Skip to main content
Log in

Phase equilibria in the Mg-Al-Ca ternary system at 773 and 673 K

  • Published:
Metallurgical and Materials Transactions A Aims and scope Submit manuscript

Abstract

The isothermal sections of the Mg-Al-Ca ternary system at 773 and 673 K were determined by phase analysis with electron-probe microanalysis (EPMA) and transmission electron microscopy (TEM). The C36 phase exists between the C14 (Mg2Ca) and C15 (Al2Ca) phases, and its stoichiometry is close to Mg2Al4Ca3. The α-Mg phase equilibrates with the C14 and C36 phases at 773 K, but with C14, C15, and β phases at 673 K, due to the decomposition of the C36 phase into C14 and C15 phases. These intermetallic phases have significant solid-solubility in the ternary system.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. S. Das: JOM, 2003, vol. 55 (11), pp. 22–26.

    Google Scholar 

  2. B.R. Powell, L.J. Ouiment, J.E. Allison, J.A. Hines, R.S. Beals, L. Kopka, and P.P. Ried: in Magnesium Technology 2004, A.A. Luo, ed., TMS, Warrendale, PA, 2004, pp. 3–10.

    Google Scholar 

  3. M.O. Pekguleryuz and A.A. Kaya: in Magnesium Alloys and Their Applications, K.U. Kainer, ed., Wiley-VCH Verlag GmbH, Weinheim, Germany, 2003, pp. 74–93.

    Google Scholar 

  4. A.A. Luo: Mater. Sci. Forum, 2003, vols. 419–422, pp. 57–66.

    Article  Google Scholar 

  5. B.R. Powell, A.A. Luo, V. Rezhets, J.J. Bommarito, and B.L. Tiwari: SAE Trans. J Mater. Manufacturing, 2001, vol. 110, pp. 406–13.

    Google Scholar 

  6. A.A. Luo, M.P. Balogh, and B.R. Powell: SAE Trans. J Mater. Manufacturing, 2001, vol. 110, pp. 414–22.

    Google Scholar 

  7. A.A. Luo, M.P. Balogh, and B.R. Powell: Metall. Mater. Trans. A, 2002, vol. 33A, pp. 567–74.

    Google Scholar 

  8. M.O. Pekguleryuz and E. Baril: Mater. Trans., 2001, vol. 42, pp. 1258–67.

    Article  CAS  Google Scholar 

  9. E. Baril, P. Labelle, and M.O. Pekguleryuz: JOM, 2003, vol. 55 (11), pp. 34–39.

    CAS  Google Scholar 

  10. P. Bakke and H. Westengen: in Magnesium Technology 2005, N.R. Neelameggham, H.I. Kaplan, and B.R. Powell, eds., TMS, Warrendale, PA, 2005, pp. 291–96.

    Google Scholar 

  11. I.P. Moreno, T.K. Nandy, J.W. Jones, J.E. Allison, and T.M. Pollock: Scripta Mater., 2003, vol. 48, pp. 1029–34.

    Article  CAS  Google Scholar 

  12. B.R. Powell, V. Rezhets, M.P. Balogh, and R.A. Waldo: JOM, 2002, vol. 54 (8), pp. 34–38.

    CAS  Google Scholar 

  13. M.S. Dargusch, G.L. Dunlop, and K. Pattersen: in Magnesium Alloys and Their Applications, B.L. Mordike and K.U. Kainer, eds., Werkstoff-Informationsgesellschaft, Frankfurt, Germany, 1998, pp. 277–82.

    Google Scholar 

  14. Y. Mori, Y. Terada, and T. Sato: Mater. Trans., 2005, vol. 46, pp. 1749–52.

    Article  CAS  Google Scholar 

  15. A. Suzuki, N.D. Saddock, J.W. Jones, and T.M. Pollock: Acta Mater., 2005, vol. 53, pp. 2823–34.

    Article  CAS  Google Scholar 

  16. A. Suzuki, N.D. Saddock, J.W. Jones, and T.M. Pollock: Scripta Mater., 2004, vol. 51, pp. 1005–10.

    Article  CAS  Google Scholar 

  17. A. Suzuki, N.D. Saddock, J.W. Jones, and T.M. Pollock: in Magnesium Technology 2005, N.R. Neelameggham, H.I. Kaplan, and B.R. Powell, eds., TMS, Warrendale, PA, 2005, pp. 111–16.

    Google Scholar 

  18. S. Amerioun, S.I. Simak, and U. Haeussermann: Inorg. Chem., 2003, vol. 42, pp. 1467–74.

    Article  CAS  Google Scholar 

  19. J.A. Catterall and R.J. Pleasance: J. Inst. Met., 1957, vol. 86, pp. 189–92.

    CAS  Google Scholar 

  20. V.G. Tkachenko, V.G. Khoruzhaya, K.A. Meleshevich, M.V. Karpets, and V.V. Frizel: Powder Metall. Met. Ceram., 2003, vol. 42, pp. 268–73.

    Article  Google Scholar 

  21. J. Groebner, D. Kevorkov, I. Chumak, and R. Schmid-Fetzer: Z. Metallkd., 2003, vol. 94, pp. 976–82.

    CAS  Google Scholar 

  22. Y. Zhong, A. Luo, J.F. Nie, J.O. Sofo, and Z.-K. Liu: in Magnesium Technology 2005, N.R. Neelameggham, H.I. Kaplan, and B.R. Powell, eds., TMS, Warrendale, PA, 2005, pp. 185–90.

    Google Scholar 

  23. H. Okamoto: J. Phase Equilibria, 1998, vol. 19, p. 490.

    Article  CAS  Google Scholar 

  24. H. Okamoto: J. Phase Equilibria, 2003, vol. 24, p. 580.

    Article  CAS  Google Scholar 

  25. H. Okamoto: J. Phase Equilibria, 1998, vol. 19, p. 598.

    Article  CAS  Google Scholar 

  26. F. Stein, M. Palm, and G. Sauthoff: Intermetallics, 2004, vol. 12, pp. 713–20.

    Article  CAS  Google Scholar 

  27. F. Stein, M. Palm, and G. Sauthoff: Intermetallics, 2005, vol. 13, pp. 1056–74.

    Article  CAS  Google Scholar 

  28. F. Laves and H. Witte: Metallwirtschaft, 1936, vol. 15, pp. 840–42.

    CAS  Google Scholar 

  29. K.H. Lieser and H. Witte: Z. Metallkd., 1952, vol. 43, pp. 396–401.

    CAS  Google Scholar 

  30. M.S. Granovsky, M. Canay, E. Lena, and D. Arias: J. Nucl. Mater., 2002, vol. 302, pp. 1–8.

    Article  CAS  Google Scholar 

  31. R. Nesper and G.J. Miller: J. Alloys Compounds, 1993, vol. 197, pp. 109–21.

    Article  CAS  Google Scholar 

  32. F. Stein, G. Sauthoff, and M. Palm: J. Phase Equilibria, 2002, vol. 23, pp. 480–94.

    Article  CAS  Google Scholar 

  33. J.L. Murray: Phase Diagrams of Binary Titanium Alloys, ASM INTERNATIONAL, Materials Park, OH, 1987, pp. 59–68.

    Google Scholar 

  34. R. Agarwal, J.J. Lee, H.L. Lukas, and F. Sommer: Z. Metallkd., 1995, vol. 86, pp. 103–08.

    CAS  Google Scholar 

  35. V.W. Klemm and F. Dinkelacker: Z. Anorg. Chem., 1947, vol. 255, pp. 2–12.

    Article  CAS  Google Scholar 

  36. V.H. Vosskuehler: Z. Metallkd., 1937, vol. 29, pp. 236–37.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Suzuki, A., Saddock, N.D., Jones, J.W. et al. Phase equilibria in the Mg-Al-Ca ternary system at 773 and 673 K. Metall Mater Trans A 37, 975–983 (2006). https://doi.org/10.1007/s11661-006-0070-6

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11661-006-0070-6

Keywords

Navigation