field of austenitic steels with up to 18% reduced mass density. The alloys are based on the Fe-Mn-Al-C system. Here, two steel types are addressed. The first one is a class of low-density twinning-induced plasticity or single phase austenitic TWIP (SIMPLEX) steels with 25–30 wt.% Mn and <4–5 wt.% Al or even <8 wt.% Al when naturally aged. The second one is a class of κ-carbide strengthened austenitic steels with even higher Al content. Here, κ-carbides form either at 500–600°C or even during quenching for >10 wt.% Al. Three topics are addressed in more detail, namely, the combinatorial bulk high-throughput design of a wide range of corresponding alloy variants, the development of microstructure–property relations for such steels, and their susceptibility to hydrogen embrittlement.
Similar content being viewed by others
References
J.G. Speer, D.K. Matlock, B.C. De Cooman, and J.G. Schroth, Acta Mater. 51, 2611 (2003).
D. Barbier, N. Gey, S. Allain, N. Bozzolo, and M. Humbert, Mater. Sci. Eng. A 500, 196 (2009).
F.G. Caballero and H.K.D.H. Bhadeshia, Curr. Opin. Solid State Mater. Sci. 8, 251 (2004).
M. Calcagnotto, Y. Adachi, D. Ponge, and D. Raabe, Acta Mater. 59, 658 (2011).
R. Song, D. Ponge, D. Raabe, J.G. Speer, and D.K. Matlock, Mater. Sci. Eng. A 441, 1 (2006).
B.C. De Cooman, O. Kwon, and K.G. Chin, J. Mater. Sci. Technol. 28, 513 (2012).
M. Calcagnotto, D. Ponge, and D. Raabe, ISIJ Int. 48, 1096 (2008).
R. Song, D. Ponge, and D. Raabe, Acta Mater. 53, 4881 (2005).
Y. Sakuma, O. Matsumura, and O. Akisue, ISIJ Int. 31, 1348 (1991).
B.C. De Cooman and J.G. Speer, Steel Res. Int. 77, 634 (2006).
Y. Toji, H. Matsuda, M. Herbig, P.-P. Choi, and D. Raabe, Acta Mater. 65, 215 (2014).
F.G. Caballero, H.K.D.H. Bhadeshia, J.A. Mawella, D.G. Jones, and P. Brown, Mater. Sci. Technol. 17, 517 (2001).
D. Raabe, S. Sandlöbes, J. Millán, D. Ponge, H. Assadi, M. Herbig, and P.P. Choi, Acta Mater. 61, 6132 (2013).
D. Raabe, D. Ponge, O. Dmitrieva, and B. Sander, Scripta Mater. 60, 1141 (2009).
L. Yuan, D. Ponge, J. Wittig, P.P. Choi, J.A. Jiminez, and D. Raabe, Acta Mater. 60, 2790 (2012).
O. Grässel, L. Krüger, G. Frommeyer, and L.W. Meyer, Int. J. Plast. 16, 1391 (2000).
G. Frommeyer, U. Brüx, and P. Neumann, ISIJ Int. 43, 438 (2003).
G. Frommeyer and U. Brüx, Steel Res. Int. 77, 627 (2006).
O. Bouaziz, S. Allain, C.P. Scott, P. Cugy, and D. Barbier, Curr. Opin. Solid State Mater. Sci. 15, 141 (2011).
A. Saeed-Akbari, L. Mosecker, A. Schwedt, and W. Bleck, Metall. Mater. Trans. A 43, 1688 (2012).
J.E. Jin and Y.K. Lee, Mater. Sci. Eng. A 527, 157 (2009).
J.K. Kim, L. Chen, H.S. Kim, S.K. Kim, Y. Estrin, and B.C. Cooman, Metall. Mater. Trans. A 40, 3147 (2009).
S. Curtze and V.T. Kuokkala, Acta Mater. 58, 5129 (2010).
I. Gutierrez-Urrutia, S. Zaefferer, and D. Raabe, Mater. Sci. Eng. A 527, 3552 (2010).
H. Idrissi, K. Renard, D. Schryvers, and P.J. Jacques, Scripta Mater. 63, 961 (2010).
O. Bouaziz, S. Allain, and C. Scott, Scripta Mater. 58, 484 (2008).
H. Beladi, I.B. Timokhina, Y. Estrin, J. Kim, B.C. Cooman, and S.K. Kim, Acta Mater. 59, 7787 (2011).
H.K. Yang, Z.J. Zhang, and Z.F. Zhang, Scripta Mater. 68, 992 (2013).
D. Barbier, N. Gey, S. Allain, N. Bozzolo, and M. Humbert, Mater. Sci. Eng. A 500, 196 (2009).
I. Gutierrez-Urrutia, S. Zaefferer, and D. Raabe, JOM 65, 1229 (2013).
I. Gutierrez-Urrutia, S. Zaefferer, and D. Raabe, Scripta Mater. 61, 737 (2009).
I. Gutierrez-Urrutia and D. Raabe, Scripta Mater. 66, 992 (2012).
I. Gutierrez-Urrutia and D. Raabe, Acta Mater. 59, 6449 (2011).
I. Gutierrez-Urrutia and D. Raabe, Scripta Mater. 66, 343 (2012).
S. Reeh, D. Music, T. Gebhardt, M. Kasprzak, T. Jäpel, S. Zaefferer, D. Raabe, S. Richter, A. Schwedt, J. Mayer, B. Wietbrock, G. Hirt, and J.M. Schneider, Acta Mater. 60, 6025 (2012).
H. Kim, D.-W. Suh, and N.J. Kim, Sci. Technol. Adv. Mater. 14, 014205 (2013).
G. Frommeyer and U. Brüx, Steel Res. Int. 77, 627 (2006).
J.D. Yoo and K.-T. Park, Mater. Sci. Eng. A 496, 417 (2008).
K.M. Chang, C.G. Chao, and T.F. Liu, Scripta Mater. 63, 162 (2010).
K. Choi, C.-H. Seo, H. Lee, S.K. Kim, J.H. Kwak, K.G. Chin, K.-T. Park, and J. Kim, Scripta Mater. 63, 1028 (2010).
I. Gutierrez-Urrutia and D. Raabe, Acta Mater. 60, 5791 (2012).
S.Y. Han, S.Y. Shin, H.-J. Lee, B.-J. Lee, S. Lee, N.J. Kim, and J.-H. Kwak, Metall. Mater. Trans. A 43A, 843 (2012).
I. Gutierrez-Urrutia and D. Raabe, Scripta Mater. 68, 343 (2013).
Y. Kimura, K. Handa, H. Hayashi, and Y. Mishima, Intermetallics 12, 607 (2004).
J.-B. Seol, D. Raabe, P. Choi, H.-S. Park, J.-H. Kwak, and C.-G. Park, Scripta Mater. 68, 348 (2013).
C.Y. Chao, C.N. Hwang, and T.F. Liu, Scripta Metall. Mater. 28, 109 (1993).
C.N. Hwang, C.Y. Chao, and T.F. Liu, Scripta Metall. Mater. 28, 263 (1993).
I. Gutierrez-Urrutia and D. Raabe, Mater. Sci. Technol. 30, 1099 (2014).
H. Springer and D. Raabe, Acta Mater. 60, 4950 (2012).
D.R. Steinmetz, T. Japel, B. Wietbrock, P. Eisenlohr, I. Gutierrez-Urrutia, A. Saeed-Akbari, T. Hickel, F. Roters, and D. Raabe, Acta Mater. 61, 494 (2013).
F. Roters, D. Raabe, and G. Gottstein, Acta Mater. 48, 4181 (2000).
H. Mecking and U.F. Kocks, Acta Metall. 29, 1865 (1981).
U.F. Kocks, A.S. Argon, and M.F. Ashby, Prog. Mater Sci. 19, 1 (1975).
R.L. Fullman, Trans. AIME. 197, 447 (1953).
S. Mahajan and G.Y. Chin, Acta Metall. 21, 1353 (1973).
A. Saeed-Akbari, J. Imlau, U. Prahl, and W. Bleck, Metall. Mater. Trans. A 40A, 3076 (2009).
M. Koyama, E. Akiyama, T. Sawaguchi, D. Raabe, and K. Tsuzaki, Scripta Mater. 66, 459 (2012).
M. Koyama, E. Akiyama, K. Tsuzaki, and D. Raabe, Acta Mater. 61, 4607 (2013).
M. Koyama, H. Springer, S.V. Merzlikin, K. Tsuzaki, E. Akiyama, and D. Raabe, Int. J. Hydrog. Energy 39, 4634 (2014).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Raabe, D., Springer, H., Gutierrez-Urrutia, I. et al. Alloy Design, Combinatorial Synthesis, and Microstructure–Property Relations for Low-Density Fe-Mn-Al-C Austenitic Steels. JOM 66, 1845–1856 (2014). https://doi.org/10.1007/s11837-014-1032-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11837-014-1032-x