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Voltammetric determination of trace level of cadmium in mussels and seawaters by a lacunar apatite-modified carbon electrode

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Abstract

An electrochemical sensor was fabricated by potassium lacunar apatite (KCaAP). This sensor, coupled with differential pulse anodic stripping voltammetry, could provide a means for a relatively inexpensive detector for trace levels of cadmium. The analytical performance was evaluated with respect to the quantity of modifier in the paste, preconcentration time and the stripping voltammetric parameters. A linear calibration graph was obtained in the concentration range 7.0 × 10–7–1.0 × 10–4 mol L−1 Cd (II) with a detection limit of 4.86 × 10−8 mol L−1. For eight repetitions, the differential pulse voltammetric response was repeated with 7.15% and 4.69% expressed as relative standard deviations in 9.0 × 10−6 and 9.0 × 10−5 mol L−1 of cadmium (II), respectively. The lacunar apatite modified carbon paste electrode (KCaAP-CPE) was applied to the detection of cadmium content in mussels and seawater samples with satisfactory results.

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Authors and Affiliations

  1. Laboratoire de Chimie, Modélisation Et Sciences de L’Environnement, Faculté Polydisciplinaire, Université Sultan Moulay Slimane, 25000, Khouribga, Morocco

    Sara Lahrich, Sana Saqrane & Moulay Abderrahim El Mhammedi

  2. Laboratoire de Sciences Des Matériaux, Des Milieux Et de La Modélisation, Faculté Polydisciplinaire, Université Sultan Moulay Slimane, 25000, Khouribga, Morocco

    Bouchaib Manoun

Authors
  1. Sara Lahrich
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  2. Sana Saqrane
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  3. Bouchaib Manoun
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  4. Moulay Abderrahim El Mhammedi
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Correspondence to Moulay Abderrahim El Mhammedi.

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Lahrich, S., Saqrane, S., Manoun, B. et al. Voltammetric determination of trace level of cadmium in mussels and seawaters by a lacunar apatite-modified carbon electrode. Food Measure 13, 2318–2327 (2019). https://doi.org/10.1007/s11694-019-00151-2

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  • DOI: https://doi.org/10.1007/s11694-019-00151-2

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