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A Study on the Microstructures and Toughness of Fe-B Cast Alloy Containing Rare Earth

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Abstract

This study investigates the effect of cerium on the microstructures, mechanical properties of medium carbon Fe-B cast alloy. The as-cast microstructure of Fe-B cast alloy consists of the eutectic boride, pearlite, and ferrite. Compared with the coarse eutectic borides in the unmodified alloy, the eutectic boride structures in the modified alloy are greatly refined. Cerium promotes the formation of Ce2O3 phase. Ce2O3 can act as effective heterogeneous nuclei of primary austenite, and refine austenite and boride. After heat treatment, the impact toughness of the modified alloy is higher than that of the unmodified alloy because there are more broken borides in the modified alloy. Meanwhile, the fracture mechanism of medium carbon Fe-B alloy is depicted and analyzed by using fractography.

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References

  1. A. Studnicki, J. Kilarski, M. Przybyl, J. Suchońand, and D. Bartocha, Wear Resistance of Chromium Cast Iron-Research and Application, J. Achiev. Mater. Manuf. Eng., 2006, 16, p 63–73

    Google Scholar 

  2. E. Zumelzu, I. Goyos, C. Cabezas, O. Opitz, and A. Parada, Wear and Corrosion Behaviour of High-Chromium (14-30% Cr) Cast Iron Alloys, J. Mater. Process. Technol., 2002, 128, p 250–255

    Article  Google Scholar 

  3. R. Correa, A. Bedolla-Jacuinde, J. Zuno-Silva, E. Cardoso, and I. Mejía, Effect of Boron on the Sliding Wear of Directionally Solidified High-Chromium White Irons, Wear, 2009, 267, p 495–504

    Article  Google Scholar 

  4. H. Fu and J. Xing, Manufacture Technology of Wear Resistant Casting, Machinery Press, Beijing, 2009, p 20–30

    Google Scholar 

  5. O. Ozdemir, M. Usta, C. Bindal, and A.H. Ucisik, Hard iron boride (Fe2B) on 99.97 wt% pure iron, Vacuum, 2006, 80, p 1391–1395

    Article  Google Scholar 

  6. M. Ulutan, Y.M. Mustafa, N.C. Osman, and S. Buytoz, Tribological properties of borided AISI, 4140 steel with the powder packboriding method, Tribol. Lett., 2010, 38, p 231–239

    Article  Google Scholar 

  7. Benxi Iron and Steel Co, Boron Steel, Metallurgical Industry Press, Beijing, 1977, p 2

    Google Scholar 

  8. D.W. Yi, J.D. Xing, and S.Q. Ma, Investigation on Microstructures and Two-Body Abrasive Wear Behavior of Fe-B Cast Alloy, Tribol. Lett., 2011, 45, p 427–435

    Article  Google Scholar 

  9. Z.L. Liu, X. Chen, Y.X. Li, and K.H. Hu, Effect of Chromium on Microstructure and Properties of High Boron White Cast Iron, Metall. Mater. Trans. A, 2008, 39, p 636–641

    Article  Google Scholar 

  10. H.G. Fu and K.H. Hu, High boron Cast Iron Base Anti-wear Alloy and Its Heat Treatment Method, Chinese Patent, CN1624180-A, 2004

  11. H.G. Fu and Z.Q. Jiang, A Study of Abrasion Resistant Cast Fe-B-C Alloy, Acta Metall. Sin., 2006, 42, p 545–548

    Google Scholar 

  12. H.G. Fu, A Study of High Boron Cast Steel Hammer, Foundry, 2006, 55, p 292–295

    Google Scholar 

  13. H.G. Fu, Q. Xiao, J.C. Kuang, Z.Q. Jiang, and J.D. Xing, Effect of Rare Earth and Titanium Additions on the Microstructures and Properties of Low Carbon Fe-B Cast Steel, Mater. Sci. Eng. A, 2007, 466, p 160–165

    Article  Google Scholar 

  14. Chinese National Standard, GB/T 6394-2002, Metal-Methods for Estimating the Average Grain Size, Bureau of Quality Supervision, Inspection and Quarantine, Manual of Chinese National Standard, Beijing, 2002

  15. American Society for Testing and Materials, ASTM E384-08, Standard Test Method for Microindentation Hardness of Materials, American Society for Testing and Materials, West Conshohocken, PA, 2008

    Google Scholar 

  16. D.W. Yi, J.D. Xing, H.G. Fu, S.Q. Ma, and Z.X. Liu, Effects of RE-Al Additions and Austenitising Time on Structural Variations of Medium Carbon Fe-B Cast Alloy, Mater. Sci. Technol., 2010, 26, p 849–857

    Article  Google Scholar 

  17. Z.S. Yu, The Application of Rare Earth in Steel, Metallurgical Industry Press, Beijing, 1987, p 231–237

    Google Scholar 

  18. R. Chotěborský, B. Bryksí-Stunová, and M. Kolaříková, Effect of Rare Earth Element on Microstructure of Fe-B Cast Alloy, 22nd International Conference on Metallurgy and Materials (Metal 2013), May 15th-17th 2013, Brno, Czech Republic

  19. D.W. Yi, J.D. Xing, and S.Q. Ma, Three-Body Abrasive Wear Behavior of Low Carbon Fe-B Cast Alloy and Its Microstructures Under Different Casting Process, Tribol. Lett., 2011, 42, p 67–77

    Article  Google Scholar 

  20. J.J. Zhang, Y.M. Gao, J.D. Xing, S.Q. Ma, and D.W. Yi, Effects of Plastic Deformation and Heat Treatment on Microstructure and Properties of High Boron Cast Steel, J. Mater. Eng. Perform., 2011, 20, p 1658–1664

    Article  Google Scholar 

  21. D.W. Yi, J.D. Xing, H.G. Fu, S.Q. Ma, and Z.X. Liu, Effects of Rare Earth-Aluminium Additions on the Microstructure of a Semisolid Low Carbon Fe-B Cast Alloy, Mater. Sci. Technol., 2011, 27, p 1518–1526

    Article  Google Scholar 

  22. H. Qiu, H. Mori, M. Enoki, and T. Kishi, Fracture Mechanism and Toughness of the Welding Heat-Affected Zone in Structural Steel Under Static and Dynamic Loading, Metall. Mater. Trans. A, 2000, 31, p 2785–2791

    Article  Google Scholar 

  23. T. Du, Physical-Chemistry Effect of Rare Earth Elements on Metallic Materials, Acta Metall. Sin., 1997, 33, p 69–77

    Google Scholar 

  24. X.H. Zhi, J.D. Xing, H.G. Fu, and Y.M. Gao, Effect of Titanium on the As-Cast Microstructure of Hypereutectic High Chromium Cast Iron, Tribol. Lett., 2008, 59, p 1221–1226

    Google Scholar 

  25. B.L. Bramfitt, The Effect of Carbide and Nitride Additions on the Heterogeneous Nucleation Behavior of Liquid Iron, Metall. Trans., 1970, 1, p 1987–1991

    Article  Google Scholar 

  26. Y.J. Tian, H.Q. Wu, J.H. Guo, and F.R. Li, Effect of RE Inclusions on Heterogeneous Nucleation of Primary Austenite in Fe-C Alloys, J. Chinese Rare Earth Soc., 1988, 6(4), p 45–48

    Google Scholar 

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Acknowledgments

This work was supported by Scientific Research Program Funded by Shaanxi Provincial Education Department (2013JK0919), the Research Foundation of Xi’an University of Science and Technology (2013QDJ026, 2012QDJ034, and 201202), and National Natural Science Foundation of China under Grant (51274016 and 51301128). Moreover, the authors also thank the financial support for this work from the Specialized Research Fund for the Doctoral Program of Higher Education of China under Grant (20110201130008), the National Science Foundation for Post-doctoral Scientists of China under Grants (2012M521767 and 2013T60875), Shaanxi provincial post-doctoral research project, and the Fundamental Research Funds of Xi’an Jiaotong University under Grant (XJJ2013038).

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Correspondence to Dawei Yi.

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Yi, D., Zhang, Z., Fu, H. et al. A Study on the Microstructures and Toughness of Fe-B Cast Alloy Containing Rare Earth. J. of Materi Eng and Perform 24, 626–634 (2015). https://doi.org/10.1007/s11665-014-1331-y

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  • DOI: https://doi.org/10.1007/s11665-014-1331-y

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