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Facile fabrication and characterization of an economical active packaging film based on corn starch–chitosan biocomposites incorporated with clove oil

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Abstract

Corn starch (CS)–chitosan (CH) films containing 9% w/w of clove oil (CO) were fabricated, and the structure, physicochemical, barrier, antioxidant activity, and biodegradability performance of the films were characterized. According to the results of atomic force microscopy characterization, the fabricated CH–CS films have a uniform shape and a smooth surface. Fourier transform infrared spectra show similar pattern absorption peaks, with the amplitude at some absorption peaks changing because of hydrogen bond formation of CH/CS-COs. The semicrystalline microstructure of the films was confirmed by X-ray diffraction (XRD) rheological studies. The XRD patterns for all combinations of the CH/CS matrix composition are identical. All CH/CS biocomposite films exhibit a very significant increase in tensile strength (TS) values, i.e., from 2.312 to 2.641 MPa, compared with the native CS (1.203 MPa) and CH (0.226 MPa) film, as well as their thermal stability. As the CH content in the matrix increases, the water vapor permeability (WVP) value of the films gradually decreases. The WVP value of pure CS is 10.13 × 10− 9 g.Pa− 1s− 1 m− 1, whereas the CH70CS30 sample has a WVP value of 2.17 × 10− 9 g.Pa− 1s− 1 m− 1. The fabricated film can be used for active packaging and can replace packaging films manufactured from native CH and CS, as well as reduce the use of packaging films derived from petrochemical raw materials.

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Data Availability

The data that confirm the results of this article are available upon reasonable request from the corresponding author, [M. Hasan].

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Acknowledgements

The authors gratefully acknowledge financial support from the PHI Research Fund Universitas Syiah Kuala and the Indonesian Ministry of Research, Technology, and Higher Education. (Grant No. 71/UN11.2.1/PT.01.03/PNBP/2020).

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All authors certify that they have no affiliations with or involvement in any organization or entity with any financial interest or non-financial interest in the subject matter or materials discussed in this manuscript.

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Authors and Affiliations

  1. Department of Chemical Education, Universitas Syiah Kuala, Darussalam Banda Aceh, 23311, Banda Aceh, Indonesia

    M. Hasan, Ibnu Khaldun, Ismi Zatya, Rusman Rusman & M. Nasir

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  1. M. Hasan
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Contributions

Conseptualization [M. Hasan, Ismi Zatya]; Methodology [M. Hasan, Ismi Zatya, I. Khaldun, Rusman, M. Nasir]; Formal Anaysis and Investigation [M. Hasan, Ismi Zatya, I. Khaldun, M. Nasir]; Writing original draft preparation [M. Hasan, Ismi Zatya], Writing-Review and Editing [M. Hasan, I. Khaldun, Ismi Zatya], Funding Acquisition [M. Hasan, R. Rusman]; Resources [Ismi Zatya, M. Hasan]; Supervision [M. Hasan, M. Nasir].

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Correspondence to M. Hasan.

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Hasan, M., Khaldun, I., Zatya, I. et al. Facile fabrication and characterization of an economical active packaging film based on corn starch–chitosan biocomposites incorporated with clove oil. Food Measure 17, 306–316 (2023). https://doi.org/10.1007/s11694-022-01616-7

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  • DOI: https://doi.org/10.1007/s11694-022-01616-7

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