Abstract
The photocatalytic decomposition characteristics of individual and binary vapors of benzene, toluene, and ethylbenzene by a UV reactor were studied. The reactor was custom-designed to have a synergistic effect of photochemical oxidation by ozone generated by UV254+185 nm lamps and photocatalytic oxidation by TiO2 photocatalyst whose surface area was almost doubled by helically inserted TiO2-coated perforated planes. The removal efficiencies of individual vapors of benzene, toluene, and ethylbenzene generally increased in proportion to the relative humidity and oxygen supply. The photocatalytic decomposition kinetics of individual vapors, as well as binary vapors consisting of benzene-toluene, benzene-ethylbenzene, and toluene-ethylbenzene, followed the Langmuir-Hinshelwood (L-H) equation quite well. Maximum elimination capacities of individual vapors were 560 g/m3∙day, 630 g/m3∙day, and 1,024 g/m3∙day for benzene, toluene, and ethylbenzene, respectively. In view of mutual impact for the photocatalytic decomposition of binary vapors, the reaction rate of the target component was more influenced by the presence of the counter component with lower bond dissociation energy.
Similar content being viewed by others
References
F. Gironi and V. Piemonte, Chem. Eng. J., 172, 671 (2011).
WHO, World Health Organization Guidelines for Drinking Water Quality, World Health Organization, Geneva, Switzerland (2004).
A. Hamad and M. E. Fayed, Chem. Eng. Res. Des., 82, 895 (2004).
S.W. Lee, J.K. Cheon, H. J. Park and M.G. Lee, Korean J. Chem. Eng., 25, 1154 (2008).
J. K. Kim, S. K. Kam and M. G. Lee, Int. J. Environ. Pollut., 39, 264 (2009).
J. S. Cho, M.W. Ryoo, K. S. Song, J. H. Lee and S. K. Kang, Korean J. Chem. Eng., 16, 478 (1999).
Y. S. Won, J.-W. Jeon, D.-H. Lee and M. G. Lee, J. Chem. Eng. Jpn., 50, 289 (2017).
K. Urashima and J. S. Chang, IEEE Transactions on Dielectrics and Electrical Insulation, 7, 602 (2000).
C.Y. Cha and C.T. Carlisle, J. Air Waste Manage. Assoc., 51, 1628 (2011).
S.W. Verbruggen, S. Ribbens, T. Tytgat, B. Hauchecorne, M. Smits, V. Meynen, P. Cool, J. A. Martens and S. Lenaerts, Chem. Eng. J., 174, 318 (2011).
J.Y. Jeong, K. Sekiguchi, W.K. Lee and K. Sakamoto, J. Photochem. Photobiol. A: Chem., 169, 279 (2005).
A.V. Vorontsov, Catal. Commun., 8, 2100 (2007).
A. Strini, S. Cassese and L. Schiavi, Appl. Catal. B: Environ., 61, 90 (2005).
N. Quici, M. L. Vera, H. Choi, G. L. Puma, D.D. Dionysiou, M. I. Litter and H. Destaillats, Appl. Catal. B: Environ., 95, 312 (2010).
C.A. Korologos, C. J. Philippopoulos and S.G. Poulopoulos, Atmos. Environ., 45, 7089 (2011).
Y. Ku, J. S. Chen and H.W. Chen, J. Air Waste Manage. Assoc., 57, 279 (2007).
D.D. Dionysiou, M.T. Suidan, I. Baudin and J. M. Laine, Appl. Catal. B: Environ., 50, 259 (2004).
Y. S. Shen and Y. Ku, Chemosphere, 46, 101 (2002).
Z. Pengyi, L. Fuyan, Y. Gang, C. Qing and Z. Wanpeng, J. Photochem. Photobiol. A: Chem., 156, 189 (2003).
S.-J. Yoa, Y.-S. Cho and J.-H. Kim, Korean J. Chem. Eng., 22, 364 (2005).
C. Feiyan, S.O. Pehkonen and M.B. Ray, Water Res., 36, 4203 (2002).
H. B. Huang and D.Y.C. Leung, J. Environ. Eng., 137, 996 (2011).
A. Bouzaza, C. Vallet and A. Laplanche, J. Photochem. Photobiol. A: Chem., 177, 212 (2006).
J. Peral and D. F. Ollis, J. Catal., 136, 544 (1992).
O. d’Hennezel, P. Pichat and D. F. Ollis, J. Photochem. Photobiol. A: Chem., 118, 197 (1998).
K.C. Jung and S. C. Hong, J. Korean Ind. Eng. Chem., 14, 671 (2003).
S.B. Kim, H.T. Hwang and S. C. Hong, Chemosphere, 48, 437 (2002).
D.Y. Shin and K. N. Kim, J. Korean Ceramic Soc., 45, 43 (2008).
J. Shang, W. Li and Y. Zhu, J. Mol. Catal. A: Chem., 202, 187 (2003).
G. S. Jolly, G. Paraskevopoulos and D. L. Singleton, Int. J. Chem. Kinet., 17, 1 (1985).
Y.R. Luo, Handbook of bond dissociation energies in organic compounds, CRC Press, 392 (2003).
A.K. Boulamanti, C.A. korologos and C. J. Philippopoulos, Atmos. Environ., 42, 7844 (2008).
W. Wang, L.W. Chiang and Y. Ku, J. Hazard. Mater., 101, 133 (2003).
Y. P. Zhang, R. Yang, Q. J. Xu and J. H. Mo, J. Air Waste Manage. Assoc., 57, 94 (2007).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Jeon, JW., Lee, DH., Won, Y.S. et al. Characteristics of photocatalytic decomposition of individual and binary mixture vapors of some VOCs by a cylindrical UV reactor with helically installed TiO2-coated perforated planes. Korean J. Chem. Eng. 35, 744–749 (2018). https://doi.org/10.1007/s11814-017-0320-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-017-0320-x