Abstract
In the current study, the effects of tungsten (W) addition on the microstructure, hardness, and room/low [223 K and 173 K (−50 °C and −100 °C)] temperature tensile properties of microalloyed forging steels were systematically investigated. Four kinds of steel specimens were produced by varying the W additions (0, 0.1, 0.5, and 1 wt pct). The microstructure showed that the addition of W does not have any noticeable effect on the amount of precipitates. The precipitates in W-containing steels were all rich in W, and the W concentration in the precipitates increased with the increasing W content. The mean sizes of both austenite grains and precipitates decreased with the increasing W content. When the W content was equal to or less than 0.5 pct, the addition of W favored the formation of allotriomorphic ferrite, which subsequently promoted the development of acicular ferrite in the microalloyed forging steels. The results of mechanical tests indicated that W plays an important role in increasing the hardness and tensile strength. When the testing temperature was decreased, the tensile strength showed an increasing trend. Both the yield strength and the ultimate tensile strength obeyed an Arrhenius type of relation with respect to temperature. When the temperature was decreased from 223 K to 173 K (from −50 °C to −100 °C), a ductile-to-brittle transition (DBT) of the specimen with 1 pct W occurred. The addition of W favored a higher DBT temperature. From the microstructural and mechanical test results, it is demonstrated that the addition of 0.5 pct W results in the best combination of excellent room/low-temperature tensile strength and ductility.
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R.M.K. Honeycombe and H.K.D.H. Bhadeshia: Steels, Microstructure and Properties, 2nd ed., Arnold, London, 1995, p. 189.
D. Whittaker: Metall., 1979, vol. 46, pp. 275-81.
M. Jahazi and B. Eghbali: J. Mater. Process. Technol., 2001, vol. 113, pp. 594-98.
G. Krauss: Steels: Processing, Structure, and Performance, ASM International, Ohio, 2005, pp. 230-32.
J. Zhao, J.H. Lee, Y.W. Kim, Z. Jiang, and C.S. Lee: Mater. Sci. Eng. A, 2013, vol. 559, pp. 427-35.
S. Roy, S. Patra, S. Neogy, A. Laik, S.K. Choudhary, and D. Chakrabarti: Metall. Mater. Trans. A, 2012, vol. 43A, pp. 1845-60.
J.G. Jung, J.S. Park, J. Kim, and Y.K. Lee: Mater. Sci. Eng. A, 2011, vol. 528, pp. 5529-35.
S. Vervynckt, P. Thibaux, and K. Verbeken: Met. Mater. Int., 2012, vol. 18, pp. 37-46.
S. Shanmugam, N.K. Ramisetti, R.D.K. Misra, T. Mannering, D. Panda, and S. Jansto: Mater. Sci. Eng. A, 2007, vol. 460-461, pp. 335-43.
Y.M. Kim, S.Y. Shin, H. Lee, B. Hwang, S. Lee, and N.J. Kim: Metall. Mater. Trans. A, 2007, vol. 38A, pp. 1731-42.
G. Huang and K.M. Wu: Met. Mater. Int., 2011, vol. 17, pp. 847-52.
C.P. Reip, S. Shanmugam, and R.D.K. Misra: Mater. Sci. Eng. A, 2006, vol. 424, pp. 307-17.
B.K. Show, R. Veerababu, R. Balamuralikrishnan, and G. Malakondaiah: Mater. Sci. Eng. A, 2010, vol. 527, pp. 1595-604.
S. Sankaran, Gouthama, S. Sangal, and K.A. Padmanabhan: Metall. Mater. Trans. A, 2006, vol. 37A, pp. 3259–73.
D. Rasouli, Sh. Khameneh Asl, A. Akbarzadeh, and G.H. Daneshi: J. Mater. Process. Technol., 2008, vol. 206, pp. 92–98.
C. Capdevila, F.G. Caballero, and C. García de Andrés: Metall. Mater. Trans. A, 2001, vol. 32A, pp. 661–69.
C. Caminaga, W.J. Botta Filho, M.L.N. Silva, and S.T. Button: Procedia Eng., 2011, vol. 10, pp. 512–17.
M.A. Suarez, M.A. Alvarez-Pérez, O. Alvarez-Fregoso, and J.A. Juarez-Islas: Mater. Sci. Eng. A, 2011, vol. 528, pp. 4924-26.
R.L. Klueh, D.J. Alexander, and P.J. Maziasz: Metall. Mater. Trans. A, 1997, vol. 28A, pp. 335-345.
J.I. Suk, C.N. Park, S.H. Hong, and Y.G. Kim: Mater. Sci. Eng. A, 1991, vol. 138, pp. 367–73.
T. Narita, S. Ukai, S. Ohtsuka, M. Inoue: J. Nucl. Mater., 2011, vol. 417, pp. 158-61.
N.H. Heo and H.C. Lee: Scripta Metall. Mater., 1995, vol. 33, pp. 2031-35.
J.S. Park, S.J. Kim, and C.S. Lee: Mater. Sci. Eng. A, 2001, vol. 298, pp. 127-36.
S.G. Hong, W.B. Lee, and C.G. Park: J. Nucl. Mater., 2001, vol. 288, pp. 202-207.
S.B. Kim, K.W. Paik, and Y.G. Kim: Mater. Sci. Eng. A, 1998, vol. 247, pp. 67-74.
W.J. Nam, C.S. Lee, and D.Y. Ban: Scr. Mater., 1997, vol. 36, pp. 1315-20.
J.R. Yang and H.K.D.H. Bhadeshia: Mater. Sci. Technol., 1989, vol. 5, pp. 93-7.
I. Madariaga, I. Gutierrez, and H.K.D.H. Bhadeshia: Metall. Mater. Trans. A, 2001, vol. 32A, pp. 2187-97.
K. Inoue, N. Ishikawa, and K. Ishida: ISIJ Int., 2001, vol. 41, pp. 175-82.
R.M. Poths, R.L. Higginson, and E.J. Palmiere: Scripta Mater., 2011, vol. 44, pp. 147-51.
R.W. Gurry, J. Christakos, and C.D. Stricker: Trans. ASM, 1958, vol. 50, pp. 105-28.
J. Zhao, Z. Jiang, J.S. Kim, and C.S. Lee: Mater. Des., 2013, vol. 49, pp. 252-58.
J. Zhao, Z. Jiang, and C.S. Lee: Mater. Des., 2013, vol. 47, pp. 227-33.
O. Grong and D.K. Matlock: Int. Met. Rev., 1986, vol. 31, pp. 27-48.
D.J. Abson and R.J. Pargeter: Int. Met. Rev., 1986, vol. 31, pp. 141-94.
Y. Ito and M. Nakanishi: Sumitomo Search, 1976, vol. 15, pp. 42-62.
R.A. Ricks, P.R. Howell, and G.S. Barritte: J. Mater. Sci., 1982, vol. 17, pp. 732-40.
J.R. Yang and H.K.D.H. Bhadeshia: in Advances in Welding Science and Technology, S.A. David, ed., ASM, Metals Park, OH, 1987, pp. 187–91.
H.K.D.H. Bhadeshia: Bainite in Steels, 2nd ed., The University Press, Cambridge, London, 2001, p. 239.
H.K.D.H. Bhadeshia and R.W.K. Honeycombe: Steels: Microstructure and Properties, 3rd ed., Elsevier Butterworth-Heinemann, Oxford, 2006, p. 291.
G. Snieder and H.W. Kerr: Can. Metall. Quart., 1984, vol. 23, pp. 315-25.
S.S. Babu and H.K.D.H. Bhadeshia: Mater. Sci. Technol., 1990, vol. 6, pp. 1005-20.
M. Strangwood and H.K.D.H. Bhadeshia: in Advances in Welding Science and Technology, S.A. David, ed., ASM, Metals Park, OH, 1987, pp. 209–13.
G.M. Smith: Ph.D. Thesis, University of Cambridge, 1984.
M.K. Graf, H.G. Hillenbrand, and P.A. Peters: Accelerated Cooling of Steel, P.D. Southwick, ed., TMS-AIME, Warrendale, 1985, pp. 349–66.
W.A. Spitzig and A.S. Keh: Acta Metall., 1970, vol. 18, pp. 1021-33.
M.R. Krishnadev and R. Ghosh: Metall. Trans. A, 1979, vol. 10A, pp. 1941-44.
S. Naamane, G. Monnet, and B. Devincre: Int. J. Plast., 2010, vol. 26, pp. 84-92.
W.A. Spitzig and A.S. Keh: Metall. Trans., 1970, vol. 1, pp. 3325-31.
C. Keller, M.M. Margulies, Z. Hadjem-Hamouche, and I. Guillot: Mater. Sci. Eng. A, 2010, vol. 527, pp. 6758-64.
S. Vaynman, M.E. Fine, S. Lee, and H.D. Espinosa: Scr. Mater., 2006, vol. 55, pp. 351-4.
P. Spätig, G.R. Odette, and G.E. Lucas: J. Nucl. Mater., 1999, vol. 275, pp. 324-31.
B.A. Hands and H.M. Rosenberg: Acta Metall., 1969, vol. 17, pp. 455-61.
Acknowledgments
This study was financially supported by the Ministry of Knowledge and Economy, Korea under the program (2009-D-2-A-Y0-B-07) of the Leading Industry Development for Dongnam Economic Region. The authors would like to thank Dr. Tania Silver from the University of Wollongong for assisting in the English editing.
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Zhao, J., Lee, T., Lee, J.H. et al. Effects of Tungsten Addition on the Microstructure and Mechanical Properties of Microalloyed Forging Steels. Metall Mater Trans A 44, 3511–3523 (2013). https://doi.org/10.1007/s11661-013-1695-x
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DOI: https://doi.org/10.1007/s11661-013-1695-x