Abstract
The phase equilibria of the Co-Cu-Mo ternary system at 900 and 1100 °C have been studied by using x-ray diffraction (XRD) and scanning electron microscopy (SEM) coupled with energy-dispersive spectroscopy (EDS). Three and five three-phase regions have been confirmed in the system at 900 and 1100 °C, respectively. No ternary compound has been found in these two isothermal sections. At 900 °C, the maximum solubilities of Co and Cu in the μ phase are 56.5 and 4.4 at.%, respectively. As the temperature rises to 1100 °C, their solubilities decrease slightly. Moreover, with the temperature increases from 900 to 1100° C, in the αCo phase, the solubility of Mo increases from 6.5 to 11.9 at.% and the solubility of Cu increases from 8.3 to 12.1 at.%.
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S.V. Aydinyan, H.V. Kirakosyan, and S.L. Kharatyan, Cu-Mo Composite Powders Obtained by Combustion–Coreduction Process, Int. J. Refract. Met. Hard Mater., 2016, 54, p 455-463
A.V. Egorov et al., Properties of Porous Tungsten-Copper and Molybdenum-Copper Pseudoalloys, Sov. Powder Metall. Met. Ceram., 1987, 26(2), p 137-140
A.G. Dirks and J.J. Broek, Metastable Solid Solutions in Vapor Deposited Cu-Cr, Cu-Mo and Cu-W Thin Films, J. Vac. Sci. Technol., 1985, 3(6), p 2618-2623
X. Wang, L. Hu, H. Wang, and E. Wang, Microstructure and Properties of Mo-50% Cu Alloy by Mechanical Milling and Pressure-Assisted Solid State Sintering, Rare Metal Mater. Eng., 2011, 40(5), p 902-905
B. Li, H. Jin, F. Ding, L. Bai, and F. Yuan, Fabrication of Homogeneous Mo-Cu Composites Using Spherical Molybdenum Powders Prepared by Thermal Plasma Spheroidization Process, 2018, Int. J. Refract. Met. Hard Mater., 2018, 73, p 13-21
G.-Q. Chen, G.-H. Wu, D.-Z. Zhu, Q. Zhang, and L.-T. Jiang, Microstructure and Thermal and Electric Conductivities of High Dense Mo/Cu Composites, Trans. Nonferr. Metal Soc., 2005, 15(3), p 110-114
D. Wang, X. Dong, P. Zhou, A. Sun, and B. Duan, The Sintering Behavior of Ultra-Fine Mo-Cu Composite Powders and the Sintering Properties of the Composite Compacts, Int. J. Refract. Met. Hard Mater., 2014, 42, p 240-245
J.T. Yao, C.J. Li, Y. Li, B. Chen, and H.B. Huo, Relationships Between the Properties and Microstructure of Mo-Cu Composites Prepared by Infiltrating Copper into Flamesprayed Porous Mo skeleton, Mater. Des., 2015, 88, p 774-780
J. Cheng, P. Song, Y. Gong, Y. Cai, and Y. Xia, Fabrication and Characterization of W-15Cu Composite Powders by a Novel Mechano-Chemical Process, Mater. Sci. Eng. A, 2008, 488(1-2), p 453-457
F.A. da Costa, A.G.P. da Silva, and U. Umbelino Gomes, The Influence of the Dispersion Technique on the Characteristics of the W-Cu Powders and on the Sintering Behavior, Powder Technol., 2003, 134(1-2), p 123-132
J.L. Johnson, Activated Liquid Phase Sintering of W-Cu and Mo-Cu, Int. J. Refract. Met. Hard Mater., 2015, 53, p 80-86
S.S. Ryu, Y.D. Kim, and I.H. Moon, Dilatometric Analysis on the Sintering Behavior of Nanocrystalline W-Cu Prepared by Mechanical Alloying, J. Alloys Compd., 2002, 335(1-2), p 233-240
X. Zhou, Y. Dong, X. Hua, Rafi-ud-din, and Z. Ye, Effect of Fe on the Sintering and Thermal Properties of Mo-Cu Composites, Mater. Des., 2010, 31(3), p 1603-1606
A. Sun, Z. Wu, X. Dong, B. Duan, and D. Wang, Effects of Ag Addition on Electrical and Thermal Properties of Mo-Cu Composites, J. Alloys Compd., 2016, 657, p 8-11
S. Guo, Q. Kang, C. Cai, and X. Qu, Mechanical Properties and Expansion Coefficient of Mo-Cu Composites with Different Ni Contents, Rare Met., 2012, 31, p 368-371
T.J. Quinn and W. Hume-Rothery, The Equilibrium Diagram of the System Molybdenum-Cobalt, J. Less Common Met., 1963, 5, p 314-324
C.P. Heijwegen and G.D. Rieck, Determination of the Phase Diagram of the Mo-Co System Using Diffusion Couples, J. Less-Common Met., 1974, 34, p 309-314
A. Davydov and U.R. Kattner, Revised Thermodynamic Description for the Co-Mo System, J. Phase Equilib. Diffus., 2003, 24(3), p 209-211
C. Lehmer, Electrical Melting of Sulfidized Ores and Smelting Product Directly into Metals, Metallurgie, 1906, 3, p 596-602
E. Siedschlag, Chromium-Molybdenum and Chro-mium-Molybdenum-Copper Alloys, Z. Anorg. Chem., 1923, 131, p 191-202
L. Dreibholz, Investigations of Binary and Ternary Molybdenum Alloys, Z. Phys. Chem., 1924, 108, p 1-50
M.L. Baskin, A.V. Savin, V.I. Tumanov, and Y.A. Eiduk, Mutual Solubility of Copper and Molybdenum and Properties of Cu-Mo Alloys, Izv. Akad. Nauk SSSR Otdel. Tekh. Nauk Met. Toplivo., 1961, 4, p 111-114
L. Brewer and R.H. Lamoreaux, Molybdenum: Physieo-Chemical Properties of Its Compounds and Alloys, Atom. Energ. Rev., 1980, 119(7), p 236-238
R. Sahmen, Metallographic Announcements from the Institute for Inorganic Chemistry of the University of Gottingen LVIII, Concerning the Alloys of Copper with Cobalt, Iron, Manganese and Magnesium, Z. Anorg. Chem., 1908, 57, p 1-33
U. Hashimoto, The Equilibrium Diagram of the Co-Cu System, J. Jpn. Inst. Met., 1937, 1(1), p 19-26
M. Hasebe and T. Nishizawa, Calculation of Phase Diagrams of the Iron-Copper and Cobalt-Copper Systems, Calphad, 1980, 4(2), p 83-100
P. Taskinen, Activities and Thermodynamic Properties of Molten Co-Cu Alloys, Z. Metallkd., 1982, 73, p 445
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This work is supported by national Natural Science Foundation of china (No. 51771160) and Scientific Research Fund of Hunan Provincial Science and Technology Department (No. 2018JJ4057, 2018).
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Liu, S., Yin, F., Hu, J. et al. Phase Equilibria of the Co-Cu-Mo System at 900 and 1100 °C. J. Phase Equilib. Diffus. 40, 275–284 (2019). https://doi.org/10.1007/s11669-019-00723-1
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DOI: https://doi.org/10.1007/s11669-019-00723-1