Abstract
Ni3Si alloys with 20, 30, and 40 wt pct Cr were fabricated by self-propagating high-temperature synthesis casting at 543 K. Thermite reaction (Cr2O3+5CrO3+12Al=7Cr+6Al2O3) was used in Cr alloying. The method is simple and economical when used to prepare Ni3Si-based alloys. The process is described in detail. The alloys were analyzed with X-ray diffraction (XRD) and scanning electron microscopy (SEM) with X-ray energy dispersive spectroscopy (EDS). The results showed the alloys mainly consisted of Ni3Si and Ni5Si2 with dissolved Cr and Cr phases. Phases and microstructures of the alloys varied with Cr content. Microhardness, bending and compressive strength, and wear rate of the alloys were measured. Microhardness of the alloys was higher than that of Ni3Si without Cr and increased with Cr content. Bending and compressive strength of the alloys were better than those of the Ni3Si without Cr, and those of the alloy with 30 wt pct Cr were the highest. The wear rate of the alloys was lower than that of the Ni3Si without Cr and decreased with Cr content.
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P.H. Thornton and R.G. Davies: Metall. Trans., 1970, vol. 1, p. 549.
K.S. Kumar: in Intermetallic Compounds—Principles and Practice, J.H. Westbrook and R.L. Fleischer, eds., John Wiley & Sons Ltd., Chichester, United Kingdom, 1995, vol. 2, pp. 211.
E.M. Grala: Mechanical Properties of Intermetallic Compounds, Wiley, New York, NY, 1960, p. 358.
T. Takasugi, D. Shindo, and O. Izumi: Acta Metall., 1990, vol. 38, p. 739.
T. Takasugi: Mater. Sci. Technol., 2000, vol. 16, p. 73.
J.S.C. Jang and C.H. Tsau: Mater. Sci. Eng., 1992, vol. A153, p. 525.
T. Takasugi, M. Nagashima, and O. Izumi: Acta Metall., 1990, vol. 38, p. 747.
CL. Ma, T. Takasugi, and S. Hanada: Mater. Trans. JIM, 1995, vol. 36, p. 30.
C.T. Liu, E.P. George, and W.C. Oliver: Intermetallics, 1996, vol. 4, p. 77.
J.S.C. Jang, S.K. Wang, and P.Y. Lee: Mater. Sci. Eng., 2000, vol. A281, p. 17.
J.S.C. Jang, C.Y. Cheng, and S.K. Wang: Mater. Chem. Phys., 2001, vol. 72, p. 66.
J.H. Ulvensøen, G. Rorvik, T. Kyvik, K. Pettersen, and L. Estrade: Proc. Int. Symp. on Structural Intermetallics, TMS, Warrendale, PA, 1993, pp. 707–13.
S. Van Dyck, L. Delaey, L. Froyen, and L. Buekenhout: Intermetallics, 1997, vol. 5, pp. 137–45.
W.C. Oliver: High-Temperature Ordered Intermetallic Alloys III, MRS Conf. Proc., Materials Research Society, Pittsburgh, PA, 1989, vol. 133, pp. 397–402.
L.M. Pike and C.T. Liu: Scripta Mater., 2000, vol. 42, pp. 265–70.
P.Q. La, M.W. Bai, Q.J. Xue, and W.M. Liu: Surface Coatings Technol., 1999, vol. 113, pp. 44.
P.Q. La, Q.J. Xue, and W.M. Liu: Metall. Mater. Trans. A, 2001, vol. 32A, p. 1823.
P.Q. La, Q.J. Xue, and W.M. Liu: Intermetallics, 2003, vol. 32A, p. 541.
J. Acker and K. Bohmhammel: Thermochimica Acta, 1999, vol. 337, p. 187.
J.A. Dean: Lang’s Handbook of Chemistry, 11th ed., McGraw-Hill, New York, NY, 1972.
Robert C. Weast: CRC Handbook of Chemistry and Physics, 63rd ed., 1982–1983, D47–D48.
J. Subrahmanyam and M. Vijayakumar: J. Mater. Sci., 1992, vol. 27, p. 6249.
N.P. Novikov, I.P. Borovinskaya, and A.G. Merzhanov: in Combustion Process in Chemical Technology and Metallurgy, Chernogolovka, Moscow, 1975, p. 174.
Z.A. Munir: Ceram. Bull., 1988, vol. 67, p. 342.
D.L. Zhang and J.J. Richmond: J. Mater. Sci., 1999, vol. 34, p. 701.
K.J. Blobaum and M.E. Reiss: J. Appl. Phys., 2003, vol. 94, p. 2915.
L.L. Wang, Z.A. Munir, and Y.M. Maximov: J. Mater. Sci., 1993, vol. 28, p. 3693.
P.Q. La, M.W. Bai, Q.J. Xue, and W.M. Liu: Mater. Sci. Technol., 2000, vol. 16, p. 110.
An Geyin: Theory of Solidification, Mechanical Industry Press, Beijing, 1988.
T.B. Massalski, L. Bennett, and L.H. Murray: Binary Alloy Phase Diagrams, ASM INTERNATIONAL, Metal Park, OH, 1986.
J.C. Anderson, K.D. Leaver, R.D. Rawlings, and J.M. Alexander: Materials Science, 3rd ed., pp. 181–286.
P.Q. La, Q.J. Xue, and W.M. Liu: Mater. Sci. Eng., 2000, vol. A277, p. 273.
Heiko Kleykamp: J. Alloys Compounds, 2001, vol. 321, pp. 138–45.
Joel I. Gersten and F.W. Smith: Phys. Chem., 2001 pp. 121–39.
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Bi, Q., La, P. & Ding, Y. Microstructure and properties of Ni3Si alloyed with Cr fabricated by self-propagating high-temperature synthesis casting route. Metall Mater Trans A 36, 1301–1307 (2005). https://doi.org/10.1007/s11661-005-0222-0
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DOI: https://doi.org/10.1007/s11661-005-0222-0