Abstract
The precipitation behaviors of the topologically close-packed (TCP) phase in the Ru-free and Ru-containing single-crystal Ni-based superalloys have been investigated. All the TCP phases have been identified as the μ phase with large numbers of planar defects by using a scanning transmission electron microscope (STEM). The addition of 3 wt pct Ru effectively suppresses the nucleation of the μ phase because the addition of 3 wt pct Ru not only decreases the supersaturation of γ phase but also increases the elastic strain energy for the nucleation of the μ phase. Additionally, the addition of 3 wt pct Ru makes more Re enter the μ phase during its growth and the critical nucleus radius of the μ phase becomes larger. Therefore, it is found that the addition of 3 wt pct Ru decreases the growth rate of the μ phase.
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Acknowledgments
This work was financially supported by the National Basic Research Program (973 Program) of China under Grant 2010CB631200 (2010CB631206) and by the National Natural Science Foundation of China (NSFC) under grants 50931004 and U1037601. The authors are grateful for the support.
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Manuscript submitted September 13, 2011.
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Tan, X., Liu, J., Jin, T. et al. Effect of Ruthenium on Precipitation Behavior of the Topologically Close-Packed Phase in a Single-Crystal Ni-Based Superalloy During High-Temperature Exposure. Metall Mater Trans A 43, 3608–3614 (2012). https://doi.org/10.1007/s11661-012-1163-z
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DOI: https://doi.org/10.1007/s11661-012-1163-z